Green smelting method for recycled aluminum alloy

An aluminum alloy melt and aluminum alloy technology, applied in the field of recycled aluminum, can solve the problems of difficult disposal of refining slag, difficult control of melt composition, and white smoke pollution, etc., and achieve high utilization rate of argon gas, easy control, and high recovery rate Effect

Active Publication Date: 2020-02-21
DELTA ALUMINUM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing "salt impurity removal-nitrogen degassing" refining process has the following problems: ① salt flux is used for refining, and the harmful white smoke pollution generated during the refining process contains Cl, F, etc.; Salt and other pollutants; ② Nitrogen is used for degassing. In the initial process, nitrogen will react with aluminum and its alloy elements such as Mg, and MgN and AlN are easily formed, resulting in difficult control of melt composition and low recovery rate
Although the method is simple and low-cost, nitrogen will react with molten aluminum to form aluminum nitride, making refining slag difficult to dispose of

Method used

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  • Green smelting method for recycled aluminum alloy
  • Green smelting method for recycled aluminum alloy
  • Green smelting method for recycled aluminum alloy

Examples

Experimental program
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Effect test

Embodiment 1

[0037] After smelting and adjusting the composition of the aluminum secondary resources after the paint removal, argon is used for refining and degassing at the same time, and the inclusions and hydrogen of the recycled aluminum alloy melt are removed. The argon gas is introduced through the breathable brick at the bottom of the melting furnace, and the recycled aluminum alloy melt is refined and degassed at 680°C for 120.0min, the flow rate of argon gas is 0.5L / min, the air pressure is 0.1MPa, and the average size of the bubbles is 0.5mm. The secondary aluminum alloy melt after refining and degassing has an inclusion content of 0.30%, a hydrogen content of 0.10ml / 100gAl, an aluminum ash residue composed of aluminum alloy and alumina, and does not contain salts and aluminum nitride pollution sources.

Embodiment 2

[0039] After smelting and adjusting the composition of the aluminum secondary resources after the paint removal, argon is used for refining and degassing at the same time, and the inclusions and hydrogen of the recycled aluminum alloy melt are removed. The argon gas is introduced through the breathable brick at the bottom of the melting furnace, and the recycled aluminum alloy melt is refined and degassed at 700°C for 110.0min, the flow rate of argon gas is 15.0L / min, the air pressure is 0.1MPa, and the average size of the bubbles is 2.0mm. The secondary aluminum alloy melt after refining and degassing has an inclusion content of 0.40%, a hydrogen content of 0.12ml / 100gAl, an aluminum ash residue composed of aluminum alloy and alumina, and does not contain salts and aluminum nitride pollution sources.

Embodiment 3

[0041] After smelting and adjusting the composition of the aluminum secondary resources after the paint removal, argon is used for refining and degassing at the same time, and the inclusions and hydrogen of the recycled aluminum alloy melt are removed. The argon gas is introduced through the breathable brick at the bottom of the melting furnace, and the recycled aluminum alloy melt is refined and degassed at 720°C for 100.0min, the flow rate of argon gas is 30.0L / min, the air pressure is 0.15MPa, and the average size of the bubbles is 4.0mm. The secondary aluminum alloy melt after refining and degassing has an inclusion content of 0.50%, a hydrogen content of 0.14ml / 100gAl, an aluminum ash residue composed of aluminum alloy and alumina, and does not contain salts and aluminum nitride pollution sources.

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Abstract

The invention relates to the technical field of recycled aluminum, and provides a green smelting method for recycled aluminum alloy. After aluminum secondary resources obtained after paint removal aresmelted and subjected to component adjustment, argon refining and argon degassing are adopted at a certain temperature, argon is introduced into a recycled aluminum alloy melt, inclusions and hydrogen are brought out of the melt, and a recycled aluminum alloy melt with high purity and low hydrogen content is obtained; the argon is fine and dispersed argon bubbles when introduced; the argon introduction mode is one or two of introduction from air-permeable bricks at the bottom of a smelting furnace and introduction from an air guide pipe; and the average size of the bubbles during argon introduction is 0.5-20.0 mm. According to the method, salt refining agents and nitrogen degassing agents are not used, the nitrogen burning loss is avoided, generated aluminum slag does not contain pollutants such as salt and aluminum nitride, and the obtained recycled aluminum melt is low in hydrogen and inclusions content. The quality of a recycled aluminum product is good, the method is simple and effective, and the application prospect is wide.

Description

technical field [0001] The invention relates to the technical field of secondary aluminum, in particular to a green smelting method of secondary aluminum alloy. Background technique [0002] The demand for aluminum is growing rapidly, and bauxite is difficult to meet. At the same time, the secondary resources of aluminum are increasing rapidly. Using aluminum secondary resources as raw materials to regenerate aluminum alloys not only does not require bauxite, but also consumes only 3%-4% of primary aluminum per ton of aluminum, which has a remarkable effect in energy saving and emission reduction. [0003] Aluminum secondary resources have a wide range of sources, including metals (such as Mg, Si, Fe, Zn, etc.) and non-metals (paint, oil, carbon fiber, etc.) And other impurities exist in the melt. Therefore, the secondary aluminum alloy melt must be refined. The existing "salt impurity removal-nitrogen degassing" refining process has the following problems: ① salt flux is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C1/03C22C1/06C22C21/00
CPCC22C1/026C22C1/03C22C1/06C22C21/00
Inventor 张深根蔺瑞刘波
Owner DELTA ALUMINUM IND
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