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An industrial wet ball milling method for manganese ore based on electrolytic manganese anolyte

A technology of wet ball milling and anolyte, which is applied in the direction of grain processing, etc., can solve the problems of dry ball mill dust collection, heavy dust, large processing problems in the dust collection section, and many auxiliary equipment, so as to shorten the production process, solve ball mill corrosion, Effect of investment cost reduction

Active Publication Date: 2021-08-17
贵州武陵锰业有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, the dry ball milling method must be equipped with a set of air duct system and many auxiliary equipments; dry ball mill dust collection, dust heavy, has become a big problem in the dust collection section

Method used

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  • An industrial wet ball milling method for manganese ore based on electrolytic manganese anolyte
  • An industrial wet ball milling method for manganese ore based on electrolytic manganese anolyte
  • An industrial wet ball milling method for manganese ore based on electrolytic manganese anolyte

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Such as figure 1 As shown, the manganese ore industrialized wet ball milling method based on electrolytic manganese anolyte adopts three-stage closed-circuit wet grinding, and the steps include:

[0022] Step 1, 1kg manganese ore (including the following mass percentage components: Mn18.32% (main phase is MnCO 3 ), Fe 2 o 3 2.14%, MgO3.54%, CaO6.2% and SiO 2 25.5% etc.) are crushed to less than 10mm, and then the electrolytic manganese anolyte (the electrolytic manganese anolyte contains sulfuric acid 30g / L) is used to adjust the slurry to 80wt%. Ball milling until the particle size of the manganese ore is below 80 mesh accounts for 90%, and the unqualified manganese ore after the primary classification is returned to the primary wet ball mill;

[0023] Step 2. Slurry the manganese ore below 80 mesh obtained in step 1 to 70wt% with the electrolytic manganese anolyte, and perform secondary wet ball milling under the conditions of a rotating speed of 40r / min and a bal...

Embodiment 2

[0027] Such as figure 1 As shown, the manganese ore industrialized wet ball milling method based on electrolytic manganese anolyte adopts three-stage closed-circuit wet grinding, and the steps include:

[0028] Step 1, 1kg manganese ore (including the following mass percentage components: Mn19.4% (main phase is MnCO 3 ), Fe 2 o 3 2.67%, MgO4.12%, CaO5.9% and SiO 2 22.4% etc.) are broken to less than 25mm, and then the electrolytic manganese anolyte (electrolytic manganese anolyte containing sulfuric acid 50g / L) is used to adjust the slurry to 85wt%. Ball milling until the particle size of the manganese ore is below 80 mesh accounts for 90%, and the unqualified manganese ore after the primary classification is returned to the primary wet ball mill;

[0029] Step 2. Slurry the manganese ore below 80 mesh obtained in step 1 to 75wt% with electrolytic manganese anolyte, and perform secondary wet ball milling until the particle size of the manganese ore is below 120 mesh at a r...

Embodiment 3

[0033] Such as figure 1 As shown, the manganese ore industrialized wet ball milling method based on electrolytic manganese anolyte adopts three-stage closed-circuit wet grinding, and the steps include:

[0034] Step 1, 1kg manganese ore (including the following mass percentage components: Mn20.1% (main phase is MnCO 3 ), Fe 2 o 3 1.98%, MgO4.07%, CaO7.1% and SiO 2 25.6% etc.) are broken to less than 15mm, and then the electrolytic manganese anolyte (the electrolytic manganese anolyte contains sulfuric acid 40g / L) is used to adjust the slurry to 82wt%. Ball milling until the particle size of the manganese ore is below 80 mesh accounts for 90%, and the unqualified manganese ore after the primary classification is returned to the primary wet ball mill;

[0035] Step 2. Slurry the manganese ore below 80 mesh obtained in step 1 to 72wt% with electrolytic manganese anolyte, and perform secondary wet ball milling until the particle size of the manganese ore is below 120 mesh at a...

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Abstract

The invention relates to an industrialized wet ball milling method for manganese ore based on electrolytic manganese anolyte, and belongs to the technical field of electrolytic manganese production. The manganese ore is slurried to more than 65wt% by using electrolytic manganese anolyte, and then subjected to a closed-circuit wet ball mill of one level or more until the particle size is below 150 mesh to obtain a qualified manganese ore powder product. The present invention adopts the electrolytic manganese anolyte to mix the manganese ore and carry out wet ball milling. On the one hand, no dust will be generated during the wet ball milling process, and no matching dust collection system is required, so the production cost is significantly reduced; The electrolytic manganese anolyte is added in the ball milling process, the electrolytic manganese anolyte is further applied, and the pre-leaching process can be carried out in advance before the leaching process, the leaching process is strengthened, the subsequent leaching time is shortened, and the leaching efficiency and leaching results are improved.

Description

technical field [0001] The invention relates to an industrialized wet ball milling method for manganese ore based on electrolytic manganese anolyte, and belongs to the technical field of electrolytic manganese production. Background technique [0002] With the development of science and technology, the application of electrolytic manganese continues to expand, and the market demand increases by about 15% annually, and it is widely used in metallurgy, medicine, electronics, communication and other fields. The metallurgical production process of electrolytic manganese is leaching, oxidation and neutralization after manganese ore grinding, then removing impurities, electrolysis, passivation and stripping after pressure filtration to prepare electrolytic manganese metal. The manganese anolyte produced by electrolytic manganese contains about 12-15g / L manganese and high-concentration ammonium sulfate, etc. Part of it is used as a leaching agent and returned to the pulping process...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B02C21/00B02C17/10
CPCB02C17/10B02C21/00
Inventor 常军秦林张超王子阳李学鹏
Owner 贵州武陵锰业有限公司