183results about How to "Shorten the leaching time" patented technology

The invention provides a method for leaching manganese sulfate from low grade pyrolusite. The method comprises the steps of crushing low grade pyrolusite and pyrite, placing crushed pyrolusite and pyrite in a leaching tank and mixing crushed pyrolusite and pyrite with sulfuric acid to prepare ore slurry. According to the invention, the mass percentage of manganese in pyrolusite is 9% to 21%, the mass ratio of pyrolusite to pyrite is 5-3:1, the molar concentration of sulfuric acid is 1 to 1.2 mol/L, and the mass ratio of sulfuric acid to pyrolusite and pyrite is 6-8:1; electrocatalytic reinforcement is carried out on the ore slurry so as to accelerate a reduction reaction. The method for leaching manganese sulfate from poor pyrolusite provided in the invention has the advantages of low cost, easy operation, short time, a high leaching rate of manganese, etc.

The invention relates to a method for recovering rare earth in neodymium-iron-boron waste by high-temperature and high-pressure leaching. The neodymium-iron-boron waste is subjected to oxidation roasting, hydrochloric acid high-temperature and high-pressure leaching, and oxidation and impurity removal purification on Fe2+ in a leachate so as to obtain a rare-earth chloride leachate; and the rare-earth chloride leachate can be used as a subsequent process and a product raw material, rare earth is obtained through extraction and separation, rare earth carbonate is prepared through precipitation,or rare earth oxide is prepared through precipitation-roasting. According to the method, a closed high-pressure reaction kettle is adopted as leaching equipment, so that the dynamic condition of theleaching process is excellent, the requirement for the particle size of the leached raw materials is low, a large amount of dust generated by the fine grinding process of the raw materials is avoided,the leaching rate of rare earth in the leaching process is high, the utilization rate of hydrochloric acid is high, no acid gas is discharged, energy is saved, and the environment is protected; and in addition, the method has the advantages of being short in process flow, simple in process conditions and low in recovery cost, and the method has considerable economic, social and environmental protection benefits for large-scale recovery of the neodymium-iron-boron waste.

The invention belongs to the field of nonferrous metal hydrometallurgy and discloses a process of efficiently recovering copper from lead matte according to oxygen pressure acid leaching and vortex electrolysis techniques. The method includes: taking lead matte as a raw material, crushing and grinding the lead matte, screening through a 100-mesh sieve, adding into a high-pressure autoclave along with sulfuric acid and a dispersing agent, feeding oxygen for leaching, carrying out liquid-solid separation to obtain solution containing copper sulfate, subjecting the solution containing copper sulfate to vortex electrolytic decopperation to obtain cathode copper, and returning after-electrodeposition liquid to the leaching procedure to replace sulfuric acid serving as the leaching agent. High efficiency in copper recycling can be realized, electrodeposition of copper can be selectively carried out according to the vortex electrolysis techniques, and high current level and current efficiency, low reagent consumption, reduction of production cost and improvement of enterprise benefits are realized. In addition, due to closed cycle of solution, harmful gas emission is avoided, and current concepts of circular economy and environment protection are met.

The invention relates to a method for strongly leaching laterite-nickel ore at normal pressure by using sulphuric acid, which comprises the following steps of: adding laterite-nickel ore into leacheate, mixing and ball-milling to be less than or equal to 100 mesh, adding concentrated sulphuric acid according to the liquid-solid ratio of (4-9):1, increasing the temperature to 150-160 DEG C, maintaining reaction for 20-60 minutes, decreasing the temperature to 80-100 DEG C, filter pressing, and pressing filtrate in a thermal insulation storage tank; adding leacheate, the volume of which is the same to that of a filter cake, to carry out pressure washing and filter pressing, obtaining filtrate and the filter cake again, also pressing the filtrate in the thermal insulation storage tank, discharging the filter cake, mixing and washing by using hot water so that crystal substances are thoroughly dissolved, and filtering to obtain the filtrate and the filter cake; and purifying the filtrate and removing impurities from the filtrate, continuously carrying out pressure washing by using clean water through the filter cake in a counter-current manner, and continuously detecting the pH value of pressure washing liquid until leached residues achieve emission standard. According to the invention, the leaching efficiency of nickel-cobalt can be increased by above 99wt%; most of all metallic elements which can be dissolved by sulphuric acid can be leached; silica gel does not exist in the leaching process; and the filtering performance of the leached residues is good.

The invention discloses a method for recovering copper from a waste circuit board and belongs to the technical field of hydrometallurgy. The method comprises the following steps: firstly crushing the waste circuit board into powder, fully mixing the powder, an ammonia water solution, an ammonium chloride solution and water to obtain ore pulp, introducing air into the ore pulp, and carrying out ultrasonic wave intensified leaching under a stirring condition; and periodically adding hydrogen peroxide in the intensified leaching process so as to leach copper from the waste circuit board, wherein the leaching rate of copper from the waste circuit board leached in 1 hour reaches over 98%. The method disclosed by the invention realizes resource utilization of effective components of the waste circuit board and moreover, the method has the advantages of being environment-friendly, mild in reaction and short in technological process, the production cost can be lowered and the metal copper recovery rate is high, and the method is suitable for recovering valuable metals in the waste circuit board.

The invention discloses a wet-process comprehensive recovery and utilization method for zinc replacement residues. The wet-process comprehensive recovery and utilization method can efficiently recover zinc, germanium, gallium, copper, iron and silicon dioxide in the zinc replacement residues, and the leaching rates of all the metals are all higher than 94%. The wet-process comprehensive recovery and utilization method is conductive to improving the metal comprehensive recovery rate, meanwhile, the energy consumption in the whole technological process is reduced, generated waste liquid is returned for leaching to achieve the purpose of cyclic utilization, the problem of environmental pollution is solved, and the wet-process comprehensive recovery and utilization method is environment-friendly.

The invention belongs to the field of hydrometallurgy of non-ferrous metals, and particularly relates to a method for pre-treating high-impurity copper anode slime rich in noble metals. The method comprises the following special steps: adding sulfuric acid in the dried copper anode slime to mix size, placing in a microwave reactor, carrying out the microwave acid leaching for 5-30 min, performing the solid-liquid separation to obtain microwave acid leaching slag and a microwave acid leaching solution, adding dilute sulphuric acid in the microwave acid leaching slag to mix size, placing the microwave acid leaching sizing agent in a high-pressure reaction kettle under the pressure of 0.8-1.2 MPa after oxygen introducing, carrying out pressure acid leaching for 4-6 h to obtain pressure acid leaching slag and a pressure acid leaching solution, recovering gold and silver from the pressure acid leaching slag, and recovering nickel from the pressure acid leaching solution. The method adopting the technical scheme improves the recovery rate of copper, selenium, tellurium and nickel in the impurity copper anode slime, shortens the processing time of the copper anode slime, increases the processing capacity of the copper anode slime, enables the trend of the noble metals to be reasonable and concentrated, and is favorable for comprehensive recovery.

The invention discloses a method for biologically leaching heavy metal from a heavy metal-contained waste based on pH and potential co-regulation. The method comprises the following steps: in a process of leaching out the heavy metal-contained waste by an acidophilic iron oxide microbial agent, the pH value of the leaching system is controlled within 1.0-4.0 in the whole process; meanwhile, an oxidizing agent is combined with a reducing agent to regulate the redox potential of the leaching system, so that the redox potential of the leaching system is controlled within 420-650 mV; the pH value of the leaching system is gradually increased phase by phase in the leaching process; the redox potential of the leaching system is gradually increased phase by phase; the total leaching time is within 8 hours; and finally, the efficient leaching of the heavy metal from the heavy metal-contained waste by the acidophilic iron oxide microbial agent is realized. The method can accelerate biologic leaching of metal from sludge to shorten the leaching time and to reduce the acid consumption, and can greatly improve the biologic leaching efficiency.

The invention discloses an electrolytic manganese residue harmless treatment and resource utilization method. The electrolytic manganese residue harmless treatment and resource utilization method comprises the steps that firstly, a calcium oxide additive and a calcium carbonate additive are added into leaching liquid, and impurities such as iron, magnesium and calcium in the leaching liquid are effectively removed; secondly, the pH value of the leaching liquid is regulated through sodium hydroxide, sodium carbonate is added to react, and thus a manganese carbonate product is obtained; and finally, by adding calcium oxide, high-concentration ammonia nitrogen in filtrate is removed in an air stripping mode, escaping gas is absorbed through clear water, and the filtrate is reused. According to the electrolytic manganese residue harmless treatment and resource utilization method, the contents of heavy metal and the ammonia nitrogen in electrolytic manganese residues are effectively decreased, the manganese and ammonia nitrogen leaching time is shortened, and the leaching rates of manganese and the ammonia nitrogen in the electrolytic manganese residues are increased; and manganese in the leaching liquid is mainly recycled as manganese carbonate, a product can be directly used as electrolytic manganese residue raw materials, and in addition, the leaching liquid after a stripping reaction can be recycled.

The invention relates to an ultrasonic-assisted method for leaching potassium at low temperature under normal pressure, which comprises the following steps: crushing and grinding: crushing and grinding potash feldspar ore until the fineness is about 150 meshes: acid-ore mixing: adding 5-15mL of phosphoric acid-organic acid mixed solution to every gram of potash feldspar, and uniformly mixing, wherein the mixing ratio of the phosphoric acid to the organic acid is (1-4):1; leaching reaction: carrying out leaching reaction on the acid-ore mixture under normal pressure at 30-100 DEG C for 10-48 hours under the assistance of ultrasonic; extraction: adding distilled water into the leaching reaction product to the original volume of the acid-ore mixture, and extracting; and carrying out solid-liquid separation to remove the filter residue, thereby obtaining the soluble potassium solution. The method is beneficial to the development of the pore fracture and the formation of the new reaction interface, promotes the action of acid dissolution, has the characteristics of short leaching time, low facility requests and the like, does not need high-temperature calcination, can perform reaction at low temperature under normal pressure, and greatly saves the production cost; and the mixed acid solution can be easily purchased in the market, and is friendly to the reaction environment.

The invention discloses a method for regenerating waste lithium nickel cobalt manganate ternary cathode material of. The method comprises lixiviating the waste lithium nickel cobalt manganate ternarycathode material by using phosphoric acid- citric acid mixed acid solution to obtain a lixivium; adjusting the metal ion ratio of the lixivium by a nickel salt, a cobalt salt and a manganese salt, andthen adding the lixivium into an oxalic acid solution for coprecipitation reaction; pre-calcining the obtained precipitate to obtain nickel cobalt manganese oxide, and grinding and mixing the nickelcobalt manganese oxide with a lithium source, calcining a resultant object to obtain a regenerated lithium nickel cobalt manganate ternary cathode material; The method adopts mixed acid lixiviating process, the acid consumption is small, the lixiviating time is short, the cost is low, the environmental impact is small, and the reducing agent is not needed, and the process is simple; The mixed acidlixivium is directly used for synthesizing ternary cathode materials, thereby avoiding the complicated process of separating and purifying various metals in the lixivium in the prior art, and realizing the closed-loop recycling utilization of metals.