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53results about How to "Enhanced leaching process" patented technology

Industrial microwave ultrasonic reaction kettle

Disclosed is an industrial microwave ultrasonic reactor. The inner wall of the reactor is provided with a liner; a microwave generation device is composed of microwave units distributed over the outer sidewall of the reactor in a spaced manner, or of a microwave pipe provided outside the reactor and microwave units distributed over the microwave pipe in a spaced manner. One end of the microwave pipe is in communication with the bottom of the reactor via a connecting pipe I and the other end is in communication with the top of the reactor via a return pipe. A shield is provided outside the microwave generation device to space the microwave units apart from the outer space, with a heat removal device being provided outside the shield. The microwave generation device is composed of ultrasonic pulse units provided along the outer sidewall of the reactor in a spaced manner; there are 10 - 30 sets of ultrasonic pulse units provided from top to bottom, each set having 10 - 50 members and being distributed along the circumferential direction of the reactor, and a stirring shaft of a stirring device is fixed below a stirring motor and extends into the reactor. The present reactor can shorten the time for chemical leaching, improve the purity of a product extracted and increase operation efficiency.
Owner:SONGXIAN EXPLOITER MOLYBDENUM

Technology for zinc wet-process clean smelting and resource comprehensive recycling

The invention belongs to the technical field of zinc smelting of the nonferrous metal smelting industry, in particular relates to a technology for valuable metal comprehensive recycling and iron element separating and concentrating during a zinc clean smelting process. Zinc calcine which is produced through calcinating zinc concentrate is separated out through neutral leaching and low-acid leaching and is then fed into a wet-process reinforced leaching system to separate acid soluble metals from insoluble substances; the separated zinc and soluble impurity-containing liquid enters a valuable metal separating and concentrating system to separate out indium, gallium, germanium and the like, the separated valuable metal sludge enters a special recycling system; and the liquid enters a zinc and iron separating system to completely separate out zinc and iron, iron is output in a high-grade iron ore concentrate mode, zinc enters the next process in a zinc sulfate mode, and the liquid enters an electrolyzing system after deep purification to output metal zinc. The technology has high metal zinc recovery rate, good valuable metal comprehensive recycling effect, a good environment-friendly effect and high iron content of hematite sludge, the hematite sludge can be treated to be used as a raw material for smelting iron, so that 'non-sludge' smelting is realized, and the smelting process is compact.
Owner:HENAN YUGUANG ZINC IND

Method and device for immobilizing CO2 by enhancing mineral carbonation

InactiveCN102343199AFast catalytic reaction ratePromotes hydrationDispersed particle separationUltrasound - actionSlurry
The invention discloses a method and device for immobilizing CO2 in industrial tail gas by enhancing mineral carbonation. The device comprises a packed column absorber, a mineral leaching tank, a carbonation reactor and a belt type filter. The method comprises the steps of: enabling the industrial tail gas containing CO2 to enter the packed column absorber filled with immobilization carbonic anhydrase, rapidly transforming the CO2 into HCO3<-> under the catalysis action of the carbonic anhydrase; with a weak acidic solution containing the HCO3<-> as a mineral leaching agent, effectively leaching calcium ions from minerals in the mineral leaching tank under the action of ultrasonic waves to form a slurry enriching Ca<2+>; introducing the slurry enriching Ca<2+> into the carbonation reactor, adding a calcium-containing alkali material, regulating the pH of the slurry to be 7-9 to ensure that the HCO3<-> is transformed into CO3<2->, and generating a carbonation reaction with the Ca<2+> leached from the minerals to generate CaCO3. The invention can promote the CO2 to be rapidly transformed into the HCO3<->, can promote the calcium ions to be leached from the minerals and the carbonation reaction, and further realizes that the CO2 in the industrial tail gas is immobilized through direct carbonation under normal pressure.
Owner:SOUTHEAST UNIV

Method for selectively enriching scandium from Bayer process red mud

The invention discloses a method for selectively enriching scandium from Bayer process red mud. The method is characterized in that the Bayer process red mud is used as a raw material, the red mud isfully wet by adding an appropriate amount of water, the red mud is sulphated by using concentrated sulfuric acid and is then calcined at a high temperature, the solid calcined product is mechanicallyactivated by grinding and is then subjected to four-stage water immersion and washing, so that a scandium-rich leaching solution, scandium-rich washing liquid and low-alkali iron-rich slag are obtained. The method enables most of scandium to be leached, but the leaching rates of impurity iron and aluminum are low, and silicon and titanium are not leached substantially, so that the formation of colloidal silicate in the leaching solution is avoided, and the selective absorption and extraction of the scandium in the subsequent leaching solution are facilitated; the generated sulfur dioxide and sulfur trioxide can be reused in the preparation of sulfuric acid, so that the production of a large amount of waste acid is avoided; the pH of the low-alkali iron-rich slag is close to neutral, and can be used in the industries such as iron making, adsorbents, ceramics, construction and the like, so that a new way is provided for the extraction of the scandium and the comprehensive utilization ofthe red mud.
Owner:GUANGXI UNIV

Iron balancing technology in low-grade sulfide ore biological heap leaching-leachate purification-extraction and separation process

The invention relates to an iron balancing technology in a low-grade sulfide ore biological heap leaching-leachate purification-extraction and separation process. The technology comprises the following steps: firstly dissolving alunite and other potassium-containing minerals in a mineral heap to form one part of iron vitriol type precipitate in the mineral heap; secondly adding lime into a biological leachate to regulate the pH value of the leachate, adding a mixed leaching bacterial solution of ferrous oxide and the like and an iron vitriol seed crystal, and accelerating the formation of the iron vitriol type precipitate by a biological vitriol formation method to realize fast and efficient purification and iron removal; and adding the mixed leaching bacterial solution of iron-oxidizing bacteria and the like before raffinate returns to the mineral heap, regenerating iron in the raffinate, and then returning the raffinate to the mineral heap as spraying liquid. The iron balancing technology provided by the invention is suitable for controlling impurities in the biological leaching process of low-grade sulfide ores, the problems of serious entrainment of valuable elements, high neutralization cost and the like caused by traditional iron removal by neutralizing with the lime are solved, and the leaching and extraction separation efficiency is improved at the same time.
Owner:GENERAL RESEARCH INSTITUTE FOR NONFERROUS METALS BEIJNG

Method for separating and enriching lithium, aluminum and silicon from fly ash

The invention discloses a method for separating and enriching lithium, aluminum and silicon from fly ash. The method comprises the following steps: (1) pretreating fly ash; (2) carrying out low-temperature alkali dip reaction on the treated fly ash, aids and a sodium hydroxide solution, and filtering; (3) washing the filter residue, removing the impurities, filtering, and drying to obtain calcium silicate; (4) regulating the pH value of the filtrate to alkalinity, separating the lithium / aluminum-containing filtrate to obtain a sodium metaaluminate concentrated solution and a lithium-rich solution, carrying out reverse osmosis on the lithium-rich solution to obtain a lithium concentrated solution, and mixing the sodium metaaluminate concentrated solution with the lithium / aluminum-containing filtrate to obtain a refined solution; (5) precipitating the sodium metaaluminate refined solution, filtering to obtain aluminum hydroxide, and calcining to obtain the aluminum oxide finished product; (6) treating the lithium-rich solution to obtain a lithium-rich concentrated solution and fresh water; and (7) carrying out carbonating precipitation on the lithium-rich concentrated solution, filtering, and drying to obtain the lithium carbonate finished product. The method is a short-stage extraction process, reduces the lithium loss, and implements separation, enrichment and extraction of calcium silicate, aluminum oxide and lithium carbonate.
Owner:HEBEI UNIV OF ENG

Composite leaching agent for enhanced leaching of weathered crust elution-deposited rare earth ores

The invention relates to the field of wet metallurgy, in particular to a composite leaching agent for enhanced leaching of weathered crust elution-deposited rare earth ores and a preparation method thereof and a method for extracting rare earth. The composite leaching agent for enhanced leaching of the weathered crust elution-deposited rare earth ores comprises 1-4 % of an inorganic leaching agentand 0.1-1.2% of one or a combination of more of dimethyl diallyl ammonium chloride, 2-chloroethyl trimetyl ammonium chloride, an acrylamide and dimethyl diallyl ammonium chloride copolymer and acrylamidetrimethyl allyl ammonium chloride according to the mass percentage. The method for extracting the rare earth comprises the step of using the composite leaching agent for enhanced leaching of the weathered crust elution-deposited rare earth ores to leach the rare earth in the rare earth ores. Under the coordination between the inorganic leaching agent and an organic stabilizer, the weathered crust elution-deposited rare earth ores are leached in situ, the permeation of the leaching agent and the leaching process of the rare earth are enhanced, the consumption of the leaching agent is reduced, the expansion of the clay minerals is inhibited, problems that stability of the weathered crust elution-deposited rare earth ores is low and the weathered crust elution-deposited rare earth ores are easy to generate landslide due to the inorganic leaching agent are solved, and the exploration period is also shortened.
Owner:SOUTH CENTRAL UNIVERSITY FOR NATIONALITIES

Dynamic leaching system and method

InactiveCN109283299AEquipment composition is simpleEasy to operateMaterial analysisSolventToxicity
The invention discloses a dynamic leaching system. The dynamic leaching system comprises a container for containing a solvent, a metering pump, a conveying pipeline, at least two columnar containers,spray heads for spraying a leaching solvent into respective columnar containers, a collection container and rain gauges. One end of the conveying pipeline communicates with the container; the meteringpump is arranged on the conveying pipeline close to one end of the container; at least two branch pipelines are arranged at the other end of the conveying pipeline; each branch pipeline communicateswith one corresponding spray head; one columnar container is arranged below each spray head; one rain gauge is arranged in a cavity of one corresponding columnar container, and other columnar containers are used for containing to-be-leached samples and are provided with water outlets in the bottom walls; a filter is arranged above the bottom walls; and the obtained lixivium flows into the collection container through the water outlets. The invention further discloses a dynamic leaching method. The dynamic leaching system is simple in structure and can simulate toxicity dynamic leaching on solid waste, such as fly ash, in an on-site environment; and the method is simple to operate, wide in application and high in simulation effect.
Owner:HUNAN JUNXIN ENVIRONMENTAL PROTECTION CO LTD

Preparation method for extracting water-soluble polyose from black pine needles according to decompression inner-boiling method

The invention discloses a preparation method for extracting water-soluble polyose from black pine needles according to a decompression inner-boiling method. The preparation method comprises the following steps: putting the black pine needles in a constant-temperature drying cabinet for 24 hours' drying at 40 DEG C, milling the dried black pine needles by a miller, and sieving with a 80-mesh sieve; weighing 1 g of the obtained black pine needle powder, putting the weighed black pine needle powder in a glass device, and adding 2 ml of ethanol for 30 minutes' uniform wetting, so as to ensure that ethanol permeates the black pine needle powder; carrying out vacuum suction to reduce the gauge pressure to -0.080 MPa, carrying out decompression suction till slightly boiled bubbles are generated on the mixture surface, and carrying out filtration; extracting a solution by utilizing hot water of which the volume is 20 times of that of the solution and the temperature is 85 DEG C for 6 minutes; selecting a small amount of the extracted solution for dilution, and measuring the polyose content according to a phenol-sulfuric acid method; precipitating the extracted solution by utilizing a 4% ethanol solution, carrying out still standing for a night, carrying out centrifugation, and then taking out the precipitate for drying in the drying box; preparing the dried solution into a polyose product. Through adoption of the technical scheme, the leaching amount of polyose is improved; the decompression inner-boiling method is low in production cost and simple in process; the preparation method has the advantages that the effective components of polyose can be quickly extracted and separated in an environment-friendly manner.
Owner:杨平

Microbial fertilizer applicable to improvement of flaky salinized areas in Ningxia and Inner Mongolia in China

The invention relates to a microbial fertilizer applicable to improvement of flaky salinized areas in Ningxia and Inner Mongolia in China. The microbial fertilizer comprises 1 to 1.5 of rice husk, 10to 15 of humic acid, 10 to 16 of balloonflower roots, 30 to 40 of earthworm soil, 2 to 3 of cytokinin, 1 to 3 of gibberellins, 15 to 20 of peroxyacetic acid, 8 of Sulfolobus acidocaldarius, 6 of Bacillus megaterium, 4 of nitrogen fixation bacteria and 2 of ferment bacteria. Directed at the characteristic of soil in flaky salinized areas in Ningxia and Inner Mongolia in China, the rice husk and theballoonflower roots are cooperated with humic acid to improve soil nutrients; the earthworm soil absorbs oozed low-position steam and fully immobilizes the steam on the surface of a soil layer; gibberellin and peroxyacetic acid rapidly fracture one-piece alkalized soil and isolated fractured alkalized soil; and then a great amount of communicating fermentation broth of Sulfolobus acidocaldarius and Bacillus megaterium obtained after glycolysis infiltrates into alkaline soil with biological components, and rapid differentiation and proliferation are realized among blocks, so the leaching and desalination capabilities of soil are improved, and the content of accumulated salt in each alkaline earth block is continuously reduced.
Owner:SHANDONG SHENGJING TOURISM DEV CO LTD

Method for leaching vanadium by anode electrolysis in strong alkali electrolyte solution

The invention belongs to the field of leaching vanadium from ferrovanadium spinel minerals by an electrolysis method, and particularly relates to a method for leaching vanadium by anode electrolysis in a strong alkali electrolyte solution. The method comprises the following steps of preparing ferrovanadium spinel type vanadium-containing concentrate into a soluble anode and directly electrolyzingin the strong alkali electrolyte solution to obtain vanadium-containing leachate. In the method, iron contained in the anode is oxidized into ferrate ions which enter the solution, and the ferrate ions further promote the oxidation and leaching of vanadium in the vanadium-containing concentrate, and at the same time, pollution-free oxygen is precipitated on the anode surface. In addition, the ferrate ions entering the electrolyte solution are reduced by water and hydrogen generated by a cathode to form ferric oxide or / and ferric hydroxide precipitate, so that vanadium and iron are separated from the solution. The method electrolyzes the ferrovanadium spinel type vanadium-containing concentrate at normal temperature and pressure without adding any oxidant by utilizing the conductivity of ferrovanadium spinel and ferrate ions with the strong oxidizing property generated by electrolysis.
Owner:UNIV OF SCI & TECH BEIJING

Method and device for immobilizing CO2 by enhancing mineral carbonation

InactiveCN102343199BFast catalytic reaction ratePromotes hydrationDispersed particle separationUltrasound - actionSlurry
The invention discloses a method and device for immobilizing CO2 in industrial tail gas by enhancing mineral carbonation. The device comprises a packed column absorber, a mineral leaching tank, a carbonation reactor and a belt type filter. The method comprises the steps of: enabling the industrial tail gas containing CO2 to enter the packed column absorber filled with immobilization carbonic anhydrase, rapidly transforming the CO2 into HCO3<-> under the catalysis action of the carbonic anhydrase; with a weak acidic solution containing the HCO3<-> as a mineral leaching agent, effectively leaching calcium ions from minerals in the mineral leaching tank under the action of ultrasonic waves to form a slurry enriching Ca<2+>; introducing the slurry enriching Ca<2+> into the carbonation reactor, adding a calcium-containing alkali material, regulating the pH of the slurry to be 7-9 to ensure that the HCO3<-> is transformed into CO3<2->, and generating a carbonation reaction with the Ca<2+> leached from the minerals to generate CaCO3. The invention can promote the CO2 to be rapidly transformed into the HCO3<->, can promote the calcium ions to be leached from the minerals and the carbonation reaction, and further realizes that the CO2 in the industrial tail gas is immobilized through direct carbonation under normal pressure.
Owner:SOUTHEAST UNIV
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