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Method for preparing core-shell type cerium-gold catalyst by reversed-phase microemulsion process and application of catalyst

A gold catalyst and inverse microemulsion technology, which is applied in the field of preparing core-shell cerium-gold catalyst by inverse microemulsion method, can solve the problems of poor reaction effect and large gold particles, and achieve stable structure, prevent agglomeration, and high catalytic activity. and longevity effects

Active Publication Date: 2020-06-26
SHANDONG UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Benefits of technology

This patented technology uses an improved way for creating small metal shell structures called cathode-supported or lithographic types made up from tiny metallic powders suspended within solvents like alcohols. These smaller particle cores help stabilizing the emulsified mixture while forming larger ones without adding any chemical agents harmful to their surroundings. By reversely mixing these mixtures together at room temperatures, they become evenly distributed throughout them due to the presence of specific molecules attached to each part of the microspheral crystal network. When this material becomes active under acidic conditions, it forms nano scale particles that prevent downstream reactions and improve its effectiveness over existing methods. Additionally, if certain materials were added into the solution containing silver salt, then other elements could attach themselves onto those surfaces instead of being absorbed into them. Overall, this new technique provides better stability, efficiency, and durability than current techniques currently available.

Problems solved by technology

Technologies described in this patented text involve developing new ways to produce small molecules called benzonil acid compounds from formalarenol through various steps like decomposition into smaller ones before being reacted chemically. These techniques include butter oil baking, heat treatment, and other technical means. Additionally, there may exist different types of catalyst systems based on these principles.

Method used

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  • Method for preparing core-shell type cerium-gold catalyst by reversed-phase microemulsion process and application of catalyst
  • Method for preparing core-shell type cerium-gold catalyst by reversed-phase microemulsion process and application of catalyst
  • Method for preparing core-shell type cerium-gold catalyst by reversed-phase microemulsion process and application of catalyst

Examples

Experimental program
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Effect test

Embodiment 1

[0044] (1) Preparation of cerium gold precursor:

[0045] Measure 0.1ml chloroauric acid solution (0.1mol / L) with pipette gun in 50ml beaker, take by weighing 0.06g cerium nitrate and 0.5g ionic liquid (wherein R 1 is a straight-chain alkyl group with a carbon chain length of 4, R 2 is methyl, R 3 is a carboxyl group connected to a straight-chain alkyl group with a carbon chain length of 4, X - for Cl - ) into the beaker; then measure 5ml of n-heptane and 25ml of hexanol with a graduated cylinder and add it to a 50ml beaker, stir evenly to obtain a slightly yellow and clear A solution;

[0046] Measure 0.1ml of sodium hydroxide solution (0.5mol / L) with a pipette gun in a 50ml beaker, weigh 0.375g of the above-mentioned ionic liquid, measure 3.3ml of n-heptane and 1.7ml of hexanol with a graduated cylinder and add them to a 50ml beaker, Stir evenly to obtain a slightly yellow and clear B solution;

[0047] Then mix A solution and B solution evenly, and stir for 30 minutes ...

Embodiment 2

[0055] R in Example 1 1 Changed to R for a straight-chain alkyl group with a carbon chain length of 4 1 It is a linear alkyl group with a carbon chain length of 10, and all the other steps are the same as in Example 1. The obtained core-shell type cerium gold catalyst is used in the reaction system of one-step oxidative esterification of aldehydes to form esters, the conversion rate of methacrolein is 98.4%, and the selectivity of methyl methacrylate is 98.1%.

Embodiment 3

[0057] R in Example 1 1 Changed to R for a straight-chain alkyl group with a carbon chain length of 4 1 It is a straight-chain alkyl group whose carbon chain length is 14, and all the other steps are the same as in Example 1. The obtained core-shell type cerium gold catalyst is used in the reaction system of one-step oxidative esterification of aldehydes into esters, the conversion rate of methacrolein is 98.8%, and the selectivity of methyl methacrylate is 98.7%.

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Abstract

The invention relates to the technical field of industrial catalysts, in particular to a method for preparing a core-shell type cerium-gold catalyst through a reversed-phase microemulsion process andapplication of the catalyst. The preparation method comprises the following steps of: preparing a cerium-gold precursor, then loading the cerium-gold precursor on a carrier, and then performing roasting to obtain the core-shell type cerium-gold catalyst. According to the invention, ionic liquid is used as a surfactant, and the core-shell type cerium-gold catalyst is prepared by a reversed-phase microemulsion process. Strong acid and other substances polluting the environment are not used, operation is easy, reaction conditions are mild, the loaded ionic liquid can be used for preparing variouscore-shell type cerium-gold catalysts with different pore diameters, and the core-shell type cerium gold catalysts have high catalytic activity and long service life when applied to alcohol aldehydeoxidative esterification reaction.

Description

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Claims

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Application Information

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Owner SHANDONG UNIV OF TECH
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