Method for preparing core-shell type cerium-gold catalyst by reversed-phase microemulsion process and application of catalyst
A gold catalyst and inverse microemulsion technology, which is applied in the field of preparing core-shell cerium-gold catalyst by inverse microemulsion method, can solve the problems of poor reaction effect and large gold particles, and achieve stable structure, prevent agglomeration, and high catalytic activity. and longevity effects
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Embodiment 1
[0044] (1) Preparation of cerium gold precursor:
[0045] Measure 0.1ml chloroauric acid solution (0.1mol / L) with pipette gun in 50ml beaker, take by weighing 0.06g cerium nitrate and 0.5g ionic liquid (wherein R 1 is a straight-chain alkyl group with a carbon chain length of 4, R 2 is methyl, R 3 is a carboxyl group connected to a straight-chain alkyl group with a carbon chain length of 4, X - for Cl - ) into the beaker; then measure 5ml of n-heptane and 25ml of hexanol with a graduated cylinder and add it to a 50ml beaker, stir evenly to obtain a slightly yellow and clear A solution;
[0046] Measure 0.1ml of sodium hydroxide solution (0.5mol / L) with a pipette gun in a 50ml beaker, weigh 0.375g of the above-mentioned ionic liquid, measure 3.3ml of n-heptane and 1.7ml of hexanol with a graduated cylinder and add them to a 50ml beaker, Stir evenly to obtain a slightly yellow and clear B solution;
[0047] Then mix A solution and B solution evenly, and stir for 30 minutes ...
Embodiment 2
[0055] R in Example 1 1 Changed to R for a straight-chain alkyl group with a carbon chain length of 4 1 It is a linear alkyl group with a carbon chain length of 10, and all the other steps are the same as in Example 1. The obtained core-shell type cerium gold catalyst is used in the reaction system of one-step oxidative esterification of aldehydes to form esters, the conversion rate of methacrolein is 98.4%, and the selectivity of methyl methacrylate is 98.1%.
Embodiment 3
[0057] R in Example 1 1 Changed to R for a straight-chain alkyl group with a carbon chain length of 4 1 It is a straight-chain alkyl group whose carbon chain length is 14, and all the other steps are the same as in Example 1. The obtained core-shell type cerium gold catalyst is used in the reaction system of one-step oxidative esterification of aldehydes into esters, the conversion rate of methacrolein is 98.8%, and the selectivity of methyl methacrylate is 98.7%.
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