Method for analyzing molecular weight of each component in polymer compound and analysis system used in analysis method
An analysis method and analysis system technology, applied in the analysis of the molecular weight of each component in a polymer compound and the analysis system field used for the analysis
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[0081] In this example, the molecular weight of the unit polymer contained in the sample was measured by an online SEC and Py-GC / MS analysis system.
[0082] First, based on the chromatogram obtained by injecting the sample into a size exclusion chromatography (SEC) (see figure 1 ) to specify the collection range (see figure 2 ). Samples were automatically collected at 30 second intervals by a PAL RTC from CTC Analytics (Switzerland) and injected directly into a pyrolysis gas chromatograph-mass spectrometer (Py-GC / MS) to obtain a mass spectrum for each collected sample. Based on MMA and styrene (PS) as the monomers of the samples, mass spectral data of 100 mass / charge (m / z) and 104 mass / charge (m / z) were extracted (see Figure 3a and Figure 3b ).
[0083] The sum of the areas from the heights of the respective peaks of the mass spectrum was set to 100, and the monomer content ratio was set to 50:50 as the monomer content ratio of the standard. The relative content ratio...
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