Conductive carbon paper and preparation method thereof

A conductive carbon and conductive technology, applied in the field of conductive carbon paper and its preparation, can solve the problems of poor catalyst layer bonding and rough surface of carbon paper, etc., and achieve high air distribution, high conductivity, and high gas diffusivity Effect

Active Publication Date: 2020-08-25
SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, in traditional electrode substrates, in order to improve the gas transport performance, the porosity o...

Method used

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  • Conductive carbon paper and preparation method thereof
  • Conductive carbon paper and preparation method thereof
  • Conductive carbon paper and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0032] A conductive carbon paper, the conductive carbon paper is composed of 2-10 layers of single-layer carbon fiber paper with a porosity of 10-80%, wherein the porosity of the single-layer carbon fiber paper on the outermost side is denoted as A, and the other side is The porosity of the outermost single-layer carbon fiber paper is recorded as B, where the units of A and B are %, and the total thickness of the conductive carbon paper is recorded as L, where the unit of L is μm. The three must meet the following relationship: 0.2≤│A-B │ / L≤0.8.

[0033] The conductive carbon paper is an asymmetric porous structure carbon paper, the side of the conductive carbon paper with high porosity is used to contact the bipolar plate, and the side with low porosity is used to contact the catalyst layer and has a microporous layer. The carbon papers are arranged in order of porosity from small to large or from large to small.

[0034] A preparation method of conductive carbon paper, com...

Embodiment 2~10

[0041] A conductive carbon paper, the conductive carbon paper is composed of 2-10 layers of single-layer carbon fiber paper with a porosity of 10-80%, wherein the porosity of the single-layer carbon fiber paper on the outermost side is denoted as A, and the other side is The porosity of the outermost single-layer carbon fiber paper is recorded as B, where the units of A and B are %, and the total thickness of the conductive carbon paper is recorded as L, where the unit of L is μm. The three must meet the following relationship: 0.2≤│A-B │ / L≤0.8.

[0042] The conductive carbon paper is an asymmetric porous structure carbon paper, the side of the conductive carbon paper with high porosity is used to contact the bipolar plate, and the side with low porosity is used to contact the catalyst layer and has a microporous layer. The carbon papers are arranged in order of porosity from small to large or from large to small.

[0043] A preparation method of conductive carbon paper, cha...

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Abstract

The invention belongs to the technical field of conductive material preparation methods, and particularly relates to conductive carbon paper and a preparation method thereof. The conductive carbon paper is composed of 2-10 layers of single-layer carbon fiber paper with porosity of 10-80%, wherein the porosity of the single-layer carbon fiber paper on the outermost side is denoted as A, the porosity of the single-layer carbon fiber paper on the outermost side of the other side is denoted as B, the unit of A and B is%, the total thickness of the conductive carbon paper is denoted as L, the unitof L is [mu] m, and the three should meet the following relationship: 0.2 < = | A-B |/L < = 0.8. A mixture containing a dispersing agent, chopped carbon fibers and carbon nanofibers is put into waterand pulped to uniformly disperse the carbon fibers and the carbon nanofibers to form a suspension; the suspension is manufactured by adopting a conventional wet papermaking technology to form carbon fiber base paper and soaked in a binder, dried, and carbonized to obtain the conductive carbon paper.

Description

technical field [0001] The invention belongs to the technical field of preparation methods of conductive materials, and in particular relates to a conductive carbon paper and a preparation method thereof. Background technique [0002] The gas diffusion layer of a proton exchange membrane hydrogen fuel cell needs to have functions such as current collection, gas transmission, and gas distribution. Therefore, the carbon fiber paper layer material constituting the gas diffusion layer is required to have properties such as high electrical conductivity, high gas diffusibility, and high gas distribution property at the same time. [0003] As carbon paper for the gas diffusion layer of a proton exchange membrane fuel cell, Japanese Laid-Open Patent No. 6-20710 discloses that chopped carbon fibers are randomly dispersed to form carbon fiber paper, and then combined with carbon materials to form a porous structure. Carbon fiber paper material. However, it is difficult for the carbo...

Claims

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Application Information

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IPC IPC(8): D21H13/50D21H15/02D21H21/08D21H21/14D21H25/06D21H17/35D21H19/38D21H19/56D21H17/26D21H17/14D21H17/37D21H17/36D21H17/56D21H17/11D21H17/53D21H17/06D21H17/07D21H17/48D21H17/24D21H17/61D21H17/51D21H17/34D21H17/47C04B35/83C04B35/532H01M8/0234H01M4/88D21H27/30B32B29/00
CPCB32B29/005C04B35/532C04B35/83C04B2235/5248C04B2235/526C04B2235/5264C04B2235/602C04B2235/656C04B2235/6567C04B2235/658C04B2235/94C04B2235/95D21H13/50D21H15/02D21H17/06D21H17/07D21H17/11D21H17/14D21H17/24D21H17/26D21H17/34D21H17/35D21H17/36D21H17/37D21H17/47D21H17/48D21H17/51D21H17/53D21H17/56D21H17/61D21H19/38D21H19/56D21H21/08D21H21/14D21H25/06D21H27/30H01M4/8807H01M8/0234Y02E60/50Y02P70/50
Inventor 吴刚平刘玉婷
Owner SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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