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Phase change material and preparation method and application thereof

A technology of phase change energy storage materials and substrates, applied in heat exchange materials, chemical instruments and methods, etc., can solve problems such as reducing heat transfer efficiency, increasing production costs, increasing heat transfer medium and phase change material thermal resistance, etc. , to achieve the effect of wide application range, high phase transition enthalpy and moderate phase transition temperature

Inactive Publication Date: 2020-10-16
安徽星贝达新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the solid-liquid phase change material has high phase change enthalpy, moderate phase change temperature, and has high use value; but a single solid-liquid phase change material has a liquid phase during the phase change process. , and most of them are corrosive, and must be packaged in a special container, which will not only increase the thermal resistance between the heat transfer medium and the phase change material, reduce the heat transfer efficiency, but also greatly increase the production cost

Method used

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  • Phase change material and preparation method and application thereof
  • Phase change material and preparation method and application thereof
  • Phase change material and preparation method and application thereof

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preparation example Construction

[0096] In the present invention, the preparation method of the foam carrier comprises the following steps: thoroughly mixing the base material, foaming agent, modifier, lubricant, nucleating agent and other auxiliary agents, and then adding them into an extruder for Melting and blending, extruding, cooling and granulating to obtain primary particles of the foaming carrier; and then foaming the primary particles of the foaming carrier to obtain the product.

[0097] A second aspect of the present invention provides a method for preparing the phase change energy storage material, comprising the following steps:

[0098] (1) The foaming carrier is placed in a stirring device for heating and stirring;

[0099] (2) Paraffin wax is heated and converted into liquid paraffin;

[0100] (3) Add the liquid paraffin obtained in step (2) directly into the stirring device of step (1), and stir for 1-3 hours under the condition that the temperature is not higher than 200° C., to obtain the ...

Embodiment 1

[0107] Embodiment 1 provides a phase change energy storage material, and the preparation raw materials of the phase change energy storage material include foam carrier and paraffin.

[0108] The raw materials for the preparation of the foam carrier, in parts by weight, include: 140 parts of substrate, 30 parts of foaming agent, 20 parts of modifier, 5 parts of lubricant, 4 parts of nucleating agent, and 2 parts of other auxiliary agents; The substrate is a mixture of polypropylene, acrylonitrile-butadiene-styrene copolymer and ethylene-butyl acrylate copolymer in a weight ratio of 1:0.2:0.4; the melt flow rate of the polypropylene is 3.1 g / 10min, purchased from Yuyao Yingcang Plastic Chemical Co., Ltd., brand T30S; the melt flow rate of the acrylonitrile-butadiene-styrene copolymer is 4.6g / 10min of acrylonitrile-butadiene-styrene Ethylene copolymer, purchased from Haosheng Plastic Raw Material Management Department, Zhangmutou, Dongguan City, brand D-1000; the source of the bu...

Embodiment 2

[0114] Embodiment 2 provides a phase change energy storage material, and the preparation raw materials of the phase change energy storage material include foam carrier and paraffin.

[0115] The raw materials for the preparation of the foam carrier, in parts by weight, include: 100 parts of substrate, 10 parts of foaming agent, 5 parts of modifier, 1 part of lubricant, 1 part of nucleating agent, and 1 part of other auxiliary agents; The substrate is a mixture of polypropylene, acrylonitrile-butadiene-styrene copolymer and ethylene-butyl acrylate copolymer in a weight ratio of 1:0.2:0.4; the melt flow rate of the polypropylene is 3.1 g / 10min, purchased from Yuyao Yingcang Plastic Chemical Co., Ltd., brand T30S; the melt flow rate of the acrylonitrile-butadiene-styrene copolymer is 4.6g / 10min of acrylonitrile-butadiene-styrene Ethylene copolymer, purchased from Haosheng Plastic Raw Material Management Department, Zhangmutou, Dongguan City, brand D-1000; the source of the butene...

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Abstract

The invention relates to the technical field of materials, in particular to a phase change material and a preparation method and application thereof. The phase change material is prepared from the following raw materials: a foaming carrier and paraffin, and the foaming carrier comprises the following raw materials in parts by weight: 100-150 parts of a base material, 10-40 parts of a foaming agent, 5-30 parts of a modifier, 1-8 parts of a lubricant, 1-10 parts of a nucleating agent and 1-5 parts of other aids. A self-made high-performance porous foaming carrier is used for adsorbing a phase-change material (paraffin) which is heated to be higher than a melting point, and the adsorption capacity of the carrier on paraffin is high and can reach 70%; and the provided phase change material shows a solid-solid phase change characteristic in a phase change process, and is high in phase change enthalpy, moderate in phase change temperature and wide in application range.

Description

technical field [0001] The invention relates to the field of material technology, in particular to a phase change energy storage material and its preparation method and application. Background technique [0002] Phase change materials (PCMs) are substances that use the massive endothermic and exothermic effects of certain substances during the phase transition process for energy storage and temperature regulation. There are many kinds of phase change materials, and more than 6,000 PCMs have been discovered. According to the properties of phase change materials, they can generally be divided into two categories: inorganic compounds and organic compounds. Inorganic phase change materials mainly include crystalline hydrated salts, molten salts, and metal alloys. Organic phase change materials mainly include organic substances such as paraffin wax and polyethylene glycol (PEG). Among them, the solid-liquid phase change material has high phase change enthalpy, moderate phase c...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L55/02C08L23/08C08L23/16C08L91/06C08L25/06C08L63/10C08J9/12C08J9/42C09K5/02
CPCC08J9/0061C08J9/122C08J9/42C08J2203/06C08J2323/12C08J2423/08C08J2423/16C08J2425/06C08J2455/02C08J2463/10C08J2491/06C09K5/02
Inventor 张乃斌
Owner 安徽星贝达新材料科技有限公司