Mass analyzer including an ion source and a reaction cell and systems and methods using them
A mass analyzer and reaction cell technology, applied in the field of ion sources, can solve problems such as lack of flexibility
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Embodiment 1
[0054] A sample comprising argon and volatile organic compounds may be introduced into chamber 316 through chamber inlet 340 of mass analyzer 300 . Depending on the voltage and pressure used, the source can provide either intact molecular ions or fragment ions to the downstream reaction cell 370 .
Embodiment 2
[0056] In another mode of operating the mass analyzer, argon itself (eg, through chamber inlet 340 ) can be provided to chamber 316 without any analyte. The generated argon ion beam having an energy distribution of about 12 eV may be directed into reaction cell 370 . The analyte vapor can then be introduced (eg, through inlet 364 ) into the reaction cell at a pressure of 5 to 10 mTorr. Analyte molecules with ionization potentials below 12eV upon collision with argon ions are ionized and remain as intact molecular ions. These ions can be mass separated using a downstream quadrupole mass filter or other mass filter.
Embodiment 3
[0058] A similar setup to that used in Example 2 may be used, but with additional excitation of the argon ions prior to providing them to the downstream reaction cell 370 . The argon ions can be excited to about 40 eV energy before entering the reaction cell 370 where they collide with sample molecules.
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