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Lead-acid storage battery positive electrode lead plaster preparation method

A technology of lead-acid batteries and positive electrode paste, applied in the direction of lead-acid batteries, electrode manufacturing, battery electrodes, etc., can solve the problems of poor operability, difficult to control the size and content of 4BS crystals, etc. Production implementation, the effect of saving energy consumption

Inactive Publication Date: 2021-02-12
CHAOWEI POWER CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The present invention aims at overcoming the problem that the crystal size and content of 4BS in the lead paste of the prior art are difficult to control and has poor operability, and provides a method for preparing the positive electrode lead paste of a lead-acid battery, which is carried out by adding lead powder twice, In the case of ensuring the effect of the lead paste formula, a certain amount of 4BS can be effectively obtained; steam heating and stirring is used to control the temperature, the speed and time of the paste machine to ensure the uniformity and content of 4BS; the curing stage saves energy and can get more and uniform 4BS

Method used

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  • Lead-acid storage battery positive electrode lead plaster preparation method

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Effect test

Embodiment 1

[0045] A kind of lead-acid storage battery cathode lead paste and preparation method, comprise following preparation steps:

[0046] (1) The first step: combine the part lead powder accounting for 60% of the total lead powder weight with the short fiber (the length of the short fiber is 4mm) accounting for 0.15% of the total lead powder weight, the graphite accounting for 0.3% of the total lead powder weight and the The red lead of 2.5% of total lead powder weight is mixed evenly, then 40s add the pure water that accounts for 14.5% of total lead powder weight, wet mix 18min after adding water, add the sulfuric acid that accounts for total lead powder weight 8% again (the density of sulfuric acid is 1.5g / cm 3 ) for acid mixing, the acid mixing time is 40 minutes to form a semi-suspension slurry, after the acid addition is completed, 90°C high-temperature steam is introduced to heat the semi-suspension slurry and stir for 25 minutes to obtain slurry A;

[0047] (2) The second ...

Embodiment 2

[0050] A kind of lead-acid storage battery cathode lead paste and preparation method, comprise following preparation steps:

[0051] (1) The first step: combine the part lead powder accounting for 40% of the total lead powder weight with the short fiber (the length of the short fiber is 6mm) accounting for 0.05% of the total lead powder weight, the graphite accounting for 0.1% of the total lead powder weight and the Mix the red lead with 5% of the total lead powder weight evenly, then add 13.5% pure water accounting for the total lead powder weight for 20 seconds, wet mix for 5 minutes after adding water, then add 10% sulfuric acid (the density of sulfuric acid is 1.4g) / cm 3 ) for acid mixing, and the acid mixing time is 15 minutes to form a semi-suspension slurry. After the addition of acid, high-temperature steam at 80° C. is introduced to heat the semi-suspension slurry and stir for 30 minutes to obtain slurry A;

[0052] (2) The second step: the oxide of antimony account...

Embodiment 3

[0055] A kind of lead-acid storage battery cathode lead paste and preparation method, comprise following preparation steps:

[0056] (1) The first step: combine the part lead powder accounting for 80% of the total lead powder weight with the short fiber (the length of the short fiber is 4mm) accounting for 0.05% of the total lead powder weight, the graphite accounting for 0.4% of the total lead powder weight and the Mix the red lead with 5% of the total lead powder weight evenly, then add 16% pure water accounting for the total lead powder weight for 20 seconds, wet mix for 5 minutes after adding water, then add 10% sulfuric acid (the density of sulfuric acid is 1.4g) / cm 3 ) for acid mixing, the acid mixing time is 60min to form a semi-suspension slurry, after the acid addition is completed, 80°C high-temperature steam is introduced to heat the semi-suspension slurry and stir for 30min to obtain slurry A;

[0057] (2) The second step: the oxide of antimony accounting for 0.1...

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Abstract

The invention relates to the technical field of lead-acid storage batteries, and discloses a lead-acid storage battery positive electrode lead plaster preparation method in order to solve the problemsof difficult control of the crystal size and content of 4BS in the lead plaster and poor operability in the prior art. The preparation method comprises the preparation steps of uniformly mixing partof lead powder with short fibers, graphite and red lead, adding pure water for wet mixing, adding sulfuric acid for acid mixing to form semi-suspended slurry, introducing high-temperature steam for heating and stirring the semi-suspended slurry after acid adding is completed, and obtaining slurry A; adding antimony oxide, bismuth oxide, zinc oxide and a salt additive into the slurry A, and uniformly stirring to obtain slurry B; and gradually adding the remaining lead powder into the slurry B in a mode of adding while stirring to obtain uniformly mixed paste. The material strength of the polarplate and the cycle life of the battery can be improved, and the service life of the battery is prolonged; and the method has few changes on the existing lead plaster mixing process, and is high in operability and convenient to produce and implement.

Description

technical field [0001] The invention relates to the technical field of lead-acid batteries, in particular to a positive lead paste for lead-acid batteries and a preparation method thereof. Background technique [0002] Valve-regulated sealed lead-acid battery is the current mainstream lead-acid battery product. Based on battery performance and environmental friendliness requirements, this type of battery generally adopts paste-type plates, and the positive grid generally uses lead-calcium alloys. Usually, the early failure modes of this type of battery are the resistance effect (also known as "antimony-free effect" or PCL-1) and the softening of the positive active material body (PCL-2) that occur at the positive grid interface. In order to overcome the "antimony-free effect" and improve the bonding performance between the grid interface and the active material, on the one hand, Sn elements can be added to the lead-calcium alloy, and on the other hand, Sn, Sb, Bi and other e...

Claims

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Application Information

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IPC IPC(8): H01M4/04H01M4/57H01M4/62H01M10/06
CPCH01M4/04H01M4/57H01M4/628H01M10/06Y02E60/10
Inventor 黄伟国陈理周志学陈幸刘孝伟
Owner CHAOWEI POWER CO LTD