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Copper salt alkalescent electroplating solution for PCB hole metallization and application of copper salt alkalescent electroplating solution

A hole metallization and weak alkaline technology, which is applied in the fields of electrical components, printed circuits, printed circuit manufacturing, etc., can solve the problems of strong dependence on additives and difficult control, and achieve high dispersion ability of plating solution, high current efficiency, The effect of improving stability

Pending Publication Date: 2021-06-11
XIAMEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The dispersing ability of the plating solution in the acidic sulfate copper plating process is highly dependent on additives, and the plating solution contains a variety of additives. It is difficult to control the synergistic effect of the mixture of various additives in the PCB acidic copper plating solution

Method used

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  • Copper salt alkalescent electroplating solution for PCB hole metallization and application of copper salt alkalescent electroplating solution
  • Copper salt alkalescent electroplating solution for PCB hole metallization and application of copper salt alkalescent electroplating solution
  • Copper salt alkalescent electroplating solution for PCB hole metallization and application of copper salt alkalescent electroplating solution

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Effect test

Embodiment 1

[0039] The specific preparation process of copper salt weak alkaline electroplating solution for PCB hole metallization is as follows (take the preparation of 1L as an example):

[0040] (1) Accurately weigh the main complexing agent and the auxiliary complexing agent, dissolve them in 400mL deionized water, then add and dissolve copper salts with an accurately weighed mass of 5-20g to obtain solution A;

[0041] (2) Accurately weigh the pH buffer and dissolve it in 200mL deionized water to obtain solution B;

[0042] (3) Accurately weigh leveling agent, dissolve in 100mL deionized water, obtain solution C;

[0043] (4) Accurately weigh the monovalent copper reduction accelerator and the polyalcohol compound, dissolve them in 200mL deionized water, and obtain solution D;

[0044] (4) Add solutions B, C, and D to solution A, and adjust the pH value in the range of 8.0-10.0 with water, and simultaneously set the volume to 1 L to obtain the copper salt weakly alkaline electropla...

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Abstract

The invention discloses a copper salt alkalescent electroplating solution for PCB hole metallization and application of the copper salt alkalescent electroplating solution. The pH is 8-10, the copper salt alkalescent electroplating solution is composed of copper salt, a main coordination agent, an auxiliary coordination agent, a pH buffer agent, a uniform plating agent and an induction activator, the mass concentration of the copper salt is 5-20 g / L, and the uniform plating agent is composed of a selenium compound and a salt compound. The induction activator is composed of a cuprous reduction accelerator and a polyalcohol compound. The copper salt alkalescent electroplating solution is stable, low in total concentration of the solution and high in dispersing capacity; and the current efficiency is high, under the specified electroplating condition, obtained copper layer particles are fine and compact, the dispersion capacity value (TP) is high, and electroplating uniform thickening of PCB through holes can be achieved.

Description

technical field [0001] The invention belongs to the technical field of electronic electroplating, and in particular relates to a copper salt weakly alkaline electroplating solution for PCB hole metallization and an application thereof. Background technique [0002] The electroplating copper process is widely used in the field of electronic electroplating, such as PCB hole metallization, PCB wiring, etc. [0003] PCB is an indispensable basic component of all electronic products, known as the "mother of electronic products". With the development of electronic products towards miniaturization, light weight, intelligence and multi-function, PCB manufacturing is also required to develop towards high density, high reliability and refinement. In order to realize the rapid development of PCB, hole metallization is very important. Copper has good ductility, excellent thermal conductivity (377 / (m·K)) and high electrical conductivity (0.0172Ω·m), and is one of the ideal hole metalli...

Claims

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Application Information

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IPC IPC(8): C25D3/38C25D7/00H05K3/42
CPCC25D3/38C25D7/00H05K3/424
Inventor 詹东平李威青金磊杨家强王赵云杨防祖田中群
Owner XIAMEN UNIV
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