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Special modifier for manufactured sand cement concrete

A technology of cement concrete and modifier, applied in the field of construction, can solve the problems of lack of river sand resources, increase in cost, increase in dosage, etc., and achieve the effects of obvious reduction in viscosity, no loss in slump, and good dispersing ability.

Inactive Publication Date: 2018-05-18
ANHUI TRANSPORTATION HLDG GRP CO LTD +3
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] (1) Proper addition of river sand is helpful to improve the workability of machine-made sand concrete, but the effect is not obvious. At the same time, due to the lack of river sand resources, the cost of machine-made sand concrete is also increased
[0006] (2) Appropriate addition of fly ash can also improve the workability of machine-made sand concrete and reduce bleeding. However, due to the unstable quality of fly ash, it increases the difficulty of concrete quality control. At the same time, the excessive amount of fly ash have a detrimental effect on the strength of concrete
[0007] (3) Adding admixtures for ordinary concrete can reduce the water consumption of machine-made sand concrete, increase strength, and improve workability. However, since ordinary concrete admixtures are not specifically for machine-made sand concrete, the amount generally needs to be increased and the cost will be increased. Large, and the improvement of the workability of concrete is also limited

Method used

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  • Special modifier for manufactured sand cement concrete
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Preparation of special modifier for machine-made sand cement concrete

[0021] Add 4kg of methacrylic acid, 10kg of polyethylene glycol monoacrylate, and 6kg of sodium methacrylic sulfonate into water to prepare a mixed aqueous solution with a concentration of 25%, and add 0.5kg of 1.5% supernatant to the mixed aqueous solution. Oxidize the tert-butyl benzoate solution, then react at a temperature of 70°C for 8 hours to obtain a reaction solution, and finally adjust the pH value of the reaction solution to 7 with 10% NaOH aqueous solution to obtain the special modifier for machine-made sand cement concrete .

Embodiment 2

[0023] Preparation of special modifier for machine-made sand cement concrete

[0024] Add 7kg of methacrylic acid, 18kg of polyethylene glycol monoacrylate, and 11kg of sodium methacryl sulfonate into water to prepare a mixed aqueous solution with a concentration of 26%, and add 1.3kg of 1.5% supernatant to the mixed aqueous solution. Oxidize the tert-butyl benzoate solution, then react at 75°C for 7 hours to obtain a reaction solution, and finally adjust the pH value of the reaction solution to 7.5 with 10% NaOH aqueous solution to obtain the special modifier for machine-made sand cement concrete .

Embodiment 3

[0026] Preparation of special modifier for machine-made sand cement concrete

[0027] Add 10kg of methacrylic acid, 26kg of polyethylene glycol monoacrylate, and 15kg of sodium methacrylate into water to prepare a mixed aqueous solution with a concentration of 28%, and add 2kg of peroxide with a concentration of 1.5% to the mixed aqueous solution. The tert-butyl benzoate solution was then reacted at 80° C. for 6 hours to obtain a reaction solution, and finally the pH value of the reaction solution was adjusted to 8 with 10% NaOH aqueous solution to obtain the special modifier for machine-made sand cement concrete.

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Abstract

The invention discloses a special modifier for manufactured sand cement concrete. The preparation method of the special modifier comprises the following steps: jointly adding any one of methacrylic acid and methyl acrylate, as well as acrylic polyethylene glycol monoester and sodium methallyl sulfonate into water, so as to form a mixed water solution, adding tert-butyl peroxybenzoate into the mixed water solution, then performing reaction at 70 to 80 DEG C, so as to obtain a reaction liquid, finally adjusting the pH value of the reaction liquid to be 7 to 8, so as to form the special modifierfor manufactured sand cement concrete. The special modifier has excellent dispersive capacity and good workability, when the mixing amount is 0.2 percent (solid), the performance of the special modifier is better than or equal to market additives with the mixing amount of 0.25 percent, the workability of the manufactured sand concrete can be obviously improved, formed manufactured sand cement concrete does not have the phenomenon of bleeding and dissociation, the slump within 60min is basically not damaged, the viscosity of concrete is obviously reduced, the strength of the manufactured sand concrete can be improved by 5 to 10 percent, and the water reducing rate reaches greater than 25 percent.

Description

technical field [0001] The invention relates to the field of building construction, in particular to a special modifier for machine-made sand cement concrete. Background technique [0002] The construction of mountainous tunnels and bridge structures requires the use of a large amount of sand and gravel resources, but with the depletion of natural sand resources and the needs of environmental protection, it has become an inevitable trend for machine-made sand to replace river sand as concrete fine aggregate. Provinces have also begun to use machine-made sand to mix cement concrete. [0003] However, due to the sharp edges and corners of the machine-made sand, the particle gradation is poor, and there are too many particles larger than 2.5mm and smaller than 0.075mm. It is easy to cause defects in the appearance quality of concrete. [0004] The current solution is mainly to improve the workability of machine-made sand cement concrete by properly adding river sand, fly ash,...

Claims

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Application Information

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IPC IPC(8): C08F283/06C08F220/06C08F220/14C08F228/02C04B24/16C04B103/30
CPCC04B24/165C04B2103/302C08F283/065C08F220/06C08F220/14C08F228/02
Inventor 黄学文吴林松何玉柒杨晓明雷进严二虎常嵘宋树贵张生
Owner ANHUI TRANSPORTATION HLDG GRP CO LTD
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