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Multilayer ceramic capacitor

A technology of ceramic capacitors and laminates, which is applied in the direction of laminated capacitors, capacitors, fixed capacitors, etc., can solve the problems of laminated ceramic capacitors such as the decline in moisture resistance reliability, and achieve the effect of suppressing the decline in moisture resistance reliability

Active Publication Date: 2021-06-18
MURATA MFG CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0011] However, it has been found that when the multilayer ceramic capacitor described in Patent Document 1 is mounted using solder, the multilayer ceramic capacitor is corroded, causing a problem that the reliability of moisture resistance is lowered.

Method used

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  • Multilayer ceramic capacitor
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  • Multilayer ceramic capacitor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0176] to have figure 2 Multilayer ceramic capacitors with external electrodes of the configuration shown (E B1 / E A1 =0,E B2 / E A2 = 0) as an object, the monolithic laminated ceramic capacitor was fixed to the support body of the foam release sheet, and then the silane coupling agent treatment of immersing in the silane coupling agent solution was performed. By controlling the type and concentration of the silane coupling agent, and the number of dips in the silane coupling agent solution, samples having various silane coupling agent concentrations on the mounting surface and the opposing surface as shown in Table 1 were produced.

Embodiment 2

[0178] to have Figure 4 Multilayer ceramic capacitors with external electrodes of the configuration shown (E B1 / E A1 =0,E B2 / E A2 = 0) as an object, the monolithic laminated ceramic capacitor was fixed to the support body of the foam release sheet, and then the silane coupling agent treatment of immersing in the silane coupling agent solution was performed. By controlling the type and concentration of the silane coupling agent, and the number of dips in the silane coupling agent solution, samples having various silane coupling agent concentrations on the mounting surface and the opposing surface as shown in Table 2 were prepared.

[0179] As a representative example of fluorine-based silane coupling agent, CF 3 (CF 2 ) 5 (CH 2 ) 2 Si(OCH 3 ) 3 (in Table 1, expressed as fluorine-based 1 (F5)) and CF 3 (CF 2 ) 4 CONH(CH 2 ) 3 Si(OCH 3 ) 3 (In Table 1, it is represented as fluorine-based 2 (F4)). In addition, as a representative example of a carbon-based sila...

Embodiment 3

[0196] [Evaluation of electrical connectivity with land]

[0197] Use with E B1 / E A1 and E B2 / E A2 Multilayer ceramic capacitors with an electrode structure of 0, 0.5, or 1 were solder-mounted and solder-mounted, and the electrical connectivity between the land and the capacitor was compared. The number of samples to be evaluated was set to 100, and electrical connectivity was confirmed by capacitance measurement. The results are shown in Table 3.

[0198] [table 3]

[0199]

[0200] As shown in Table 3, at E B1 / E A1 and E B2 / E A2 In the area exceeding 0.5, a part of poor connection was confirmed by solder mounting. According to the section observation, it can be considered that the cause is "tombstone". On the other hand, in E B1 / E A1 and E B2 / E A2 In the area where the value is 0.5 or less, the generation of "tombstone" was not confirmed, and the connection failure was not confirmed.

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Abstract

The present invention provides a multilayer ceramic capacitor that suppresses degradation of moisture resistance reliability caused by solder mounting. The multilayer ceramic capacitor includes a laminate including dielectric layers and internal electrode layers, and external electrodes on surfaces of the laminate. A silane coupling agent layer is on at least a mounting surface among surfaces of the laminate. The silane coupling agent layer is made of a fluorine-based silane coupling agent, and a silane coupling agent concentration on the mounting surface is about 0.1 or higher and about 365 or lower and is higher than a silane coupling agent concentration on a counter surface opposing the mounting surface, or the silane coupling agent layer is made of a carbon-based silane coupling agent, and a silane coupling agent concentration on the mounting surface is about 0.91 or higher and about 38.10 or lower and is higher than a silane coupling agent concentration on a counter surface opposing the mounting surface.

Description

technical field [0001] The present invention relates to laminated ceramic capacitors. Background technique [0002] In recent years, miniaturization and thinning of electronic devices such as mobile phones and portable music players are progressing. Many multilayer ceramic electronic components such as multilayer ceramic capacitors are mounted on electronic equipment. Along with the miniaturization of electronic equipment, the miniaturization of multilayer ceramic electronic components built in substrates or mounted on the surface of substrates and mounted on electronic equipment is also gradually developing. Thinning. Accompanying the thinning of such multilayer ceramic electronic components, securing the strength of the multilayer ceramic electronic components has become an issue. [0003] Patent Document 1 discloses a multilayer ceramic electronic component including a ceramic body, a first external electrode, and a second external electrode as a low-profile multilayer ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G4/30H01G4/224
CPCH01G4/30H01G4/224H01G2/065H01G4/012H01G4/1218H01G4/232H01G4/12H05K3/3442H05K3/3489H05K2201/10015H01G4/008
Inventor 中野贤村松谕北条梨沙野村善行
Owner MURATA MFG CO LTD