Methods of extraction of products from titanium-bearing materials
A technology of perovskite and titanyl sulfate, applied in chemical instruments and methods, titanium compounds, titanium dioxide, etc., can solve the problems of using highly toxic gases and high temperatures
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Embodiment 1
[0346] Such as figure 1 As shown, this example describes one embodiment of the method of the present invention. Slag is prepared by grinding to the desired particle size. The slag and sulfuric acid are fed to a continuous reactor suitable for continuous mixing of slag, sulfuric acid and the formed sulfuric acid filter cake. The slag and sulfuric acid are mixed and fed to the reactor at a rate sufficient to effect the sulfation of titanium, magnesium, aluminum and calcium and other minor species present in the slag feedstock. The sulfated filter cake exits the reactor and is fed to a leaching step where it is contacted with water or dilute acid to produce a solid and liquid phase which are separated, preferably by filtration. The solid phase is recovered as calcium sulphate and silica and the liquid leach phase is fed to the titanium hydrolysis step. In the hydrolysis step, the TiO 2 The nuclei are contacted with the liquid leach solution in a suitable container at a suita...
Embodiment 2
[0348] This embodiment describes an embodiment of the preferred method of the invention, such as figure 2 shown. Slag is prepared by grinding to the desired particle size. The slag and sulfuric acid are fed into a continuous reactor adapted for continuous mixing of slag, sulfuric acid and the formed sulphated filter cake. The slag and sulfuric acid are mixed and fed through the reactor at a rate sufficient to effect the sulfation of titanium, magnesium, aluminum and calcium and other minor species present in the slag feedstock. The sulfated filter cake exits the reactor and is fed to a leaching step where it is contacted with water or dilute acid to produce a solid and liquid phase which are separated, preferably by filtration. The solid phase is recovered as calcium sulphate and silica and the liquid leach phase is fed to the titanium hydrolysis step. In the hydrolysis step, the TiO 2 The nuclei are contacted with the liquid leach solution in a suitable vessel at a suita...
Embodiment 3
[0351] Example 3 - New Zealand Steel Slag
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Abstract
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