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Magnetic field enhanced capacitive deionization continuous water purification device and method thereof

A capacitive deionization and water purification device technology, applied in the fields of magnetic field/electric field water/sewage treatment, chemical instruments and methods, water/sewage treatment, etc., can solve the problem of difficult desorption of adsorbed ions, high cost of electrodes, and the need for periodic replacement To achieve the effect of strengthening ion adsorption effect, improving adsorption efficiency and adsorption thickness

Pending Publication Date: 2021-08-20
XIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to overcome the above-mentioned deficiencies in the prior art, the object of the present invention is to provide a method for continuous water purification (MECDI) of magnetic field-enhanced capacitive deionization, which uses a wheel model or a waterwheel model to periodically load the electric field on the electrode plate to realize waste water purification. The adsorption process of positive and negative ions and the desorption process of adsorbed ions solve the problem of periodic replacement of electrodes in the existing CDI technology due to ion adsorption saturation on the electrode surface, ensuring the reliability of the continuous water treatment process; using the principle of magnetic field enhancement , using a closed magnetic field (magnetic field line) to constrain the ion movement space on the electrode surface, thereby realizing the effective adsorption of ions on the electrode surface, and solving the problems of high electrode cost and difficult desorption of adsorbed ions caused by the existing CDI technology relying on the high specific surface area of ​​the electrode

Method used

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  • Magnetic field enhanced capacitive deionization continuous water purification device and method thereof
  • Magnetic field enhanced capacitive deionization continuous water purification device and method thereof
  • Magnetic field enhanced capacitive deionization continuous water purification device and method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] Sample collection The circulating water treatment sample of the heating pipeline of a thermal power plant, its main ion composition and the pH and conductivity data of the wastewater are shown in the table.

[0054]

[0055] The amount of waste water sample used in the experiment is 2L, and the MECDI water treatment experimental device such as figure 2 As shown, the diameter of the rotating disk is 150mm, and 8 independent fan-shaped chambers are designed. The volume of a single chamber is about 14.4ml, and the distance between the inner and side walls of the chamber is 10mm; 16 NdFeB permanent magnets with alternating magnetic poles are evenly arranged on the outside (magnetic induction intensity B =1.2T); load voltage 1V~2V, current ≤2A; rotation speed 30rpm, wastewater injection flow (0.8~0.9)ml / sec; pH and conductivity data of treated water during MECDI water treatment process are shown in Figure 3 , as can be seen from the data curve in the figure, for the cond...

Embodiment 2

[0057] Sample collection The industrial water treatment samples of an energy company, the main ion composition and the pH and conductivity data of the wastewater are shown in the table.

[0058]

[0059] The amount of waste water sample used in the experiment is 2L, and the MECDI water treatment experimental device such as figure 2 As shown, the diameter of the rotating disk is 150mm, and 8 independent fan-shaped chambers are designed. The volume of a single chamber is about 14.4ml, and the distance between the inner and side walls of the chamber is 10mm; 16 NdFeB permanent magnets with alternating magnetic poles are evenly arranged on the outside (magnetic induction intensity B =1.2T); load voltage 1V~2V, current ≤2A; rotation speed 30rpm, wastewater injection flow (0.8~0.9)ml / sec; pH and conductivity data of treated water during MECDI water treatment process are shown in Figure 4 , has an obvious exponential change feature, with a sharp change in the early stage and a gr...

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Abstract

The invention provides a magnetic field enhanced capacitive deionization continuous water purification device, which comprises isolation chambers which are arranged in a packaging shell and insulated from each other, wherein the isolation chambers are in rolling connection with a rotary driving roller, a packaging shell fixes and supports a wastewater injection pipe to inject water into the isolation chambers, a closed magnetic field along the side wall is arranged in the isolation chamber, the packaging shell is provided with a plurality of groups of sliding contact electrodes, an elastic isolation baffle is arranged on the bottom plate of the packaging shell, and the upper end of the elastic isolation baffle makes elastic contact with the outer edge of the isolation chamber. The method comprises the following steps: injecting wastewater into an isolation chamber of an electric field loading area for ion adsorption; discharging purified water subjected to electric field adsorption treatment through a guide groove; enabling an atomization flushing mechanism to flush ions on the desorption surface, wherein the flushing solution enters a sedimentation tank; and enabling the isolation chamber to continuously rotate to enter the electric field loading area, and repeatedly performing the steps to continuously purify and treat the industrial water. According to the invention, the device has the characteristics of low energy consumption, low cost, long service life, high efficiency, no pollution, environmental protection and energy conservation.

Description

technical field [0001] The invention belongs to the technical field of environmental protection, and in particular relates to a continuous water purification method of magnetic field enhanced capacitive deionization (MECDI) for industrial water treatment. Background technique [0002] With the rapid development of my country's economy, water pollution, industrial water softening related to environmental protection, water-soluble radioactive waste, sewage from power plant circulating cooling systems, comprehensive wastewater from steel mills, papermaking wastewater, synthetic ammonia wastewater, cold rolling wastewater from steel mills and Water treatment technologies such as petrochemical refinery wastewater have received widespread attention because they involve the national economy and people's livelihood. At present, widely used water treatment technologies include ion exchange, reverse osmosis, and electrodialysis. However, these methods have limitations such as high ener...

Claims

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Application Information

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IPC IPC(8): C02F9/12
CPCC02F9/00C02F1/48C02F1/481C02F2001/007
Inventor 张卫华周少华姚大勇
Owner XIAN UNIV OF TECH
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