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Polyurethane foam stabilizer with excellent foam performance as well as preparation method and application of polyurethane foam stabilizer

A technology of polyurethane foam and stabilizer, applied in the field of polyurethane foam, can solve the problems of complex reaction and difficult grafting reaction, and achieve the effects of simple raw material structure, increased compatibility, good nucleation performance and cell opening performance

Active Publication Date: 2022-03-22
JIANGSU MAYSTA CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the polyether used is special and needs to be capped with an allyl group, and the reaction is complicated
[0005] Patent CN201810893336.3 describes a silicone foam stabilizer, using allyl-terminated polyether and silicon-hydrogen-terminated low-hydrogen silicone oil for grafting reaction , the obtained foam stabilizer has good emulsification, this invention is to improve the gas permeability of the product by increasing the molecular weight of polyether, but too high molecular weight of polyether will make the grafting reaction difficult

Method used

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  • Polyurethane foam stabilizer with excellent foam performance as well as preparation method and application of polyurethane foam stabilizer
  • Polyurethane foam stabilizer with excellent foam performance as well as preparation method and application of polyurethane foam stabilizer
  • Polyurethane foam stabilizer with excellent foam performance as well as preparation method and application of polyurethane foam stabilizer

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0039] A polyurethane foam stabilizer with excellent cell properties is obtained by mixing component A and component B.

[0040] Component A:

[0041] (1) In the 500ml round-bottomed flask that is equipped with mechanical stirrer, dry nitrogen pipeline and reflux condenser, add 185.0g the polyether that the allyl starting ester group that average molecular weight is 4000 (this polyether contains mole percentage is 50% ethyleneoxy groups), 35.0 g of an allyl starting ester-terminated polyether with an average molecular weight of 500 (this polyether contains 50 mole percent ethyleneoxy groups), 75.0 g polysilicone (MD 65 D' 5 M), 200 ppm NN-dimethylmethanolamine. Stir the mixture in a nitrogen atmosphere, raise the temperature to 85-90°C, keep warm for 0.5h, add 10ppm chloroplatinic acid, keep warm for 3h, and a clear and transparent light brown liquid is obtained. Lower the temperature to 40-60°C, add 150.0g of dipropylene glycol to obtain component A, coded as SPA1.

[00...

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Abstract

The invention relates to the technical field of polyurethane foam, in particular to a polyurethane foam stabilizer with excellent foam performance and a preparation method and application thereof.The polyurethane foam stabilizer is obtained by mixing a component A and a component B. The chemical structure of the component A is as follows: x = 60-100, y = 3-10; the general structural formula of R1 is (CH2) p (OC2H4) g (OC3H6) hOR2, p is equal to 2-4, g is equal to 10-40, and h is equal to 0-40; r2 is H,-CH3 or-C (O) CH3; the chemical structure of the component B is shown in the specification, Ra is an organic silicon chain segment, and Rb is a polyether chain segment.

Description

technical field [0001] The invention relates to the technical field of polyurethane foam, and specifically relates to a polyurethane foam stabilizer based on a silicone foam stabilizer and a preparation method thereof. Background technique [0002] Foam stabilizer is an important component in the polyurethane preparation process, which is related to the open cell ratio, cell size and distribution of polyurethane products. Application indicators such as the feel and air permeability of polyurethane soft foam. [0003] At present, when the existing foam stabilizers are used in the polyurethane foaming system, there are problems such as thick foam cells, low air permeability, and rough foam feel to varying degrees. [0004] Patent CN201510679357.1 describes a polyurethane soft foam with fine cells. The performance active agent used has a special structure. Effectively improve the polyurethane foam structure, making the cell structure of the foam more uniform and dense, and th...

Claims

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Application Information

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IPC IPC(8): C08J9/00C08J9/08C08G18/48C08G77/46C08L75/08
CPCC08J9/0061C08J9/08C08G18/48C08G77/46C08J2375/08C08J2203/02Y02E60/10
Inventor 洪满心杭帆李丰富
Owner JIANGSU MAYSTA CHEM
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