Co-Zr catalyst for Fischer-Tropsch synthesis and its prepn and application

A catalyst, Tropsch synthesis technology, applied in catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the constraints of industrial application of the Fischer-Tropsch synthesis process, the high cost of catalyst per ton of oil, and the limited life of the catalyst. and other problems, to achieve the effects of excellent reaction performance, excellent stability, and high metal dispersion.

Inactive Publication Date: 2003-02-26
SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since the supports of the above-mentioned several catalysts can chemically interact with metal cobalt to form cobalt aluminate (cobalt silicate, cobalt titanate) compounds that are difficult to reduce, when the catalyst is running in a slurry bed or in a fixed bed...

Method used

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Examples

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Embodiment Construction

[0068] (%) (wt%) g / ml / h per / 100hr comparative example 75.5 12.1 0.15 0.77 embodiment 1 64.8 8.7 0.19 0.04 embodiment 2 83.8 12.9 0.23 0.08 embodiment 3 65.6 12.8 0.14 0.06 embodiment 4 79.6 14.0.0.19 embodiment Example 5 62.5 12.8 0.13 0.06 Example 6 95.5 5.9 0.27 0.08 Example 7 43.1 7.8 0.13 0.02

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Abstract

A catalyst for Fischer-Tropsch synthesis consists of Co 10.0-80.0 wt%, zirconia 15.0-85.0 wt% and other metal oxide 0-5.0 wt%, and is prepared by the codeposition process or soaking process. The catalyst has excellent stability, high reduction degree and high metal dispersivity.

Description

[0001] Field: [0002] The invention belongs to a Fischer-Tropsch synthesis catalyst and a preparation method thereof, in particular to a cobalt-zirconium Fischer-Tropsch synthesis catalyst and a preparation method thereof Background technique: [0003] With the development of the national economy and the improvement of environmental awareness, the gap between the supply and demand of clean and high-quality diesel in my country is getting bigger and bigger. Since my country is a net importer of oil, and the cost of deep desulfurization and denitrification of refinery products is high, there are many problems in ensuring the supply of diesel oil by increasing refinery production capacity. At the same time, compared with developed countries, my country has problems such as a low utilization ratio of natural gas resources in the chemical industry and poor resource utilization efficiency. Converting natural gas into syngas and then converting it into high-quality fuel oil through...

Claims

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Application Information

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IPC IPC(8): B01J23/889B01J37/03
Inventor 孙予罕陈建刚张峻岭陶智超
Owner SHANXI INST OF COAL CHEM CHINESE ACAD OF SCI
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