Polyamide film roll and its manufactring method
A technology of polyamides and manufacturing methods, applied in the field of polyamide film rolls and its manufacture, can solve the problems of film roll shape deterioration, slippery change, wrinkling, etc., achieve excellent strength and gas barrier properties, and prevent deterioration Effect
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Embodiment 1
[0050] For sheet A formed of 97.00% by weight of nylon 6 (relative viscosity = 2.8), 3.00% by weight of silica (average particle diameter: 3.0 μm) and 96.15% by weight of nylon 6 (relative viscosity = 2.8), polyadipyl Sheet B formed by 3.00% by weight of m-xylylenedimethylamine (relative viscosity = 2.1), 0.15% by weight of ethylene bis-octadecamide, and 0.70% by weight of silica (average particle diameter: 1.8 μm) was pre-dried, respectively. As shown in Table 1, while continuously supplying 5.0% by weight of sheet A and 95.0% by weight of sheet B to the hopper directly above the extruder using a quantitative screw feeder, they were mixed in the hopper and heated at 270°C. It was melt-extruded with a uniaxial extruder, and then quenched to obtain an unstretched film with a thickness of 257 μm. The hopper has a capacity capable of holding 150 kg of raw material chips, and the discharge rate of the extruder is 450 kg per hour. In addition, the inclination angle of the hopper i...
Embodiment 2
[0053] Each raw material sheet was pre-dried separately, and 3.0 wt. The mixture was mixed in a hopper, melt-extruded with a single-screw extruder at 280° C., and quenched to obtain an unstretched film with a thickness of 180 μm. The hopper has a capacity capable of holding 100 kg of raw material chips, and the discharge rate of the extruder is 450 kg per hour. In addition, the inclination angle of the hopper is 70°.
[0054] The unstretched film was preheated at 100°C for 10 seconds, stretched 4.0 times in the transverse direction at 78°C with a tenter, and then heat-treated at 82°C for 10 seconds to continuously produce a polyamide-based film with a thickness of 45 μm. More than 1000m. The fluctuation range of the film surface temperature during continuous production of 1000m film is within the range of ±0.8°C average temperature in the preheating process, ±0.5°C average temperature in the stretching process, and ±0.5°C average temperature in the heat treatment process. T...
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