Organometallic complex and organic electroluminescent device employing the same
A technology of organic metals and complexes, applied in the direction of electroluminescent light sources, indium organic compounds, platinum group organic compounds, etc., can solve problems such as narrow range, and achieve the effect of superior luminous performance
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[0073] In the following examples, iridium complexes were prepared by Schlenk technique or glove box technique under nitrogen atmosphere excluding moisture and oxygen. Synthetic routes are shown in the following schemes in turn:
[0074] plan 1
[0075]
[0076]
[0077]
[0078] when L is , the product is a compound of formula 3 (Nico).
[0079] when L is , the product is a compound of formula 4 (Nico(Br)).
[0080] when L is , the product is a compound of formula 5 (CF3PhBen).
[0081] when L is , the product is a compound of formula 6 (CF3Nico).
[0082] (1) Preparation of compound (F 2 ppyH)
[0083] In a 500ml flask, 2M aqueous sodium carbonate solution was added to the following solution: 19.85g (1.25×10 4 mmol) 2-bromopyridine, 25.00g (1.58×10 4mmol) 2,4-difluorophenylboronic acid), 100 ml of toluene, 48 ml of ethanol and 95 ml of water, the mixture was stirred at room temperature under a nitrogen atmosphere. Then, 4.53g (3.92mmol) tetrakis (trip...
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