Direct SNP detection with unamplified DNA
A technology for detecting samples and detecting oligonucleotides, which is applied in the field of direct SNP detection using non-amplified DNA, and can solve problems such as not ideal
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Embodiment 1
[0106] One-step and two-step hybridization methods for SNP identification in non-amplified genomic DNA using nanoparticle probes
[0107] Prepared by the methods described in PCT / US97 / 12783, filed July 21, 1997, PCT / US00 / 17507, filed June 26, 2000, PCT / US01 / 01190, filed January 12, 2001 Gold nanoparticle oligonucleotide probes for the detection of target Factor II, MTHFR and Factor V sequences, which are incorporated by reference in their entirety. image 3 The use of oligonucleotide-conjugated gold nanoparticle probes for the detection of target DNA using DNA microarrays with wild-type or mutant capture probe oligonucleotides is conceptually illustrated. The oligonucleotide sequence bound to the nanoparticle is complementary to one part of the target sequence, and the capture oligonucleotide sequence bound to the glass chip is complementary to another part of the target sequence. Under hybridization conditions, the nanoparticle probe, capture probe, and target sequence bind ...
Embodiment 2
[0141] Hybridization conditions of the method of the present invention
[0142]The standard recommended protocol for efficient hybridization reactions described in the prior art (T. Maniatis, E.F. Fritsch, and J. Sambrook in "Molecular Cloning, A Laboratory Manual", Cold Spring Harbor Laboratory, 1982, p324) mainly specifies the hybridization temperature ~10-20 degrees Celsius below the Tm, which is calculated based on the selected hybridization conditions, including salt and formamide concentrations. There are different methods for calculating Tm values, each based on the exact oligonucleotide sequence and buffer conditions. For example, such calculations can be performed using computer programs, commercially available or on-line, such as HYTHER developed on the Wayne State University website. TM server. The inventor will HYTHER TM All available programs on the server were used to perform these calculations, resulting in Tm values for capture and detection probes (ie oli...
Embodiment 3
[0145] Preparation of Nanoparticle-Oligonucleotide Conjugated Probes
[0146] In this example, representative nanoparticle-oligonucleotide conjugated probe probes for PCR amplification of mec A and Tuf gene targets were prepared. Using the method described in PCT / US97 / 12783, filed July 21, 1997, PCT / US00 / 17507, filed June 26, 2000, PCT / US01 / 01190, filed January 12, 2001 Preparation of gold nanoparticle-oligonucleotide probes for detecting target mec A or Tuf gene sequences, the entirety of these documents is incorporated by reference.
[0147] (a) Preparation of gold nanoparticles
[0148] Such as Frens, 1973, Nature Phys.Sci., 241 : 20 and Grabar, 1995, Anal.Chem. 67 : 735, gold colloids (diameter 13nm) were reduced by using citrate to reduce HAuCl 4 to prepare. Briefly, all glassware is in aqua regia (3 parts HCl, 1 part HNO 3 ) and washed with Nanopure H 2 O rinse, then oven dry before use. HAuCl 4 and sodium citrate were purchased from Aldrich Chemical Company. h...
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