Carbon white in use for synthetic rubber, and preparation method

A technology of synthetic rubber and silica, which is applied in the preparation of silica for synthetic rubber, the application of silicone rubber additives, and the field of tire rubber to achieve the effect of low energy consumption

Inactive Publication Date: 2007-02-21
周玉芳 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem to be solved by the present invention is: aiming at the development trend of colored and light-colored rubber products, tires require colored or flashing rings, to replace the current situation where tires are smeared black, the present invention provides a kind of white carbon black for synthetic rubber, which is One-time synthesis of gel-free silica solves the problem of high cost and high price of foreign high-dispersion silica, which is based on the production of gel-containing products first, and then uses special chemical preparations for surface modification. Disadvantages: When white carbon black for synthetic rubber is added to the rubber compound, the mixing proceeds smoothly, the roll temperature is low, the energy consumption is reduced, the Mooney viscosity is low, the scorch time is prolonged, and the safety performance is high; secondly, due to the compatibility with rubber Good performance, no "agglomeration" phenomenon, high proportion of bonded glue, so that the amount added per 100 kg of rubber can be greatly increased, up to 85 kg of highly dispersible silica can be added, and at the same time in the glue The dispersion coefficient in the material reaches 95-100%

Method used

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specific Embodiment approach

[0035] A kind of white carbon black for synthetic rubber of the present invention, wherein contains the SiO that weight percentage is more than 90% 2 , the specific surface area of ​​silica for synthetic rubber is 150m 2 / g~380m 2 / g between.

[0036] A method for preparing white carbon black for synthetic rubber. The raw materials used include sodium silicate, concentrated sulfuric acid and water with a concentration of 90% to 99% by mass, and the method includes the following steps:

[0037] 1) First add sodium silicate in the synthesis tank, then add water to dissolve;

[0038] 2) Add sulfuric acid with a mass percentage concentration of 90 to 99% in the synthesis tank to carry out a chemical reaction, and add the stabilizer Na 2 SO 4 , adding an appropriate amount of dispersant Na 2 SO 4 , it is necessary to stir while reacting, and the stirring speed is controlled in the range of 40-200 rpm;

[0039] 3) After the chemical reaction is over, use acid to adjust the pH...

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Abstract

This invention discloses a white carbon black for synthesizing rubber. The white carbon black comprises more than 90 wt. % SiO2, and has a specific surface area of 150-380 m2 / g. When the white carbon black is used as tire rubber or silicon rubber additive, the weight ratio of the white carbon black to ruuber is (20-85): 100, while the dispersion coefficient of the white carbon black in rubber is up to 95-100%. This invention also discloses a technique for producing the white carbon black. The technique comprises dissolving, synthesizing, filtering and spraying to directly produce the white carbon black, and can lower the cost.

Description

technical field [0001] The invention relates to a white carbon black for synthetic rubber, which is widely used in tires and green tires, rubber products, latex products, silicone rubber products and special rubber products, especially as an additive for tire rubber and silicone rubber, and for synthetic rubber Preparation method of white carbon black. Background technique [0002] With the continuous progress of human society, the requirements for the environment are getting higher and higher, and the requirements for the environmental protection, safety, colorization and service life of rubber tires are also getting higher and higher. First of all, low rolling resistance and low emissions are required for rubber tires. The rolling resistance of rubber tires added with white carbon black of this product is 25-35% lower than that of ordinary (carbon black) tires, and every 5% reduction in rolling resistance can save 1% of fuel, which can save energy by 5-8%. Significantly ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K3/36C08L21/00C01B33/113
Inventor 周玉芳邱根萍
Owner 周玉芳
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