Synthesis of functionalized high vinyl rubber

Abstract

This invention is based upon the discovery that rubbery polymers having a high vinyl content and a low degree of branching can be synthesized with an initiator system that is comprised of (a) a lithium initiator selected from the group consisting of allylic lithium compounds and benzylic lithium compounds, (b) a Group I metal alkoxide, and (c) a polar modifier; wherein the molar ratio of the Group I metal alkoxide to the polar modifier is within the range of about 0.1:1 to about 10:1; and wherein the molar ratio of the Group I metal alkoxide to the lithium initiator is within the range of about 0.01:1 to about 20:1. These high vinyl polymers offer reduced levels of hysteresis and better functionalization efficiency.

Description

[0001] This patent application is a divisional of U.S. patent application Ser. No. 10 / 669,223 filed on Sep. 24, 2003 which claims the benefit of U.S. Provisional Patent Application Ser. No. 60 / 436,923, filed on Dec. 27, 2002.BACKGROUND OF THE INVENTION [0002] It is highly desirable for tires to exhibit good traction characteristics on both dry and wet surfaces. However, it has traditionally been very difficult to improve the traction characteristics of a tire without compromising its rolling resistance and tread wear. Low rolling resistance is important because good fuel economy is virtually always an important consideration. Good tread wear is also an important consideration because it is generally the most important factor in determining the life of the tire. [0003] The traction, tread wear, and rolling resistance of a tire is dependent to a large extent on the dynamic viscoelastic properties of the elastomers utilized in making the tire tread. In order to reduce the rolling resis...

AI Technical Summary

Benefits of technology

[0018] These high vinyl polymers offer reduced levels of hysteresis and better functionalization efficiency. By virtue of their lower level of hysteresis these polymers can be utilized in manufacturing tire tread compounds that exhibit lower levels of rolling resistance and can accordingly be used to improve the fuel economy of motor vehicles without compromising other desirable characteristics, such as traction and tread-wear.

Problems solved by technology

However, it has traditionally been very difficult to improve the traction characteristics of a tire without compromising its rolling resistance and tread wear.

However, such blends are not totally satisfactory for all purposes.

However, styrene is a relatively expensive monomer and the inclusion of SBR is tire tread formulations leads to increased costs.

However, using sodium t-amylate as the polymerization modifier in commercial operations where recycle is required can lead to certain problems.

These problems arise due to the fact that sodium t-amylate reacts with water to form t-amyl alcohol during steam stripping in the polymer finishing step.

Since t-amyl alcohol forms an azeotrope with hexane, it co-distills with hexane and thus contaminates the feed stream.

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