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Fe-based amorphous alloy ribbon

a technology of amorphous alloy ribbons and amorphous alloys, applied in the direction of magnetic materials, magnetic bodies, cores/yokes, etc., can solve the problems of increased core losses at high operating magnetic flux densities, poor b80/bs and insufficient mass production of fe-based amorphous alloy ribbons. , to achieve the effect of high saturation magnetic flux density, low core loss

Active Publication Date: 2006-01-05
HITACHI METALS LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0006] Accordingly, an object of the present invention is to provide an Fe-based amorphous alloy ribbon having a high saturation magnetic flux density and a low core loss, which is provided with high B80 / BS, excellent thermal stability and suppressed embrittlement by controlling a weight ratio of Si to C and the roughness of a roll-contacting surface, and by controlling the range and peak of a C-segregated layer from a free surface and a roll-contacting surface by the amount of a gas blown onto a roll. SUMMARY OF THE INVENTION

Problems solved by technology

However, the Fe-based amorphous alloy ribbons are poorer than silicon steel plates presently used mostly for magnetic cores for transformers in saturation magnetic flux density.
Even with the same saturation magnetic flux density, Fe-based amorphous alloy ribbons having low B80 / BS would have increased core losses at high operating magnetic flux densities.
However, Fe-based amorphous alloy ribbons having B80 of more than 1.55 T are not mass-produced at present.
The reason therefor is that if alloy ribbons having high saturation magnetic flux densities contain more than 81 atomic % of Fe, they cannot be mass-produced stably because of surface crystallization and thermal stability decrease.
Though these means can improve alloy's properties, the resultant ribbons are brittle, and ribbons having additives distributed uniformly cannot be produced continuously.
For these reasons, such amorphous alloy ribbons cannot be mass-produced.
In addition, embrittlement, surface crystallization and thermal stability decrease are serious problems for Fe-based amorphous alloy ribbons containing 81 atomic % or more of Fe.
Though the addition of C and P can improve saturation magnetic flux densities, the resultant ribbons are so brittle that they cannot be easily formed into transformers.

Method used

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Examples

Experimental program
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Effect test

example 1

[0030] 200 g of an alloy having a composition of Fe82Si2B14C2 was melted in a high-frequency furnace, and ejected through a nozzle of the furnace onto a copper roll rotating at 25-30 m / s while blowing a CO2 gas from rear the nozzle, to produce Fe-based amorphous alloy ribbons having various widths of 5 mm, 10 mm and 20 mm, respectively, and a thickness of 23-25 μm. Each of the Fe-based amorphous alloy ribbons had a C-segregated layer at a depth of 2 to 20 nm from the surface. The Fe-based amorphous alloy ribbons were annealed at such temperatures as to minimize a core loss, which were within a range of 300 to 400° C. With the blowing rate of a CO2 gas changed, measurement was conducted with respect to the properties of the Fe-based amorphous alloy ribbons. The results are shown in Table 1.

[0031] BS and B80 were measured on single-plate samples, and a core loss W13 / 50 at a magnetic flux density of 1.3 T and a frequency of 50 Hz, and a core loss W14 / 50 at a magnetic flux density of 1...

example 2

[0038] 200 g of alloy melts having compositions shown in Table 3 were rapidly quenched in the same manner as in Example 1 to form Fe-based amorphous alloy ribbons of 5 mm in width and 23-25 μm in thickness. The properties of each Fe-based amorphous alloy ribbon are shown in Table 3. The Fe-based amorphous alloy ribbons having high B80 can keep low core loss at high operating magnetic flux densities. Sample 8 was subjected to element analysis in a depth direction from its roll-contacting surface. The results are shown in FIG. 5. The average surface roughness Ra of Samples 7 to 22 was 0.38.

TABLE 3SampleCompositionB80BsB80 / BsNo.FeCoNiSiBC[T][T](× 100%)778.0——11.012.90.11.4611.55094.3880.0——9.010.90.11.4851.57094.6981.0——5.013.01.01.5981.61998.71082.0——2.016.00.051.6091.63298.61182.0——0.117.80.11.6251.65598.21282.0——1.016.90.11.6351.66598.21382.0——2.015.90.11.6151.64398.31482.0——1.016.01.01.6401.66198.71582.0——3.014.01.01.6381.65998.71682.0——4.013.01.01.6141.65697.51782.0——0.115.92.01...

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Abstract

An Fe-based amorphous alloy ribbon having a composition comprising FeaSibBcCd and inevitable impurities, wherein a is 76 to 83.5 atomic %, b is 12 atomic % or less, c is 8 to 18 atomic %, and d is 0.01 to 3 atomic %, the 5 concentration distribution of C measured radially from both surfaces to the inside of said Fe-based amorphous alloy ribbon having a peak within a depth of 2 to 20 nm.

Description

FIELD OF THE INVENTION [0001] The present invention relates to an Fe-based amorphous alloy ribbon having a high magnetic flux density and a low core loss, suitable for magnetic cores for transformers, motors, generators and choke coils, magnetic sensors, etc. BACKGROUND OF THE INVENTION [0002] Fe-based amorphous alloy ribbons have been attracting much attention for magnetic cores for transformers because of excellent soft magnetic properties, particularly low core loss. Particularly amorphous Fe—Si—B alloy ribbons having high saturation magnetic flux densities BS and excellent thermal stability are used for magnetic cores for transformers. However, the Fe-based amorphous alloy ribbons are poorer than silicon steel plates presently used mostly for magnetic cores for transformers in saturation magnetic flux density. Thus, development has been conducted to provide Fe-based amorphous alloy ribbons with high saturation magnetic flux densities. To increase the saturation magnetic flux den...

Claims

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Application Information

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IPC IPC(8): C22C45/02
CPCH01F1/15308H01F41/0226H01F3/04
Inventor OGAWA, YUICHINAOE, MASAMUYOSHIZAWA, YOSHIHITO
Owner HITACHI METALS LTD
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