Optical detection of planarization, breakthrough and end-point in membrane-mediated electropolishing of metal layers
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[0020]This invention is directed to optical methods and apparatuses for detecting in situ changes in the topography of a work-piece during the progress of MMEP. The optical apparatuses and methods can be used to detect in situ the point of breakthrough, where a thin metal coating is first cleared from certain areas of a substrate. The apparatuses and methods can also be used to detect in situ the end-point, where a thin metal coating has been entirely removed from raised, plateau areas on the substrate surface, prior to removal by MMEP of the metal coating from recessed areas of the substrate.
[0021]In an MMEP process, the workpiece is physically separated from the electrolyte and cathode by a charge-selective ion-conducting membrane, wherein the membrane is essentially impermeable to the electrolyte but permeable to the ions produced by anodic oxidation of the work piece. MMEP is described in co-pending applications (U.S. Ser. No. 10 / 976,897; U.S. Ser. No. 10 / 986,048; and U.S. Ser. ...
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