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Transparent thermoplastic resin pellet manufacturing method

a thermoplastic resin and manufacturing method technology, applied in the direction of mixing, transportation and packaging, rotary stirring mixers, etc., can solve the problems of difficult reduction of resin gels, severe manufacturing conditions, and large influence on product reliability, and achieve the effect of less yellowish, less gels generated, and less yellowish

Active Publication Date: 2017-09-05
IDEMITSU KOSAN CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides a method to produce a transparent thermoplastic resin pellet that contains a low amount of gels and is less yellow when molded into a sheet or film. This results in a more desirable product with improved quality.

Problems solved by technology

In particular, in the manufacture of an optical light guide plate, a change of hue of the resin constituting a substrate and a foreign matter in a substrate give an extremely large influence against the reliability of the product.
In a method of obtaining a molded substrate of a relatively small and medium sized mobile phone or the like by means of injection molding, or a method of manufacturing a sheet molded substrate or film molded substrate by melt extruding a transparent thermoplastic resin and extrusion molding the extruded molten material, it is considered that it is very difficult to reduce gels resulting from the resin.
In particular, in the case where it is intended to manufacture a sheet molded substrate or film molded substrate by using a thermoplastic resin which is liable to generate a gel, a manufacture condition becomes severe for the purpose of decreasing the amount of gels generated in the sheet molded substrate or film molded substrate.
However, when a screw made of a combination of elements is used, large sized colored materials and foreign matter such as gelled products are often generated.
However, according to this technique, if a material having low corrosion resistance is used for the screw, there is a concern that crevice corrosion of the screw is generated due to a stress to generate contamination with foreign matter, resulting in a hindrance to reduction of foreign matter.
In addition, a screw noise is generated due to torque variations or screw vibration at the time of resin extrusion depending on the constitution, resulting in not only a hindrance to stable production but metal fatigue or deterioration of the screw.

Method used

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  • Transparent thermoplastic resin pellet manufacturing method

Examples

Experimental program
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Effect test

reference example 1

[0051]For reference, molding was conducted by using a polycarbonate resin PC-1 not having been passed through a twin-screw kneader, and the YI and number of gels were measured. Results are shown in Table 2.

examples 1 to 11

, Comparative Examples 1 to 5, and Reference Example 2

[0052]A polycarbonate resin, a twin-screw kneader, and a screw shown in Table 2 were used, the polycarbonate resin was charged into the twin-screw kneader under a condition shown in Table 2, and kneading was conducted by properly setting a cylinder temperature of the twin-screw kneader to an appropriate value in conformity to fluidity of the resin, thereby producing a polycarbonate resin pellet. Molding was conducted by using the obtained polycarbonate resin pellet, and the YI and number of gels were measured. Results are shown in Table 2.

[0053]

TABLE 2ReferenceComparativeComparativeExample 1Example 1Example 1Example 2Polycarbonate resinPC-1PC-1PC-1PC-1Viscosity average17,00017,00017,00017,000molecular weight MvTwin-screw kneader No.—111Screw type—AAAScrew diameter D[mm]—373737Resin supply amount Q[kg / h]—202020Screw rotation number N[rpm]—100200160Q / N—0.200.10.125Residence time tr[sec]—39.239.239.2Shear rate γ[sec−1]—52.4104.783.8...

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Abstract

A method for producing a transparent thermoplastic resin pellet comprising a step of kneading a transparent thermoplastic resin with a kneader under a condition under which a damage history calculated according to the following formula is 500 to 2,500:Damage history={Residence time (tr)}×{Shear rate (γ)}Residence time (tr)=(W×H×L) / Q Shear rate (γ)=(π×D×N) / H in the formulae, W represents a screw groove width (pitch) [cm]; H represents a screw groove depth [cm]; L represents a screw length [cm]; Q represents a resin supply amount [g / s]; D represents a screw diameter [cm]; and N represents a screw rotation number [rps].

Description

TECHNICAL FIELD[0001]The present invention relates to a method for manufacturing a transparent thermoplastic resin pellet, and in particular, the present invention relates to a method for manufacturing a pellet of a transparent thermoplastic resin such as a polycarbonate resin, etc.BACKGROUND ART[0002]In recent years, transparent thermoplastic resins such as polyarylate resins, polymethyl methacrylate resins, polystyrene resins and polycarbonate resins are preferably used as a molding material in the optical field. In these applications, the size or amount of foreign matter (e.g., dusts, carbides, gelled products, etc.) in the resin, and whether the hue of the resin is good or bad largely influences the quality of the product. In particular, in the manufacture of an optical light guide plate, a change of hue of the resin constituting a substrate and a foreign matter in a substrate give an extremely large influence against the reliability of the product.[0003]In a method of obtaining...

Claims

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Application Information

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Patent Type & Authority Patents(United States)
IPC IPC(8): B29B7/42B29C47/92B01F7/00B29C47/60B29B7/48B29B9/16B29B9/12C08J3/00B29B9/06B29B7/00B29B7/80B29C48/40B29C48/625B29C48/92B29K69/00
CPCC08J3/005B01F7/00416B29B7/002B29B7/48B29B7/489B29B7/80B29B9/06B29B9/12B29B9/16B29C47/6087B29C47/92B01F2215/0049B29K2069/00B29K2995/0026C08J2369/00B29C48/92B29C48/625B29C48/40B29B7/38B01F27/1143B01F2101/2805
Inventor TANAKA, TAKAYOSHICHOSA, MUNEHIROYAMAZAKI, YASUNOBU
Owner IDEMITSU KOSAN CO LTD
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