According to the lithium metal negative electrode of the hollow carbon sphere loaded with the silver particles and the solid-state battery, the carbon wall of the hollow carbon sphere is formed by amorphous carbon, the thickness of the carbon wall is 6-15 nm, the diameter of a hollow inner cavity of the hollow carbon sphere is 400-700 nm, the silver particles are loaded on the inner wall of the hollow carbon sphere, and the diameter of the silver particles is 5-20 nm. Silver particles are loaded on amino-functionalized silicon dioxide spheres, then resorcinol and formaldehyde are used as carbon source precursors, phenolic resin coating is carried out, finally calcination is carried out, silicon dioxide sphere templates are removed through hydrofluoric acid etching, and the prepared product is obtained. The hollow carbon sphere loaded with the silver particles serves as a three-dimensional framework, provides an electron ion channel, can effectively guarantee reversibility of lithium ion intercalation and deintercalation, does not generate inactive lithium, plays a stress buffering role in the cycle process of a solid-state battery, further effectively limits volume expansion generated in the cycle process of the solid-state battery, and improves the performance of the solid-state battery. And the safety of the battery is improved.