Carbon nano-tube connecting carbon fiber multi-scale reinforcing body and method for producing the same
A carbon nanotube and carbon fiber technology, applied in the field of carbon fiber reinforcement and its preparation, can solve the problems of reduced material toughness, unable to improve the performance of fiber resin matrix, and increased interface rigidity, so as to improve performance, promote popularization and use, and reduce interface defects. Effect
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specific Embodiment approach 1
[0012] Specific implementation mode one: combine figure 1 Describe this embodiment. In this embodiment, the carbon nanotube-connected carbon fiber multi-scale reinforcement is composed of 2 to 6 parts by weight of carbon nanotubes 1 modified by 1,6 hexamethylenediamine and 100 parts of carbon fibers 2 with acid chloride functional groups on the surface. Made by combining; carbon nanotubes 1 are connected to the surface of carbon fibers 2 through chemical bonds.
[0013] In this embodiment, the carbon nanotubes modified by 1,6 hexamethylenediamine are made according to the following steps: 1. Pretreatment of carbon nanotubes: putting the carbon nanotubes into a mixed solution of sulfuric acid and nitric acid for 1s pulse ultrasonic treatment for 8-12min , and then reflux at 95-105°C for 4±0.1h, then filter and wash the solid phase until neutral, then dry and grind; 2. Put the pretreated carbon nanotubes into SOCl 2 Medium 1s pulse ultrasonic treatment for 8-12min, then add N,N...
specific Embodiment approach 2
[0016] Specific embodiment 2: The difference between this embodiment and specific embodiment 1 is that the carbon nanotube-connected carbon fiber multi-scale reinforcement consists of 3 to 5 parts by weight of carbon nanotubes modified by 1,6 hexamethylenediamine and 100 carbon fibers with acid chloride functional groups on the surface are combined. Others are the same as the first embodiment.
specific Embodiment approach 3
[0017] Specific embodiment three: The difference between this embodiment and specific embodiment one is: the carbon nanotubes connected carbon fiber multi-scale reinforcement is composed of 4 parts by weight of carbon nanotubes modified by 1,6 hexamethylenediamine and 100 parts It is made by combining carbon fibers with acid chloride functional groups on the surface. Others are the same as the first embodiment.
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Abstract
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