Thermal expansion inhibitor, zero thermal expansion material, negative thermal expansion material, method for inhibiting thermal expansion, and method for producing thermal expansion inhibitor
一种负热膨胀系数、热膨胀的技术,应用在零或负热膨胀材料,热膨胀抑制剂的制造领域,能够解决不能热膨胀抑制剂使用、相变幅度窄等问题
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[0158] (1) Manufacture of thermal expansion inhibitors
[0159] mn 3 A 1 N 3 and Mn 3 A 2 N(A 1 and A 2 is Mn, Co, Ni, Cu, Zn, Ga, Ge, Pd, Ag, In or Sn, the same below) is by Mn 2 N and A are Mn:A 1 or A 2 After weighing and stirring at a molar ratio of =3:1, vacuum seal the quartz tube (approximately 10 -3 torr), obtained by heating and roasting at 500-770°C for 60-70 hours. However, Mn 3 GaN is based on Mn 2 N and GaN are used as raw materials, and they are obtained by heating and roasting at 760°C for 60 hours in 1 atmosphere of nitrogen. In addition, Mn 4 N is obtained by heating and calcining metal Mn at 450°C for 120 hours under 1 atmosphere of nitrogen gas.
[0160] Moreover, Mn 3 A 1 1-x1 A 2 x1 N is the Mn produced by the above method 3 A 1 N and Mn 3 A 2 The powder of N is mixed and stirred according to the required molar ratio (1-x1): (x1), then compacted into a sheet, sealed in vacuum or heated for 60 hours at 800°C in a nitrogen atmosphere o...
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