Thermal expansion inhibitor, zero thermal expansion material, negative thermal expansion material, method for inhibiting thermal expansion, and method for producing thermal expansion inhibitor

一种负热膨胀系数、热膨胀的技术,应用在零或负热膨胀材料,热膨胀抑制剂的制造领域,能够解决不能热膨胀抑制剂使用、相变幅度窄等问题

Inactive Publication Date: 2007-08-22
RIKEN
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this phenomenon is a violent first-order phase transition, and the phase transition range is relatively narrow, roughly within 1°C, so it cannot be used as an industrial thermal expansion inhibitor.

Method used

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  • Thermal expansion inhibitor, zero thermal expansion material, negative thermal expansion material, method for inhibiting thermal expansion, and method for producing thermal expansion inhibitor
  • Thermal expansion inhibitor, zero thermal expansion material, negative thermal expansion material, method for inhibiting thermal expansion, and method for producing thermal expansion inhibitor
  • Thermal expansion inhibitor, zero thermal expansion material, negative thermal expansion material, method for inhibiting thermal expansion, and method for producing thermal expansion inhibitor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0158] (1) Manufacture of thermal expansion inhibitors

[0159] mn 3 A 1 N 3 and Mn 3 A 2 N(A 1 and A 2 is Mn, Co, Ni, Cu, Zn, Ga, Ge, Pd, Ag, In or Sn, the same below) is by Mn 2 N and A are Mn:A 1 or A 2 After weighing and stirring at a molar ratio of =3:1, vacuum seal the quartz tube (approximately 10 -3 torr), obtained by heating and roasting at 500-770°C for 60-70 hours. However, Mn 3 GaN is based on Mn 2 N and GaN are used as raw materials, and they are obtained by heating and roasting at 760°C for 60 hours in 1 atmosphere of nitrogen. In addition, Mn 4 N is obtained by heating and calcining metal Mn at 450°C for 120 hours under 1 atmosphere of nitrogen gas.

[0160] Moreover, Mn 3 A 1 1-x1 A 2 x1 N is the Mn produced by the above method 3 A 1 N and Mn 3 A 2 The powder of N is mixed and stirred according to the required molar ratio (1-x1): (x1), then compacted into a sheet, sealed in vacuum or heated for 60 hours at 800°C in a nitrogen atmosphere o...

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Abstract

Provided is a thermal expansion inhibitor which has a much broader application range and which can be used with ease. Used is a thermal expansion inhibitor comprising a manganese nitride crystal.

Description

technical field [0001] The present invention relates to a thermal expansion suppressor for suppressing thermal expansion caused by temperature rise, and a zero or negative thermal expansion material using the thermal expansion suppressor, a thermal expansion suppressing method and a manufacturing method of the thermal expansion suppressor. Background technique [0002] In general, it is known that a substance expands thermally as its temperature increases. Therefore, various problems arise in components used in devices that undergo temperature changes. [0003] Therefore, until now, methods for suppressing thermal expansion at various temperatures have been studied. For example, JP-A-2003-146693 describes an invention in which the invention adopts a -1×10 -6 / ℃~-12×10 -6 Ceramics or glass ceramics with a negative linear expansion coefficient of / °C, and as such ceramics or glass ceramics, ceramics or glass ceramics with β-quartz solid solution or β-eucryptite solid soluti...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/00G02B5/18
CPCG02B1/02G02B7/008H05K1/0373H05K2201/0209H05K2201/068C09K3/00G02B5/18
Inventor 竹中康司高木英典
Owner RIKEN
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