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Titanium-molybdenum-nickel alloys

A titanium-molybdenum-nickel and alloy technology, applied in the field of titanium-molybdenum-nickel alloys, can solve the problems of reducing plasticity, low yield, increasing the brittleness of titanium and titanium alloys, etc. Effect

Inactive Publication Date: 2008-06-04
JIANGSU HONGBAO GROUP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, there are obvious deficiencies in the application of such titanium alloy pipes: 1) the price of imported pipes is high, and the investment cost is high; 2) it cannot meet the height requirements of nuclear power plants and other special industries for titanium and titanium alloy pipes: 3) Due to the high content of H, O, N and carbon elements, the brittleness of titanium and titanium alloys is increased and the plasticity is reduced. It makes the subsequent processing into titanium and titanium alloy pipes more difficult and the yield rate is low. Generally, the length of the pipe produced is ≤8 meters, and the ultra-long titanium alloy pipes of 12 meters to 16 meters cannot be produced. It needs to be welded and lengthened during use, which affects the performance of the product. Reliability has a big impact, and the yield of finished products is low (ie, low yield)

Method used

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  • Titanium-molybdenum-nickel alloys

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Example 1: A titanium-molybdenum-nickel alloy tube blank with a brand name of TA10 and a diameter of 85mm is used, and its composition is as follows: N: 0.009wt%, C: 0.025wt%, H: 0.004wt%, Fe: 0.07wt%, O: 0.07wt%, Mo: 0.38wt%, Ni: 0.8wt%, and the balance Ti, after piercing a bar with an outer diameter of 85mm, the outer diameter is 50.8mm and the wall thickness is 0.899mm through the production process steps in Table 1. A total of 100 pieces of ultra-long titanium alloy tubes with a length of 12.2 meters were fed, of which TA10 means titanium-molybdenum-nickel alloy.

[0020] Table 1 Process steps for producing ultra-long titanium alloy tubes

[0021]

[0022] After the above process steps, 5 cracks were found, among which 3 cracks were found in the first rolling of 72×6.5, and cracks occurred in the second rolling of 69×5.5, and the remaining 95 were all finished products. damage phenomenon.

Embodiment 2

[0023] Example 2. Using TA10, a titanium-molybdenum-nickel alloy tube blank with a diameter of 85mm, its composition is as follows: N: 0.0075wt%, C: 0.02wt%, H: 0.003wt%, Fe: 0.065wt%, 0:0.06wt% %, Mo: 0.35wt%, Ni: 0.75wt%, the remainder Ti, after being perforated by a bar with a diameter of 85mm, the outer diameter is 50.8mm, the wall thickness is 0.899mm, and the length is A total of 100 pieces of 12.2-meter-long titanium alloy pipes were fed, and only 3 pieces were found to be cracked, among which cracks appeared during the second rolling of 69×5.5, and the remaining 97 pieces were not damaged to the finished product.

Embodiment 3

[0024] Example 3: Using TA10, a titanium-molybdenum-nickel alloy tube blank with a diameter of 85mm, its composition is as follows: N: 0.006wt%, C: 0.015wt%, H: 0.0015wt%, Fe: 0.06wt%, O: 0.055wt% %, Mo: 0.3wt%, Ni: 0.7wt%, the remainder Ti, after being perforated by a bar with a diameter of 85mm, the outer diameter is 50.8mm, the wall thickness is 0.899mm, and the length is A total of 100 pieces of ultra-long titanium alloy tubes of 12.2 meters were fed in, and it was found that only one piece was cracked, and the remaining 99 pieces were not damaged when they reached the finished product.

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Abstract

The invention discloses a titanium-molybdenum-nickel alloy. Compositions of the invention are that: nitrogen: less than or equal to 0.01 weight percent; carbon: less than or equal to 0.03 weight percent; hydrogen: less than or equal to 0.005 weight percent; ferrum: less than or equal to 0.08 weight percent; oxygen: less than or equal to 0.08 weight percent; molybdenum: more than or equal to 0.2 weight percent and less than or equal to 0.4 weight percent; nickel: more than or equal to 0.6 weight percent and less than or equal to 0.9 weight percent; elementary residue: less than or equal to 0.1 weight percent; gross residue: less than or equal to 0.4 weight percent; the residual composition in the alloy is titanium. The titanium-molybdenum-nickel alloy of the invention has the advantages of capability of producing an ultra-long high inside diameter-wall thickness ratio titanium alloy pipe with a length of 12 meters to 16 meters, and the titanium alloy pipe has good quality and high yield.

Description

technical field [0001] The invention relates to a titanium alloy, in particular to a titanium-molybdenum-nickel alloy made of super-length and high diameter-to-wall ratio. Background technique [0002] Since my country entered the 21st century, titanium production has entered a stage of rapid development. Before 2001, my country's titanium production was basically about 2,000 tons per year, but in the past five years, the output of sponge titanium and titanium materials has reached a new high; in 2005, the annual production capacity of sponge titanium in China reached 13,000 tons, and the actual output was 9,500 tons. And the production of titanium alloy ingots reached more than 16,000 tons, a year-on-year increase of 37.3%; processed materials were nearly 10,000 tons, a year-on-year increase of 17%. Despite the high-speed growth of titanium production, it is still unable to meet domestic demand and is imported in large quantities. In 2005, my country imported more than 1,7...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C14/00
Inventor 王忠华朱玉宝
Owner JIANGSU HONGBAO GROUP CO LTD
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