Method for removing sulfur dioxide in flue gas with white slime and device

A technology of sulfur dioxide and flue gas, applied in chemical instruments and methods, separation methods, separation of dispersed particles, etc., can solve the problem of not fully considering the characteristics of white mud, and achieve the effect of improving the desulfurization rate

Active Publication Date: 2008-11-12
ZHEJIANG TIANLAN ENVIRONMENTAL PROTECTION TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This invention adopts the traditional limestone-gypsum desulfurization process, and only uses white clay instead of absorbent in the selection of absorbent, without fully considering the characteristics of white clay, that is, white clay cont

Method used

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  • Method for removing sulfur dioxide in flue gas with white slime and device
  • Method for removing sulfur dioxide in flue gas with white slime and device

Examples

Experimental program
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Effect test

Embodiment 1

[0021] In a paper mill, 8 sets of 75t / h fluidized bed boilers adopt this process for desulfurization, the pH value of the first stage is controlled at 5.0, and the liquid-gas ratio is selected at 6L / m 3 , the pH value of the second stage is controlled at 6.8, and the liquid-gas ratio is selected as 2L / m 3 , imported sulfur dioxide concentration 4600mg / m 3 , the outlet sulfur dioxide concentration is 182mg / m 3 , The purity of gypsum reaches 91%.

Embodiment 2

[0023] In a paper mill, two 130t / h pulverized coal furnace boilers adopt this process for desulfurization, the pH value of the first stage is controlled at 5.1, and the liquid-gas ratio is selected at 4L / m 3 , the pH value of the second stage is controlled at 6.5, and the liquid-gas ratio is selected as 2L / m 3 , imported sulfur dioxide concentration 2800mg / m 3 , the outlet sulfur dioxide concentration is 154mg / m 3 , The purity of gypsum is 90%.

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Abstract

The invention discloses a method for removing sulfur dioxide in smoke by using white mud, which uses the white mud plasma as desulfurization solution, and implements the two-stage absorption desulfurization to the sulfur dioxide in smoke and then dissipates fog and discharges the smoke. The desulfurization solution absorbed in the first stage is collected at a low position, and is stored for recycling thereby forming a low position cycle, and the desulfurization solution absorbed in the second stage is collected at a high position, and is stored for recycling thereby forming a high position cycle; the desulfurization solution stored in the high position cycle overflows to the low position cycle, and the desulfurization gypsum generated in the low position cycle is pumped out for cyclone separation, top-flowing thin gypsum plasma refluxes to the high position cycle, and the bottom thick gypsum plasma is treated for deslagging. The invention also discloses a device for realizing the method. The inventive method and device has reasonable design and can effectively improve desulfurization efficiency.

Description

technical field [0001] The invention relates to the technical field of environmental protection and resource utilization, in particular to a method and a device for removing sulfur dioxide in flue gas with lime mud. Background technique [0002] White mud, as a kind of waste from papermaking enterprises, contains a large amount of calcium carbonate. Due to the high alkali content in white mud, direct discharge will cause serious pollution and harm to the environment; the cost of its treatment is high, so most enterprises still use foreign landfill or direct discharge. Using lime mud to remove sulfur dioxide in flue gas can not only solve the problem of waste disposal and pollution, but also greatly reduce the cost of desulfurization. At present, there have been many reports on the use of lime mud as a desulfurizer, the main ones are as follows: [0003] The Chinese patent application with the application number 200510200279.9 adopts a single-loop liquid circulation system,...

Claims

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Application Information

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IPC IPC(8): B01D53/50B01D53/80
Inventor 吴忠标程常杰莫建松徐小勇
Owner ZHEJIANG TIANLAN ENVIRONMENTAL PROTECTION TECH
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