Use of spiro imidazolidine-4, 3'-indole-2, 2', 5' (1H) triones for treatment of conditions associated with vanilloid receptor 1
A vanilloid receptor and imidazolidine technology, which can be used in medical preparations containing active ingredients, bone diseases, respiratory diseases, etc., and can solve problems such as irritation, neurotoxicity, hypothermia, etc.
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[0246] The invention will be illustrated by the following non-limiting examples.
[0247] usual method
[0248] The invention will be illustrated by the following examples, in which, in general:
[0249] (i) Unless otherwise indicated, the operation is carried out at normal or room temperature, that is, 17-25°C and an atmosphere of an inert gas such as argon;
[0250] (ii) Evaporation is carried out by rotary evaporation under vacuum, followed by work-up procedures after removal of residue by filtration;
[0251] (iii) 1 H NMR spectra were measured by Brucker at 400 MHz. Mass spectrometry was performed using electrospray (LC-MS; LC: Waters2790, column XTerra MS C 8 2.5μm 2.1X30mm, buffer gradient H 2 O+0.1%TFA:CH 3 CN+0.04%TFA, MS: micromass ZMD / / ammonium acetate buffer) ionization technique;
[0252] (iii) if there is a yield, it is not necessarily the maximum obtainable;
[0253] (v) use the following abbreviations:
[0254] alloc allyloxycarbonyl
[0255] DCE D...
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