Composite catalytic viscosity reducer for steam injection to thickened oil and preparation method and use thereof

A technology for catalytic viscosity reduction and steam injection, which is applied in chemical instruments and methods, drilling compositions, etc., and can solve the problems of ineffective catalyst effect, poor fluidity and dispersibility, and difficult mixing of catalysts.

Active Publication Date: 2009-05-06
中国石油化工股份有限公司河南油田分公司石油工程技术研究院 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Since the 1990s, domestic research on heavy oil underground upgrading based on hydrothermal cracking has been carried out. By adding transition metal salt catalysts, heavy oil viscosity reduction, gas generation comparison, heavy oil composition comparison, heavy oil component etc., studied the effect of the catalyst in detail and achieved certain results, but both hydrothermal hydrogenation and hydrogen supply by hydrogen donors require a temperature above 240°C, but the range of formation reaching this temperature under steam injection conditions is relatively small. Small catalyst radius and short production cycle are the most

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] In this embodiment, weigh 2g of cumene hydroperoxide, 2g of manganese oleate, and 0.5g of sodium dihydrogen phosphate, and add them to a high-temperature and high-pressure reactor equipped with 70g of heavy oil and 30g of water, and heat up to 100°C after sealing. ℃, keep the temperature for 16 hours, slowly lower the temperature to room temperature, add 0.1g sodium hydroxide, 0.2g active agent and 0.1g salicylaldehyde amine, heat up to 200℃ after resealing, keep the temperature for 24 hours, slowly lower the temperature to room temperature, pour Take out the crude oil and measure the viscosity of the crude oil. Its viscosity reduction rate was measured to be 99.9%.

[0031] The salicylaldehyde amine of this embodiment is prepared from salicylaldehyde, p-phenylenediamine and absolute ethanol, wherein the weight percentage of each component is 9.2% of salicylaldehyde and 4.1% of p-phenylenediamine , absolute ethanol 86.7%.

[0032] The preparation method of salicylalde...

Embodiment 2

[0034] In this embodiment, weigh 1g of cumene hydroperoxide, 2g of manganese oleate, and 0.5g of sodium dihydrogen phosphate, and add them to a high-temperature and high-pressure reactor equipped with 70g of heavy oil and 30g of water, and heat up to 100°C after sealing. ℃, keep the temperature for 16 hours, slowly lower the temperature to room temperature, add 0.1g sodium hydroxide and 0.2g surfactant, heat up to 200℃ after resealing, keep the temperature for 24 hours, slowly lower the temperature to room temperature, pour out the crude oil, and measure the viscosity of the crude oil . Its viscosity reduction rate was measured to be 98%.

[0035] Wherein each component is commercially available commodity.

Embodiment 3

[0037] In this example, 0.1g of sodium hydroxide and 0.1g of salicylaldehyde amine were weighed, respectively added to a high-temperature and high-pressure reactor containing 70g of heavy oil and 30g of water, sealed and heated to 200°C, and kept at a constant temperature for 24 hours. Slowly lower the temperature to room temperature, pour out the crude oil, and measure the viscosity of the crude oil. The viscosity reduction rate was measured to be 92.4%.

[0038] The preparation method of the salicylaldehyde amine of the present embodiment is: using salicylaldehyde, p-phenylenediamine and absolute ethanol as raw materials, wherein, the weight percentage of each component is 10.2% of salicylaldehyde, p-phenylenediamine 5.1%, absolute ethanol 84.7%, salicylaldehyde, p-phenylenediamine, and absolute ethanol were stirred and reacted at room temperature for 4 hours, and the orange solid obtained by suction filtration was salicylaldehyde amine.

[0039] On-site injection method: F...

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Abstract

The invention relates to a composite catalytic viscosity reducer for thick oil steam injection production, as well as a preparation method and application thereof. The viscosity reducer is formed by combining three slugs, wherein a slug I comprises the following components in weight percentage content: 1 to 2 percent of cumene hydroperoxide, 1 to 3 percent of manganese oleate, 0.2 to 0.5 percent of sodium dihydrogen phosphate, 0.1 to 0.5 percent of alkaline matter and the balance being water; a slug II comprises the following components in weight percentage content: 0.05 to 0.1 percent of hydrothermal cracking catalysts, 0.05 to 0.2 percent of alkaline matter and the balance being water; and a slug III comprises the following components in weight percentage content: 0.1 to 0.5 percent of surfactant, 0.1 to 0.3 percent of alkaline matter and the balance being water. The composite viscosity reducer formed by combining three viscosity reducers has the advantages of good viscosity reducing effect, as well as wider adaptive range and better effects during field application through combination. Experiments prove that the composite viscosity reducer can reduce the viscosity of crude oil from 309,028 mPa.s to 55 mPa.s within 24 hours at a temperature between 100 and 200 DEG C, and reaches the viscosity reducing rate of over 99.9 percent.

Description

technical field [0001] The invention relates to a combined catalytic viscosity reducer for heavy oil steam injection exploitation, and also relates to a preparation method of the combined catalytic viscosity reducer for heavy oil steam injection exploitation, which belongs to the field of petroleum exploitation chemistry. Background technique [0002] The methods of steam injection huff and puff or steam flooding are commonly used in the production of heavy oil. Although the method of injecting heat medium can reduce the viscosity of crude oil, which is beneficial to the production of heavy oil, but after a short period of production after steam injection, the formation temperature will drop greatly, and the viscosity of heavy oil will decrease. increase again; therefore, in order to further improve the flowability of crude oil in the formation, it is often necessary to add active agents and other methods to reduce the viscosity of crude oil to prolong the thermal recovery pe...

Claims

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Application Information

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IPC IPC(8): C09K8/594C09K8/52
Inventor 赵长喜张文玉程红晓潘忠陈渊
Owner 中国石油化工股份有限公司河南油田分公司石油工程技术研究院
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