Medium-grained carbon anode matched with 300KA aluminum electrolyzer

A technology of aluminum electrolytic cell and carbon anode, which is applied in the field of carbon anode processing, can solve the problems of low gas reactivity, high consumption of anode per unit of primary aluminum, and high air permeability of carbon anode, and achieve high volume density, low oxidation activity, and reduced The effect of production costs

Inactive Publication Date: 2011-07-20
CHALCO SHANXI NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The present invention provides a 300KA aluminum electrolytic cell in order to solve the problems of low gas reactivity, high air permeability of carbon anode produced by small particle formula and high anode consumption per unit of raw aluminum in the existing technology of manufacturing aluminum electrolytic cell supporting carbon anode. Medium-sized carbon anode for the tank

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0008] Example 1, a medium-sized carbon anode supporting a 300KA aluminum electrolytic cell, its preparation method is: crushing, screening, batching, kneading, molding, and roasting of raw materials,

[0009] a. The composition of raw materials is as follows

[0010] Calcined coke (8-0) mm 84%, residual pole (8-0) mm 0%, coal tar pitch 16% (mass ratio)

[0011] The so-called broken pole is the old carbon anode after crushing. Coal tar pitch refers to medium temperature coal tar pitch or high temperature coal tar pitch or modified coal tar pitch.

[0012] b. Particle size composition

[0013] Granularity mm

+8

-8+4

-4+2

-0.15

-0.074

% of dry material

<3

15±2

13±2

35±2

25±2

[0014] c. Purity requirements for raw materials of each particle size (50-100)%.

[0015] The kneading temperature is 135°C, the molding temperature is 160°C, and the firing temperature is 1050°C.

Embodiment 2

[0017] a. The composition of raw materials is as follows

[0018] Calcined coke (8-0) mm 79%, scrap (8-0) mm 5%, coal tar pitch 16% (mass ratio)

[0019] b. Particle size composition

[0020] Granularity mm

+8

-8+4

-4+2

-0.15

-0.074

% of dry material

<3

21±2

16±2

36±2

24±2

[0021] c. Purity requirements for raw materials of each particle size (50-100)%.

[0022] The kneading temperature is 185°C, the molding temperature is 120°C, and the firing temperature is 1300°C.

Embodiment 3

[0024] a. The composition of raw materials is as follows

[0025] Calcined coke (8-0) mm 76%, scrap (8-0) mm 10%, coal tar pitch 14%

[0026] b. Particle size composition

[0027] Granularity mm

+8

-8+4

-4+2

-0.15

-0.074

% of dry material

<3

15±2

16±2

36±2

24±2

[0028] c. Purity requirements for raw materials of each particle size (50-100)%.

[0029] The kneading temperature is 145°C, the molding temperature is 130°C, and the firing temperature is 1100°C.

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Abstract

The present invention relates to a carbon anode processing method, in particular to a medium-grained carbon anode matched with a 300KA aluminum electrolyzer, which solves the problem that the prior art for manufacturing carbon anodes matched with aluminum electrolyzers is low in gas reactivity, high in the air permeability of the carbon anodes produced through small-particle formulation, high in the unit consumption of primary aluminum anodes, and the like. The preparation method comprises raw material crushing, screening, proportioning, mixing-kneading, molding and roasting, and is characterized in that raw materials are 59 to 84 percent of screened calcined coke, 0 to 25 percent of residual pole pieces and 14 to 18 percent of coal tar pitch; the range of the particle size of the raw materials at each level in the formulation is 8 to 0 mm; the purity of the raw materials in each grain size is required to be between 50 and 100 percent; the mixing-kneading temperature is 135 to 185 DEG C; the molding temperature is 120 to 160 DEG C; and the roasting temperature is 1,050 to 1,300 DEG C. The method can reduce anode consumption by 10 kg / t-Al and then can reduce the production cost of primary aluminum.

Description

technical field [0001] The invention relates to a carbon anode processing method, in particular to a medium-sized carbon anode matched with a 300KA aluminum electrolytic cell. Background technique [0002] With the development of electrolytic cells towards large capacity and automation, the 300KA aluminum electrolytic cell has gradually become the preferred cell type for the replacement of domestic electrolytic aluminum enterprises. However, the production formula of the matching carbon anode still follows the traditional Large particle formula (15-0mm or 12-0mm or 10-0mm) or small particle formula (6-0mm or 4-0mm). The carbon anode produced by the large particle formula has low volume density, carbon dioxide reactivity and air reactivity, and the carbon anode produced by the small particle formula has high air permeability and high consumption of primary aluminum per unit anode. Therefore, in terms of the selection of carbon anode formulations, emphasis is placed on introd...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C25C3/12
Inventor 李少康杨从国肖利峰张甲子张安全陈杰穆二军黄空军周晓温俊华周艳桃高晶
Owner CHALCO SHANXI NEW MATERIAL CO LTD
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