Chopped fiber bundle, molding material, and fiber reinforced plastic, and process for producing them
A technology for chopped fibers and molding materials, which is applied in the field of fiber reinforced plastics and molding materials for molding fiber reinforced plastics, can solve the problems of increased production costs of SMC sheets, uneven distribution of reinforcing fibers, and reduced mechanical properties of molded bodies.
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[0263] Example 1
[0264] As the continuous reinforcing fiber bundle, a continuous reinforcing fiber bundle composed of a plurality of substantially untwisted and unsizing carbon fibers is used. The diameter of the reinforcing fiber (monofilament) is 7 μm, the number of reinforcing fibers is 12,000, the tensile strength of the reinforcing fiber bundle is 5.0 GPa, and the tensile modulus of the reinforcing fiber bundle is 240 GPa. The continuous reinforcing fiber bundle is continuously immersed in the sizing agent mother liquor, the sizing agent is given to the continuous reinforcing fiber bundle so that the resin content is 2.0% by mass, and the reactive polyurethane resin emulsion is diluted with purified water in the sizing agent mother liquor (First Industrial Pharmaceutical Co., Ltd. product, Superflex-R5000). Under a dry tension of 600g / dtex, the continuous reinforcing fiber bundle with the sizing agent was dried with a heat roller at 150°C and a drying oven at 200°C to rem...
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[0272] Example 2
[0273] When cutting the same continuous reinforcing fiber bundle as in Example 1 to obtain a chopped fiber bundle, knife edges were provided at intervals of 12.5 mm in the circumferential direction of the rotary cutter, and the continuous reinforcing fiber bundle was inserted at an angle of 30° to the knife edges. The resulting chopped fiber bundle is figure 2 Chopped fiber bundle CFB2 in the form shown. The edges 16a and 16b of the ends of the chopped fiber bundle CFB2 have a linear form at an angle of 30° to the arrangement direction of the reinforcing fiber 11, and the fiber length Lf of the reinforcing fiber 11 is 25mm, although there is 2% in the same chopped fiber bundle The difference between left and right. From the end to the center of the chopped fiber bundle CFB2, there are transition zones 13a and 13b where the number of reinforcing fibers increases in the arrangement direction of the reinforcing fibers 11, and the number of reinforcing fibers in ...
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[0277] Example 3
[0278] As the continuous reinforcing fiber bundle, a continuous reinforcing fiber bundle (RS570M-521ZS, fiber basis weight 570 tex, manufactured by Nittobo Co., Ltd.) composed of a plurality of glass fibers to which a sizing agent was adhered was used. The continuous reinforcing fiber bundle was pulled out in a non-twisted state by lateral unwinding from the copper pipe, and it was cut in the same manner as in Example 1 to obtain a chopped fiber bundle. The resulting chopped fiber bundle is figure 2 Chopped fiber bundle CFB2 in the form shown. The edges 16a and 16b of the ends of the chopped fiber bundle CFB2 have a linear form at an angle of 12° to the arrangement direction of the reinforcing fibers 11. The fiber length Lf of the reinforcing fiber 11 is 25 mm, although there are 2 in the same chopped fiber bundle. % Around the difference. From the end to the center of the chopped fiber bundle CFB2, there are transition zones 13a and 13b where the number of ...
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