Application of active etherate containing pyrogallol acetonide resin as heat-sensitive CTP thermo-sensitive imaging liquid of dissolution inhibitor

A technology of pyroglucinol acetone and solvent resistance, which is applied in the application field of information recording materials, can solve the problems of small molecular weight, weak solvent resistance of developing solution, and poor film-forming performance of products, and achieve high printing durability and improved Developing and imaging performance, the effect of high sensitivity

Inactive Publication Date: 2010-06-30
TAIXING CITY ORIENT IND +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The invention provides all small molecular compound compounds as the retarding solvent. The disadvantage is that the molecular weight is too small, the film-forming performance of the product is not good, and the solvent retarding performance in the developer is also weak.

Method used

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  • Application of active etherate containing pyrogallol acetonide resin as heat-sensitive CTP thermo-sensitive imaging liquid of dissolution inhibitor
  • Application of active etherate containing pyrogallol acetonide resin as heat-sensitive CTP thermo-sensitive imaging liquid of dissolution inhibitor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Take 0.3g of Japanese NK-2014 infrared absorbing dye, 0.27g of basic brilliant blue, 0.03g of crystal violet, and the acid generator is 1-p-methoxynaphthyl-3,5-bistrichloromethyl triazine, that is, Beijing Normal University 0.2g of S-triazine, 0.2g of barbituric acid produced by University Experimental Chemical Factory, 8.09g of BX-20 phenolic resin produced by Benxi Ruishida Chemical Co., Ltd.; pyrogallol acetonide resin with structure such as general formula I 0.9g of active ether compounds, wherein n is 8-12, R is methyl; ethylene glycol monoethyl ether 113g;

[0026] First, dissolve the infrared absorbing dye NK-2014, basic brilliant blue and crystal violet in ethylene glycol monoethyl ether, and then add phenolic resin and other components after they are completely dissolved. The filter element with a pore size of μm is subjected to three-stage filtration to obtain a heat-sensitive CTP thermal imaging liquid CTP-1.

Embodiment 2

[0028] Take 0.1 g of benzindocyanine dye, 0.4 g of basic brilliant blue, and the acid generator is 1-p-methoxynaphthyl-3,5-bistrichloromethyl triazine, which is produced by Beijing Normal University Experimental Chemical Factory. - Triazine 0.2g, barbituric acid 0.2g, Shandong Weihai Economic and Technological Development Zone Tiancheng Chemical Company BTB-225 phenolic resin 4.85g, BTB-15 phenolic resin 3.24g; structure such as the pyrogallol acetone of general formula I 0.8g of active etherified resin, wherein n is 8-12, R is ethyl; 50g of methyl ethyl ketone;

[0029] Firstly, dissolve the infrared absorbing dye benzindocyanine dye and basic brilliant blue in methyl ethyl ketone, after completely dissolving, add phenolic resin and other components, and then use 8μm, 5μm, and 0.5μm filter elements for three-stage Filtrate to prepare thermosensitive CTP thermal imaging liquid CTP-2.

Embodiment 3

[0031] Get 0.3g of PS-102 infrared absorbing dye from Nippon Kayaku Corporation, 0.3g of crystal violet, 0.2g of tribromomethylphenylsulfone as the acid generator, 0.3g of 1,3-dimethylbarbituric acid, Weihai Economic 8.19g of BTB-26 phenolic resin of Tiancheng Chemical Company in Technology Development Zone; 0.32g of active etherified product of pyrogallol acetonide resin with the structure of general formula II, wherein n is 8-12, R is isobutyl; ethylene glycol Monoethyl ether 64g, methyl ethyl ketone 49g;

[0032] First, dissolve the infrared absorbing dye Nippon Kayaku PS-102 and crystal violet in a mixed solvent of ethylene glycol monoethyl ether and methyl ethyl ketone. After completely dissolving, add phenolic resin and other components. , and a filter element with a pore size of 0.5 μm for three-stage filtration to obtain a thermosensitive CTP thermal imaging liquid CTP-3.

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Abstract

The invention discloses an application of active etherate containing pyrogallol acetonide resin as heat-sensitive CTP thermo-sensitive imaging liquid of dissolution inhibitor, relating to the technical field of optical information recording material application. The imaging liquid comprises the following components: film-forming resin, dissolution inhibitor, infrared dye, coloring background dye, acid-forming agent, additive and solvent. The dissolution inhibitor is the active etherate of the pyrogallol acetonide resin, which decomposes and releases an alkaline solubility group-phenolic hydroxyl under the action of protonic acid produced in an exposure area, thereby creating a large dissolution difference between the exposure area and a non-exposed area, and increasing the developing and imaging performances of plates. The dissolution inhibitor can obviously increase sensitivity and aging resistance, development latitude and comprehensive imaging performance of the heat-sensitive CTP plate.

Description

technical field [0001] The invention belongs to the technical field of application of information recording materials, and in particular relates to a thermosensitive CTP thermal imaging fluid containing active etherified pyrogallol acetonide resin as a retarding solvent. Background technique [0002] In the prior art, the Chinese patent application number CN 1490667 discloses a patent entitled "Thermosensitive Imaging Composition for Positive Thermal Computer-to-Plate Making", the patent 2,2-diphenyl-2-phenolic acid Derivatives are active ester ether compounds obtained by the addition reaction of intermediates of solvent-inhibiting and solubilizing compounds with vinyl ethers, dihydropyrans, etc., or lactone compounds containing active ethers. Solubility-inhibiting and solubilizing compounds with high solubility-resistance and high solubility-promoting properties after acidolysis, combined with novolac resins with acidolysis-solubility-promoting properties, infrared absorbin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G03F7/004
Inventor 沙栩正邹应全
Owner TAIXING CITY ORIENT IND
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