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Compound fluxing agent for float glass

A technology of float glass and flux, which is applied in the field of new float glass composite flux, which can solve the problems of moldy glass, limited fluxing effect of float glass, and high melting temperature

Inactive Publication Date: 2011-01-19
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Na 2 O is used as a single fluxing component of float glass, generally composed of soda ash (Na 2 CO 3 ) introduced, Na 2 O as a float glass flux is characterized by a wide range of sources and low cost, but there are also many problems, such as ①Na 2 The fluxing ability of O is limited, and when the content is constant, the corresponding melting temperature is relatively high; ②Because the float glass contains about 14% Na 2 O, Na + It is easy to migrate to the surface of the glass, which will cause the phenomenon of "mold" on the glass
[0007] Although using Na 2 As a flux for float glass, O has the characteristics of low cost, but its fluxing effect on float glass is limited. With the shortage of energy, the price of fuel will continue to increase, and the structure and performance of float glass will not change basically. Under the condition of lowering the melting temperature of float glass, a flux with better fluxing effect is required

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] step 1:

[0020] List the oxide composition of a certain float glass, see Table 3:

[0021] Table 3 (grams)

[0022] SiO 2

Al 2 o 3

Fe 2 o 3

CaO

MgO

R 2 o

SO 3

total

72.10

1.00

0.10

8.60

4.00

14.00

0.20

100

[0023] R stands for Na, K and other alkali metal ions

[0024] Step 2:

[0025] By Bi 2 o 3 , B 2 o 3 , CeO 2 The total mass of the three oxides is 0.5 g, where Bi 2 o 3 The content of 0.4 grams, B 2 o 3 The content is 0.09 g, CeO 2 The content is 0.01 grams.

[0026] Step 3:

[0027] Calculate the ingredients based on the amount of oxides in Table 3 and the content of the components in step 2 to obtain a list of ingredients. Use mineral raw materials and chemical raw materials to introduce various oxides, and carry out weighing and mixing.

[0028] Step 4:

[0029] This group of glass batch materials is melted, and the high-temperature viscosity of ...

Embodiment 2

[0031] step 1:

[0032] List the oxide composition of a certain float glass, see Table 4:

[0033] Table 4 (grams)

[0034] SiO 2

al 2 o 3

Fe 2 o 3

CaO

MgO

R 2 o

SO 3

total

72.10

1.00

0.10

8.60

4.00

14.00

0.20

100

[0035] R stands for Na, K and other alkali metal ions

[0036] Step 2:

[0037] By Bi 2 o 3 , B 2 o 3 , CeO 2 The total mass of the three oxides is 5 grams, where Bi 2 o 3 The content is 4 grams, B 2 o 3 The content is 0.9 g, CeO 2 The content is 0.1 grams.

[0038] Step 3:

[0039] Calculate the ingredients based on the amount of oxides in Table 4 and the content of the components in step 2 to obtain a list of ingredients. Use mineral raw materials and chemical raw materials to introduce various oxides, and carry out weighing and mixing.

[0040] Step 4:

[0041] This group of glass batch materials is melted, and the high-temperature viscosity of the ...

Embodiment 3

[0043] step 1:

[0044] List the oxide composition of a certain float glass, see Table 5:

[0045] Table 5 (grams)

[0046] SiO 2

Al 2 o 3

Fe 2 o 3

CaO

MgO

R 2 o

SO 3

total

72.10

1.00

0.10

8.60

4.00

14.00

0.20

100

[0047] R stands for Na, K and other alkali metal ions

[0048] Step 2:

[0049] By Bi 2 o 3 , B 2 o 3 , CeO 2 The total mass of the three oxides is 10 grams, where Bi 2 o 3 The content is 8 grams, B 2 o 3 The content is 1.8 g, CeO 2 The content is 0.2 grams.

[0050] Step 3:

[0051] Calculate the ingredients based on the amount of oxides in Table 5 and the content of the components in step 2 to obtain a list of ingredients. Use mineral raw materials and chemical raw materials to introduce various oxides, and carry out weighing and mixing.

[0052] Step 4:

[0053] Melt this group of glass batch materials, and use a high-temperature rotational viscom...

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PUM

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Abstract

The invention relates to a compound fluxing agent for float glass, which is mainly used for fluxing in the process of melting the float glass. The compound fluxing agent consists of three oxides of Bi2O3, B2O3 and CeO2 and Na2O, wherein the Na2O is the inherent component of the float glass, and the three oxides of Bi2O3, B2O3 and CeO2 are added; and if the total mass of the oxides of the float glass is 100 grams, the sum range of the total mass of the three oxides of Bi2O3, B2O3 and CeO2 which are added is 0.5 to 10 grams, and the weight ratio of the Bi2O3, B2O3 to CeO2 is 80-90:8-18:2-4. Under the synergism of the four oxides, the aim of reducing the melting temperature of the float glass is fulfilled, and the melting quality of the float glass is guaranteed, so that the compound fluxing agent of the invention is particularly applied to the preparation of the float glass. Under the condition of keeping the basic properties of the float glass unchanged, the melting temperature can be reduced by 80 DEG C to the maximum extent.

Description

technical field [0001] The invention relates to a novel float glass composite flux. It is especially suitable for the production of float glass, which can ensure the quality of float glass and realize energy saving and emission reduction in its production. Background technique [0002] Float glass is a method of flat glass production. It refers to the method in which glass melt floats on the surface of molten tin liquid to produce flat glass. Its advantages are high glass quality, fast pulling speed, large output, thickness can be controlled at 0.7-30mm, and width can reach 5.6m at present, which is convenient for production automation. The advent of float glass is a major change in the history of world glass production and development, and it is gradually replacing various drawing methods of flat glass. [0003] A very important link in the production of float glass is to continuously put the batch materials into the melting furnace through the feeder for melting, and he...

Claims

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Application Information

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IPC IPC(8): C03C1/00
Inventor 何峰张文涛马艳程金树
Owner WUHAN UNIV OF TECH
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