The invention belongs to the technical field of daily use ceramics, and particularly relates to a high-thermal stability and high-whiteness ceramic and a preparation method thereof. The high-thermal stability and high-whiteness ceramic comprises a high-thermal stability and high-whiteness blank and a transparent glaze, and the high-thermal stability and high-whiteness blank comprises Inner Mongolia potash feldspar, Lincang kaolin, Longyan kaolin, bentonite and a low expansion agent; and the transparent glaze comprises, by weight, Jiangxi potash feldspar, quartz, Longyan kaolin, heavy calcium,calcined zinc oxide, barium sulfate, calcined talcum powder and a regulator. The prepared ceramic blank and glaze are well combined by adopting the method, so the ceramic of the invention has delicatetransparent porcelain and a smooth and bright glaze surface, has a whiteness reaching 81 or more, and achieves thermal exchange at 200-20 DEG C two times without cracking due to high thermal stability; and the preparation method has the advantages of easily availably preparation raw materials, wide firing range, simple preparation process and high product yield, and is suitable for being promotedand applied to the field of daily use ceramics.