Efficient scrap rubber regeneration activator and preparation method thereof

A technology of activator and waste rubber, which is applied in the field of high-efficiency activator for waste rubber regeneration and its preparation, can solve the problems of poor quality of recycled rubber, increased power consumption and crushing, low tensile strength and elongation at break, etc. The effect of good quality of recycled rubber, improved tensile strength and simple production process

Inactive Publication Date: 2011-05-11
胥干
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This activator has the following disadvantages: First, the activation is not strong, such as the regeneration of waste rubber in the low-sulfur cross-linking vulcanization system of peroxide cross-linking and sulfur-containing compounds is not strong; second, the regenerated rubber produced The quality is poor, the tensile strength and elongation at break are low, which cannot meet the needs of industrial production; the third is the poor infiltration and penetration, which can only be...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] In Laiwu Rubber Factory, Shandong Province, it is used for the regeneration of waste rubber, and a high-efficiency activator for the regeneration of waste rubber is prepared, which consists of 2,4,6-tri-tert-butylphenol and disulfur dichloride in a weight ratio of 100 : 25 by weighing, 1000 kilograms of 2,4,6-tri-tert-butylphenol can be weighed, 250 kilograms of disulfide dichloride can be weighed, and then 2,4,6-tri-tert-butylphenol weight per 1000 The ratio of adding 3000ml in 1 kg measures 3000ml of sulfuric acid, through melting 2,4,6-tri-tert-butylphenol and inhaling in the enamel reaction kettle, then adding sulfuric acid and dripping disulfur dichloride successively to obtain the waste High-efficiency activator for rubber regeneration.

[0023] Its production steps are:

[0024] (1), material preparation: weigh 2,4,6-tri-tert-butylphenol and disulfide dichloride in a ratio of 100:25 by weight, that is, weigh 1000 kilograms of 2,4,6-tri-tert-butylphenol , put in...

Embodiment 2

[0032] Still on probation at Laiwu Rubber Factory in Shandong Province, technique is with embodiment 1.

[0033] However, in the production step (1), 2,4,6-tri-tert-butylphenol and disulfur dichloride are weighed in a ratio of 100:26 by weight, that is, 1000 kilograms of 2,4,6-tri-tert-butylphenol are weighed. Butylphenol, take by weighing 260 kilograms of disulfur dichloride, then measure sulfuric acid at the ratio of adding 3000ml in every 1000 kilograms of 2,4,6-tri-tert-butylphenol weight, namely measure 3000ml of sulfuric acid, for subsequent use; In step (4), the temperature display on the enamel reaction kettle is controlled to be 82° C. and kept for 30 minutes; When the temperature on the enamel reaction kettle shows 62°C at the position of 40cm out, and keep at 62°C, disulfur dichloride is added dropwise; after dropping, continue to stir for 2 hours to obtain the finished waste rubber regeneration high-efficiency activator , sealed in barrels for later use.

[0034]...

Embodiment 3

[0037] Still on probation at Laiwu Rubber Factory in Shandong Province, technique is with embodiment 1.

[0038] However, in the production step (1), 2,4,6-tri-tert-butylphenol and disulfide dichloride are weighed in a ratio of 100:22 by weight, that is, 1000 kilograms of 2,4,6-tri-tert-butylphenol are weighed. Butylphenol, take by weighing 220 kilograms of disulfur dichloride, then measure sulfuric acid at the ratio of adding 3000ml in every 1000 kilograms of 2,4,6-tri-tert-butylphenol weight, namely measure 3000ml of sulfuric acid, for subsequent use; In step (4), the temperature on the enamel reaction kettle is displayed as 80° C. and kept for 30 minutes; in the production step (5), the enamel metering tank containing disulfur dichloride is placed higher At the position of 20cm, when the temperature on the enamel reaction kettle shows 58°C, and keep at 58°C, disulfur dichloride is added dropwise; after dropping, continue to stir for 1 hour to obtain the finished waste rubbe...

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Abstract

The invention discloses an efficient scrap rubber regeneration activator and a preparation method thereof. The preparation method is characterized by comprising the following steps: weighing 2,4,6-tri-tert-butylphenol and disulfur dichloride in weight ratio of 100:(22 to 26); measuring sulfuric acid according to the addition of 3000ml of sulfuric acid/1000 kilograms of 2,4,6-tri-tert-butylphenol; thawing the 2,4,6-tri-tert-butylphenol and absorbing into an enamel reaction vessel; then adding the sulfuric acid for catalyzing, slowly dripping the disulfur dichloride, and stirring evenly to obtain the efficient scrap rubber regeneration activator. The efficient scrap rubber regeneration activator and the preparation method thereof have simple production process, low production cost and strong activity, dispense with large-scale equipment and can be widely used for scrap rubber regeneration, and the produced regenerated rubber has good quality, the elongation at break and tensile strength are obviously improved, and the mooney viscosity can be effectively reduced.

Description

technical field [0001] The invention relates to an activator for waste rubber regeneration and the improvement of its production method, in particular to a high-efficiency activator for waste rubber regeneration and its preparation method. Background technique [0002] With the rapid development of the automobile industry and the home appliance industry, the use of rubber is also increasing. my country is one of the main bases for the processing and production of rubber products in the world, and it is also a big rubber consumer. According to relevant statistics, my country's total consumption of natural rubber and synthetic rubber has surpassed that of the United States. [0003] The strength, elongation and mechanical properties of rubber will decrease rapidly during use, especially under the conditions of high temperature, strong light, ozone, copper or aluminum and other trace elements, so that the rubber will age quickly until it cannot be used. Aged rubber is commonl...

Claims

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Application Information

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IPC IPC(8): C08J11/24C08J11/16C08L17/00
CPCY02W30/62
Inventor 胥乾
Owner 胥干
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