Elastomer plastic, conductive plastic, conductive plastic bipolar plate and preparation methods thereof

A technology of elastomeric plastics and conductive plastics, applied in the field of elastomeric plastics, can solve the problems of processing and tissue damage, processing and assembly damage, high electrical conductivity, etc., achieve continuous industrial production, improve long-term stability, and improve comprehensive performance. Effect

Inactive Publication Date: 2011-07-13
BEIJING PRUDENT CENTURY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] CN 1845368A: Graphite plate is used as bipolar plate material of liquid flow battery. Graphite has good electrical conductivity and corrosion resistance, but it is difficult to seal graphite and frame, which may easily cause battery internal leakage, and graphite has poor toughness, which is very easy to Cause damage in processing and organization, and the price of graphite is expensive and the processing and production of large-size graphite plates are difficult. Therefore, there are many technical obstacles to the application of graphite in flow batteries
[0009] WO2002101864 uses CPVC and ABS blended polymers as the base material of conductive plastics, and adds conductive fillers such as graphite. This kind of conductive plastics uses blended polymers, which cannot completely solve the shortage of material strength and toughness, and high content of single conductive fillers Failure to obtain high conductivity
[0010] US1997005626986 uses a blend of polymers and rubber materials as the basis of conductive plastics. Rubber materials contain carbon-carbon double bonds, so they are easily oxidized and decomposed by strong oxidizing substances, resulting in product failure
[0011] To sum up, the current graphite bipolar plates are expensive, the product size cannot meet the needs of high-power products, and are easily damaged during processing and assembly, while other conductive plastic bipolar plates are mostly in the research stage. There are no mature products, and the conductivity of the material is usually only improved by adding conductive fillers, so the mechanical strength of the material is usually poor, and there are certain limitations in corrosion resistance, and there is no large-scale mass production process

Method used

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  • Elastomer plastic, conductive plastic, conductive plastic bipolar plate and preparation methods thereof
  • Elastomer plastic, conductive plastic, conductive plastic bipolar plate and preparation methods thereof
  • Elastomer plastic, conductive plastic, conductive plastic bipolar plate and preparation methods thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0086] 1. Preparation of elastomeric plastics

[0087] Example 1-1. The dried polypropylene pellets PP (MI-5) and PP (MI-20) (obtained from Sinopec) with a melt index (MI) of 5g / 10min and 20g / 10min respectively : After mixing with a mass ratio of 80, it is transferred to the XHM-140 internal mixer (produced by Dalian Rubber Machinery Factory), mixed and internalized at 180°C for 10 minutes, and then passed through the STJ-78 / 180 twin-screw extruder (Lanzhou Lanzhou Produced by Tai Plastic Machinery Co., Ltd.) extrusion granulation, the obtained granules are represented by EP1-1.

[0088] Example 1-2. The dried polyethylene pellets PE (MI-10) and PE (MI-30) (obtained from Sinopec) with a melt index (MI) of 10g / 10min and 30g / 10min respectively After mixing at a mass ratio of 60, it is transferred to the XHM-140 internal mixer (produced by Dalian Rubber Machinery Factory), mixed and internalized at 140°C for 10 minutes, and then passed through the STJ-78 / 180 twin-screw extruder (Lanz...

Embodiment 3-1、3-4、3-7 and 3-10

[0112] Specific process parameters of Examples 3-1, 3-4, 3-7 and 3-10

[0113] High speed mixing

[0114] Speed: 1500rmp / min

[0115] Chamber temperature: 170℃

[0116] Stirring time 30min

[0117] Extrusion granulation

[0118] The temperature of the back section of the extruder is 150℃, the temperature of the middle section is 160℃, and the outlet temperature is 165℃

[0119] Speed ​​15rmp / min

[0120] Mixer temperature 170℃

[0121] Twin screw extruded into tablets

[0122] The temperature of the back section of the extruder is 140℃, the temperature of the middle section is 150℃, and the outlet temperature is 155℃

[0123] Speed ​​10rmp / min

[0124] Cooling temperature: 30℃ water cooling.

Embodiment 3-2

[0125] Specific process parameters of Examples 3-2, 3-5, 3-8 and 3-11

[0126] High speed mixing

[0127] Speed: 1300rmp / min

[0128] Chamber temperature: 160℃

[0129] Stirring time 20min

[0130] Extrusion granulation

[0131] The temperature of the back section of the extruder is 180°C, the temperature of the middle section is 160°C, and the outlet temperature is 175°C

[0132] Speed ​​20rmp / min

[0133] Internal mixer temperature 160℃

[0134] Twin screw extruded into tablets

[0135] The temperature of the back section of the extruder is 120℃, the temperature of the middle section is 150℃, and the outlet temperature is 155℃

[0136] Speed ​​12rmp / min

[0137] Cooling temperature: 25℃ water cooling.

[0138] Specific process parameters of Examples 3-3, 3-6, 3-9 and 3-12

[0139] High speed mixing

[0140] Speed: 1400rmp / min

[0141] Chamber temperature: 130℃

[0142] Stirring time 15min

[0143] Extrusion granulation

[0144] The temperature of the back section of the extruder is 120℃, the temper...

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Abstract

The invention relates to an elastomer plastic which is characterized by being blended from single thermoplastic resins with at least two different specifications. The invention also relates to a conductive plastic containing the elastomer plastic and a conductive plastic bipolar plate. The invention also relates to preparation methods of the elastomer plastic, the conductive plastic containing the elastomer plastic, and the conductive plastic bipolar plate.

Description

Technical field [0001] This application relates to an elastomer plastic, in particular to an elastomer plastic, and also to a conductive plastic and a conductive plastic bipolar plate containing the elastomer plastic. This application also relates to the preparation method of elastomer plastic, conductive plastic containing the same, and conductive plastic bipolar plate. Background technique [0002] Electricity is an indispensable secondary energy source in human life and production in modern society. With the development of social economy, people's demand for electricity is getting higher and higher. According to the "Analysis and Forecast of National Electricity Supply and Demand and Economic Operation Situation in the Third Quarter of 2005" issued by the China Electricity Council: The growth rate of national electricity consumption in 2006 was about 11%, and the electricity consumption was about 2,730 billion kWh . The power gap is mainly concentrated in North China and th...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08L23/12C08L23/20C08L27/06C08L25/06C08L77/00C08L69/00C08L33/12C08L33/08C08L59/00C08L71/12C08L81/02C08L81/06C08L27/12C08K3/04C08K7/06C08K7/00H01B1/24H01M4/00H01M4/86H01M8/02H01M4/88H01M8/0202
CPCY02E60/50Y02P70/50
Inventor 尹海涛
Owner BEIJING PRUDENT CENTURY TECH CO LTD
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