Polyester composite material with controllable crystallinity for sheet material
A technology of crystalline polyester and composite materials, which is applied in the field of controllable crystalline polyester composite materials for sheet materials, can solve the problems that the concept of controllable crystallization and high temperature resistance have not been proposed, and achieve high toughness, controllable crystallization, and temperature resistance outstanding effect
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Embodiment 1
[0064] 100 parts of polyethylene terephthalate dried to below 100 ppm of water content, intrinsic viscosity 0.8 (Sinopec Yizheng Chemical Fiber Company), 6 parts of ethylene-sodium methacrylate ionomer (DuPont Sulyn8920), 5 parts Polyethylene glycol-400-dilaurate, 2 parts of trimellitic anhydride (Shanghai Reagent Company), 8 parts of ethylene-butyl methacrylate-glycidyl acrylate (DuPont PTW) and 0.5 parts of 1010 were mixed evenly . The twin-screw extruder melts and extrudes at 280°C. Water-cooled strips and diced. The controllable crystalline polyester composite material is obtained.
[0065] Controlled crystallization polyester composites were vacuum dried at 120 °C for 8 h. After drying, the slices are extruded into a special sheet extruder. The barrel temperature of the special extruder for sheet is set at 240-310°C. The head temperature is 280°C. The sheet extruder had an aspect ratio of 45:1. The extruded controlled crystallization polyester sheet is immediately ...
Embodiment 2
[0070] 80 parts of polyethylene terephthalate dried to water content below 100ppm, intrinsic viscosity 0.85 (Sinopec Yizheng Chemical Fiber Company) and 20 parts of polybutylene terephthalate, intrinsic viscosity 1.0 (Sinopec Yizheng Chemical Fiber Company) ), 1 part of sodium montanate (Clariant Chemical Company NAV101), 5 parts of neopentyl glycol dibenzoate, 2 parts of 1,4-polybenzobisoxazole (Shanghai Reagent Company), 8 parts of Ethylene-ethyl acrylate-glycidyl methacrylate (Atofina AX8900) and 0.5 parts of 1010 were mixed evenly. The twin-screw extruder melts and extrudes at 270°C. Water-cooled strips and diced. That is, a controlled crystalline polyester composite material is obtained.
[0071] The controlled crystallization polyester sheet composite was vacuum dried at 130°C for 5 hours. After drying, the slices are extruded into a special sheet extruder. The barrel temperature of the special extruder for sheet is set at 240-310°C. The head temperature is 230-290°...
Embodiment 3
[0076] Dry 100 parts of polyethylene terephthalate with an intrinsic viscosity of 0.8 (Sinopec Yizheng Chemical Fiber Company), 2 parts of talcum powder (Liaoning Haicheng Talcum Powder Company, 800 mesh) and 0.5 part of polyethylene terephthalate dried to a water content of less than 100 ppm. Sodium fatty acid (Beijing Reagent Company), 5 parts of polyethylene glycol 2000 (Liaoning Oak Chemical Company), 2 parts of toluene diisocyanate (Shanghai Reagent Company), 8 parts of ethylene-butyl methacrylate-acrylic acid shrink Glyceride (DuPont PTW) and 0.5 parts of 1010 were mixed well. The twin-screw extruder melts and extrudes at 280°C. Water-cooled strips and diced. The controllable crystalline polyester composite material is obtained.
[0077] The controlled crystallization polyester composite was vacuum dried at 140°C for 3 hours. After drying, the slices are extruded into a special sheet extruder. The barrel temperature of the special extruder for sheet is set at 240-310...
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