Method for preparing slurry for catalyst coating membrane electrode of proton exchange membrane fuel cell

A catalyst coating and proton exchange membrane technology, applied in battery electrodes, circuits, electrical components, etc., can solve the problems of uneven catalyst loading and poor electrode slurry stability, and achieve uniform and stable discharge performance. High discharge performance Effect

Inactive Publication Date: 2011-08-03
SUNRISE POWER CO LTD
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  • Summary
  • Abstract
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  • Claims
  • Application Information

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Problems solved by technology

[0006] The disadvantage of the prior art is that the stability of the electrode slurry is poor, and it will settle after a short period of time. After two or three hours, the slurry will be stratified. The upper layer is a clear solvent, and the lower layer is a mixture of catalyst and ion exchange resin.
The continuous production of electrodes using such electrode slurry will lead to uneven catalyst loading

Method used

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  • Method for preparing slurry for catalyst coating membrane electrode of proton exchange membrane fuel cell
  • Method for preparing slurry for catalyst coating membrane electrode of proton exchange membrane fuel cell

Examples

Experimental program
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Effect test

Embodiment 1

[0015] 1) Weigh 2g of 50%wt.Pt / C catalyst, 80g of deionized water, 60g of isopropanol, 18g of 5% Nafion solution, and 0.5g of ethylene glycol solution in a 250ml screw bottle.

[0016] 2) Disperse the catalyst material with a disperser. The speed of the disperser is controlled at 25,000 rpm, and the dispersion time is 60 minutes. At the same time, circulating water is used to cool the electrode slurry to ensure that the temperature of the electrode slurry does not rise under high-speed stirring.

[0017] 3) Place the dispersed electrode slurry in a water bath at 60°C for concentration, and at the same time stir with an electric stirrer to ensure that the solvent in the slurry is evenly volatilized. Stop concentrating when the quality of slurry is reduced to 125.625g.

[0018] 4) Place the concentrated electrode slurry in an autoclave, set the temperature of the autoclave to 80° C., adjust the pressure to 6 MPa and keep the pressure constant for 10 hours, then release the press...

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Abstract

The invention discloses a method for preparing slurry for a catalyst coating membrane electrode of a proton exchange membrane fuel cell. The method is characterized in that: the slurry has uniform dispersion and good stability, is not easy to settle, can be used for preparing the electrode by a method of spraying, brushing, blade coating, silk screen printing and the like, and is suitable for mechanized production. The electrode slurry contains a catalyst, proton exchange resin, a dispersant and an auxiliary agent added in a ratio; and the preparation method comprises four processes of material adding, dispersion, concentration and activating treatment. Because the slurry contains a thickening agent or a stabilizing agent, the slurry has good stability and is not easy to settle after dispersion, concentration and activating treatment. The catalyst coating membrane electrode prepared by adopting the electrode slurry has good discharge performance, and the electrode slurry is suitable for preparing the electrode by a process of spraying, brushing, blade coating, silk screen printing and the like.

Description

technical field [0001] The invention relates to the field of proton exchange membrane fuel cells, in particular to a preparation method of a catalyst coating membrane electrode of a proton exchange membrane fuel cell, in particular to a preparation method of a catalyst coating membrane electrode slurry. Background technique [0002] Electrode is a key component of fuel cell and an important factor affecting the performance of fuel cell. To improve fuel cell performance and reduce the amount of noble metal platinum used as a fuel cell catalyst, researchers have investigated various electrode structures. At present, the catalyst-coated membrane electrode (CCM) structure is commonly used, that is, the catalytic layer is made on the proton exchange membrane to separate the catalytic layer from the gas diffusion layer (GDL). Since the catalyst-coated membrane electrode closely connects the catalytic layer and the proton exchange membrane, and the catalytic layer does not contain...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/88H01M4/86
CPCY02E60/50
Inventor 张可宋书范邢丹敏张玉海侯中军明平文
Owner SUNRISE POWER CO LTD
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