Method for producing epoxy fatty acid methyl ester by using illegal cooking oil
A technology of epoxy fatty acid methyl ester and fatty acid methyl ester, which is applied in the directions of fatty acid esterification, fatty acid production, fatty acid chemical modification, etc. Large and other problems, to achieve the effect of good plasticizing effect, low odor and simple process
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Embodiment 1
[0017] (1) Put 95% waste oil and 5% sulfuric acid into the reaction kettle by weight percentage, heat to 75-85°C, add methanol dropwise for esterification reaction, the methanol drop rate is 180kg / h, and the amount of methanol is 1 ton of waste water Oil 120kg, reaction time 8h, simultaneously reclaim and distill out the methanol after condensing and put into methanol rectification tower to recycle and use, after reaction finishes, separate the glycerol of lower layer, add its weight 5% sodium hydroxide to neutralize in upper layer liquid Surplus sulfuric acid, let stand to stratify again, the upper layer is crude fatty acid methyl ester;
[0018] (2) Purify the crude fatty acid methyl ester obtained in step (1) by molecular rectification, the distillation temperature is 200-220°C, the vacuum degree is 0.1-10Pa, and the colloid and plant asphalt are separated to obtain the purified fatty acid methyl ester ;
[0019] (3) Put the fatty acid methyl ester purified in step (2) int...
Embodiment 2
[0029] (1) Add 97% waste oil and 3% sulfuric acid into the reaction kettle by weight percentage, heat to 75-85°C, add methanol dropwise for esterification reaction, the methanol drop rate is 150kg / h, and the amount of methanol is 1 ton of waste water Oil 160kg, reaction time 10h, reclaim simultaneously the methanol after steaming and condensing is put into methanol rectification tower and reclaim and recycle, after reaction finishes, separate the glycerol of lower layer, add its weight 6% sodium hydroxide to neutralize in upper layer liquid Surplus sulfuric acid, let stand to stratify again, the upper layer is crude fatty acid methyl ester;
[0030] (2) Purify the crude fatty acid methyl ester obtained in step (1) by molecular rectification, the distillation temperature is 200-220°C, the vacuum degree is 0.1-10Pa, and the colloid and plant asphalt are separated to obtain the purified fatty acid methyl ester ;
[0031] (3) Put the fatty acid methyl ester purified in step (2) i...
Embodiment 3
[0034] (1) Add 99.8% waste oil and 0.2% sulfuric acid into the reaction kettle by weight percentage, heat to 75-85°C, add methanol dropwise for esterification reaction, the methanol drop rate is 200kg / h, and the amount of methanol is 1 ton of waste water Oil 140kg, reaction time 9h, reclaim simultaneously the methanol after steaming and condensing put into methanol rectification column and recycle and use, after the reaction finishes, separate the glycerol of lower layer, add its weight 8% sodium hydroxide to neutralize in the upper layer liquid Surplus sulfuric acid, let stand to stratify again, the upper layer is crude fatty acid methyl ester;
[0035] (2) Purify the crude fatty acid methyl ester obtained in step (1) by molecular rectification, the distillation temperature is 200-220°C, the vacuum degree is 0.1-10Pa, and the colloid and plant asphalt are separated to obtain the purified fatty acid methyl ester ;
[0036] (3) Put the fatty acid methyl ester purified in step ...
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