Preparation method of highly-oriented carbon nanotube paper

A carbon nanotube paper and carbon nanotube technology, applied in nanotechnology and other directions, can solve the problems of complex preparation process, limited application of carbon nanotube paper, and high equipment requirements, and achieve the effect of simple and efficient process and good application prospects.

Inactive Publication Date: 2011-09-14
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The carbon tubes in the bucky paper formed by this method can only be highly oriented in one direction, which does not bring significant improvement in mechanical properties, and the size of the bucky paper is limited by the size of the carbon nanotube array
Although the chemical vapor deposition method can obtain carbon nanotube paper with a certain degree of orientation, the preparation process of the method is complicated and requires high equipment requirements.
To sum up, the traditional carbon nanotube bucky paper is mostly a disordered carbon nanotube network structure, which greatly weakens the mechanical properties and electrical conductivity of the bucky paper, which seriously limits the application of carbon nanotube paper.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Preparation of High Strength and High Orientation Carbon Nanotube Paper

[0027] (1) Production of the winding device: the main component of the winding device is a winding roller made of stainless steel, and a glass tube with an outer diameter of 3 cm is set on the winding roller. The winding roll is connected with a small motor through a coupling and a belt. The motor is controlled by an adjustable power supply to control the speed of the winding roller; (the outer diameter of the winding roller in this step can be adjusted according to actual requirements)

[0028] (2) After spraying the release agent on the outer glass tube of the winding roller, the carbon nanotube film is pulled out from the spinnable carbon nanotube array and glued to the glass tube, and the motor is driven by the rotation of the winding roller The operation of carbon nanotubes, the direction of operation is perpendicular to the winding axis; (the experimental parameters in this step are aimed a...

Embodiment 2

[0034] Preparation of ultrathin highly oriented carbon nanotube paper.

[0035] (1) Manufacturing of the winding device: the main component of the winding device is a winding roller made of glass, and a glass tube with an outer diameter of 3 cm is set on the winding roller. The winding roll is connected with a small motor through a coupling and a belt. The motor is controlled by an adjustable power supply to control the speed of the winding roller; (the outer diameter of the winding roller in this step can be adjusted according to actual requirements)

[0036] (2) Coating a layer of polymer film on the winding roller, winding the solid-phase stretched film carbon nanotube film with a width of more than 1 cm on the winding roller;

[0037] (3) while carrying out step (2), volatile solvent is sprayed on the winding roller surface that is wound with carbon nanotube film, and solvent is made up of ethanol, and film running speed is set to 5 millimeters per second;

[0038](4) Af...

Embodiment 3

[0040] Preparation of carbon nanotube paper with different internal orientations.

[0041] (1) Manufacturing of the winding device: the main component of the winding device is a winding roller made of stainless steel, and a glass tube with an outer diameter of 3 cm is set on the winding roller. The winding roll is connected with a small motor through a coupling and a belt. The motor is controlled by an adjustable power supply to control the speed of the winding roller; (the outer diameter of the winding roller in this step can be adjusted according to actual requirements)

[0042] (2) if Figure 4 As shown in (a), during the winding process, the carbon nanotube film is wound on the winding roller at a winding angle of 90°, and the film covers the entire surface of the winding roller by moving the winding roller horizontally.

[0043] (3) while carrying out step (2), volatile solvent is sprayed on the winding roller surface that is wound with carbon nanotube film, and solvent...

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Abstract

The invention relates to a preparation method of a piece of highly-oriented carbon nanotube paper. The preparation method comprises the following steps: sticking and wrapping a carbon nanotube film onto a winding roller, then winding the carbon nanotube film, simultaneously, spraying a volatile solvent onto the winding roller, and then preparing the carbon nanotube paper with controllable orientation after the volatile solvent is fully volatilized. The preparation method is simple and efficient in process, avoids the damage of the structure and the morphology of a carbon nanotube and can achieve the carbon nanotube paper with controllable thickness, size and internal structure by changing equipment parameters; and the prepared carbon nanotube paper can be widely applied to batteries and filtering materials and further has a good application prospect.

Description

technical field [0001] The invention belongs to the field of preparation of carbon nanotube paper, in particular to a preparation method of carbon nanotube paper with high degree of orientation. Background technique [0002] Carbon nanotube (CNT) was discovered by Iijima, a Japanese electron microscope expert, in 1991. It is another new member of the carbon family after C60. Due to their excellent physical and chemical properties, carbon nanotubes have good application prospects in fields such as field emission, batteries and supercapacitors, sensors, and high-performance composite materials. So far, the macrostructures assembled by it include carbon nanotube ribbons, fibers, films, and carbon nanotube paper (also known as Buckypaper, Bucky paper). Carbon nanotube paper is a paper-like thin layer of carbon nanotubes composed of intertwined carbon nanotubes through the Van der Waals force between the tubes. Whether used as a functional material or a reinforcing material, ca...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B31/02B82Y40/00
Inventor 刘玮邱夷平许福军
Owner DONGHUA UNIV
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