Hydrolysis-resistance alcoholysis-resistance glass fiber reinforced PPA (phenyl-propanolamine) material and preparation method thereof

An alcoholysis-resistant and hydrolysis-resistant technology, applied in the field of polymer materials, can solve the problems of failing to meet customer requirements, being easily eroded, and reducing mechanical properties, achieving high mechanical properties, excellent hydrolysis resistance, and simple preparation process. Effect

Active Publication Date: 2012-12-19
徐东
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Ordinary glass fiber reinforced PPA material has good heat resistance and mechanical properties, but when used to make these water chamber parts, it is easily corroded due to long-term immersion in hot water and ethylene glycol solution, and the mechanical properties are greatly reduced , can not meet the requirements of customers

Method used

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  • Hydrolysis-resistance alcoholysis-resistance glass fiber reinforced PPA (phenyl-propanolamine) material and preparation method thereof
  • Hydrolysis-resistance alcoholysis-resistance glass fiber reinforced PPA (phenyl-propanolamine) material and preparation method thereof
  • Hydrolysis-resistance alcoholysis-resistance glass fiber reinforced PPA (phenyl-propanolamine) material and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0045] The PPA is 76.8% by weight percentage (below is weight percentage), heat stabilizer H1610.4%, alcoholysis-resistant protective agent 0.3%, hydrolysis-resistant protective agent 0.2%, OP wax 0.6%, nucleating agent 0.2%, Weigh the black mother N54 1.5%, pour it into a blender and stir evenly. The mixed materials are put into the hopper of the twin-screw extruder, and the glass fiber HP361020% is fed into the extruder through side feeding, melted and blended, extruded and granulated to form a composite material. Among them, the temperature settings of each heating zone of the screw are: the temperature of the first zone is 270°C; the temperature of the second zone is 290°C; the temperature of the third zone is 310°C; the temperature of the fourth zone is 300°C; 16MPa.

Embodiment 2

[0047] PPA is 61.8% by weight percentage (hereinafter all are percentage by weight), heat stabilizer H1610.4%, alcoholysis-resistant protective agent 0.3%, hydrolysis-resistant protective agent 0.2%, OP wax 0.6%, nucleating agent 0.2%, Weigh the black mother N54 1.5%, pour it into a blender and stir evenly. The mixed materials are put into the hopper of the twin-screw extruder, and glass fiber HP3610 35% is fed into the extruder through side feeding, melted and blended, extruded and granulated to form a composite material. Among them, the temperature settings of each heating zone of the screw are: the temperature of the first zone is 270°C; the temperature of the second zone is 290°C; the temperature of the third zone is 310°C; the temperature of the fourth zone is 300°C; 16MPa.

Embodiment 3

[0049]PPA is 46.8% by weight percentage (below all is weight percentage), heat stabilizer H1610.4%, alcoholysis-resistant protective agent 0.3%, hydrolysis-resistant protective agent 0.2%, OP wax 0.6%, nucleating agent 0.2%, Weigh the black mother N54 1.5%, pour it into a blender and stir evenly. The mixed materials are put into the hopper of the twin-screw extruder, and the glass fiber HP361050% is fed into the extruder through side feeding, melted and blended, extruded and granulated to form a composite material. Among them, the temperature settings of each heating zone of the screw are: the temperature of the first zone is 270°C; the temperature of the second zone is 290°C; the temperature of the third zone is 310°C; the temperature of the fourth zone is 300°C; 16 MPa.

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Abstract

The invention discloses a hydrolysis-resistance alcoholysis-resistance glass fiber reinforced PPA (phenyl-propanolamine) material and a preparation method thereof. The hydrolysis-resistance alcoholysis-resistance glass fiber reinforced PPA material consists of the following components in percentage by weight: 46 to 76 percent of polyphthalamide resin, 20 to 50 percent of glass fibers, 0.3 to 0.6 percent of heat stabilizer, 0.2 to 0.4 percent of alcoholysis-resistance protective agent, 0.1 to 0.3 percent of hydrolysis-resistance protective agent, 0.4 to 0.8 percent of polarity OP (oxidized polyethlene) wax, 0.1 to 0.3 percent of nucleating agent and 1.0 to 2.0 percent of black color masterbatch. The reinforced PPA material disclosed by the invention not only has excellent mechanical property, but also has excellent hydrolysis-resistance and alcoholysis-resistance characteristics. When the hydrolysis-resistance alcoholysis-resistance glass fiber reinforced PPA material is soaked in hot water and ethylene glycol solution for a long time, over 80 percent of mechanical property can be kept. The hydrolysis-resistance alcoholysis-resistance glass fiber reinforced PPA material can be widely used in the automobile industry and other fileds. When the hydrolysis-resistance alcoholysis-resistance glass fiber reinforced PPA material is used for manufacturing parts which are in contact withwater and antifreezing solution for a long time, not only can the manufacturing cost of the parts be reduced, but also the weights of the parts can be greatly reduced.

Description

[technical field] [0001] The invention relates to the technical field of polymer materials, in particular to a hydrolysis-resistant and alcoholysis-resistant glass fiber reinforced PPA material and a preparation method thereof. [Background technique] [0002] PPA (polyphthalamide) resin is a semi-aromatic polyamide made of phthalic acid. Under high temperature and high humidity, the tensile strength of PPA is 20% higher than that of nylon 6 and higher than that of nylon 66; The flexural modulus of PPA material is 20% higher than that of nylon, the hardness is greater, and it can resist long-term tensile creep; and the resistance of PPA to gasoline, grease and coolant is also stronger than that of PA. [0003] With the rapid development of the automobile industry, replacing steel with plastic has become the trend and direction of the development of automobile materials. Glass fiber reinforced PPA materials are widely used in water chamber parts of automobiles, such as thermos...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L77/00C08K13/04C08K7/14B29B9/06B29C47/92B29C48/92
Inventor 徐东徐永周兵
Owner 徐东
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