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Hole-transmission type organic thin-film transistor and manufacturing method thereof

A technology of hole transport and organic thin film, which is applied in the manufacture of semiconductor/solid-state devices, electric solid-state devices, semiconductor devices, etc., can solve the problems of increasing manufacturing costs, harsh manufacturing environment requirements, and limiting the development of transistors, so as to reduce mutual collisions, The effect of improving the transport ability and carrier mobility and reducing the threshold voltage

Inactive Publication Date: 2012-01-25
UNIV OF ELECTRONIC SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, single crystal organic transistors have very harsh requirements on the preparation environment, which increases the preparation cost, which greatly limits the further development of transistors.

Method used

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  • Hole-transmission type organic thin-film transistor and manufacturing method thereof
  • Hole-transmission type organic thin-film transistor and manufacturing method thereof
  • Hole-transmission type organic thin-film transistor and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0048] Device structure such as figure 1 As shown, it is a bottom-gate top-contact structure. The material and thickness of each layer of the device are as follows: the substrate 1 is glass, the gate electrode 2 is ITO (180 nm), the gate insulating layer 3 is PMMA (500 nm), the first transition layer 4 and the second transition layer 7 are both Hexathiophene (2 nm), the first organic semiconductor layer 5 and the second organic semiconductor layer 8 are copper phthalocyanine (25 nm), the hole blocking layer 6 is TPBi (5 nm), the source electrode 9 and the drain electrode 10 are both for Au (50 nm).

[0049] The preparation method of the hole transport type organic thin film transistor is as follows:

[0050] ① Thoroughly clean the sputtered ITO glass substrate first, and dry it with dry nitrogen after cleaning;

[0051] ②Using the spin coating method to prepare PMMA film on ITO to form gate insulating layer;

[0052] ③Heating and baking the spin-coated PMMA film;

[0053]...

Embodiment 2

[0061] The structure of the transistor is as figure 1 shown. The material and thickness of each layer of the transistor are as follows: the substrate 1 is glass, the gate electrode 2 is ITO (180 nm), the gate insulating layer 3 is PS (50 nm), the first transition layer 4 and the second transition layer 7 are both Hexathiophene (2 nm), the first organic semiconductor layer 5 and the second organic semiconductor layer 6 are copper phthalocyanine (25 nm), the hole blocking layer 6 is TPBi (5 nm), the source electrode 9 and the drain electrode 10 are both for Au (50 nm).

[0062] The fabrication process of the transistor is similar to that of Example 1.

Embodiment 3

[0064] Transistor structures such as figure 1 shown. The material and thickness of each layer of the transistor are: the substrate 1 is glass, the gate electrode 2 is ITO (180 nm), the gate insulating layer 3 is PVA (2000 nm), the first transition layer 4 and the second transition layer 7 are both Hexathiophene (2 nm), the first organic semiconductor layer 5 and the second organic semiconductor layer 6 are copper phthalocyanine (25 nm), the hole blocking layer 6 is BCP (5 nm), the source electrode 9 and the drain electrode 10 are both for Au (50 nm).

[0065] The fabrication process of the transistor is similar to that of Example 1.

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Abstract

The invention discloses a hole-transmission type organic thin-film transistor and a manufacturing method thereof. The hole-transmission type organic thin-film transistor has a bottom gate top contacting type or bottom gate bottom contacting type structure and comprises a substrate, a gate electrode, a gate insulation layer, a first transition layer, a P type organic semiconductor layer, a source electrode and a drain electrode, wherein the P type organic semiconductor layer comprises a first organic semiconductor layer and a second organic semiconductor layer; a hole barrier layer is arranged between the first organic semiconductor layer and the second organic semiconductor layer; and a second transition layer is arranged between the hole barrier layer and the second organic semiconductor layer. In the hole-transmission type organic thin-film transistor, a hole barrier layer is inserted into organic functional layers so as to turn a traditional single-channel transmission mode into a double-layer channel transmission mode, and the insulation layer and the hole barrier layer are respectively provided with a transition layer so as to promote the crystallizing degree of two organic functional layers and further to approach high migration rate characteristics of a mono-crystal organic transistor, thereby greatly lowering the manufacturing cost and being more suitable for large-scale industrialized production.

Description

technical field [0001] The invention relates to the technical field of electronic components, in particular to a hole transport type organic thin film transistor and a preparation method thereof. Background technique [0002] Since the first organic thin film transistors (OTFT) were reported by Tsumura et al. in 1986, organic thin film transistors have been widely used due to their potential application value in active matrix display, organic integrated circuits, electronic trademarks and sensors. received widespread attention. Organic thin film transistors can be classified into electron transport type organic thin film transistors and hole transport type organic thin film transistors according to different types of transport carrier charges. In the electron transport transistor, the carriers are electrons, and the charge is negative; while in the hole transport transistor, the carriers are holes, and the charge is positive. [0003] Field-effect mobility is one of the mo...

Claims

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Application Information

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IPC IPC(8): H01L51/05H01L51/40
Inventor 蒋亚东于军胜蔡欣洋于欣格
Owner UNIV OF ELECTRONIC SCI & TECH OF CHINA