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Agent for rapidly removing high sulfur coal mine underground hydrogen sulfide gas, and device thereof

A hydrogen sulfide, high sulfur technology, applied in mining equipment, mining equipment, chemical instruments and methods, etc., to achieve the effect of simple and flexible equipment, improve absorption efficiency, and promote full contact

Inactive Publication Date: 2012-02-22
四川省煤炭产业集团有限责任公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The above treatment methods are generally used for low-concentration H 2 The treatment of S, for the solution of underground H in high-sulfur coal mines 2 The outburst problem of S has great application limitations, and there is no solution for the outburst H in mines. 2 Related reports on S gas treatment, so coal mine H 2 The rapid control of S prominence is a difficult problem faced by many mines today. It is of great significance to develop a method for quickly removing hydrogen sulfide gas under the mine to ensure the safe and efficient production of coal mines.

Method used

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  • Agent for rapidly removing high sulfur coal mine underground hydrogen sulfide gas, and device thereof
  • Agent for rapidly removing high sulfur coal mine underground hydrogen sulfide gas, and device thereof
  • Agent for rapidly removing high sulfur coal mine underground hydrogen sulfide gas, and device thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] 1) Put the hydrogen sulfide sensor in the simulated roadway, set the upper limit of the sensor concentration to 800ppm, and the lower limit to 6.6ppm. The mass fractions of sodium carbonate and chloramine-T in the prepared absorption solution are 0.2% and 0.4%, respectively.

[0031] 2) Hydrogen sulfide gas is decompressed by the pressure reducing valve and adjusted by the flow meter to enter the simulated roadway, and the concentration of hydrogen sulfide in the simulated cabin is adjusted by controlling the flow and time to make it gradually increase. When the concentration exceeds the alarm limit value of 800ppm, the sensor on the sensor The automatic alarm device starts to alarm, and immediately closes the hydrogen sulfide gas cylinder to stop the air intake, and at this time, the mist misting machine automatically starts to spray. The spray volume was 1.5L / min, and the concentration of hydrogen sulfide in the simulated cabin was measured after spraying for 5s, 10s, ...

Embodiment 2

[0033] 1) Put the hydrogen sulfide sensor in the simulated roadway, set the upper limit of the sensor concentration to 800ppm, and the lower limit to 6.6ppm, and prepare the mass fractions of sodium carbonate and chloramine-T in the absorption solution to 0.3% and 0.3%, respectively.

[0034] 2) Hydrogen sulfide gas is decompressed by the pressure reducing valve and adjusted by the flow meter to enter the simulated roadway, and the concentration of hydrogen sulfide in the simulated cabin is adjusted by controlling the flow and time to make it gradually increase. When the concentration exceeds the alarm limit value of 800ppm, the sensor on the sensor The automatic alarm device starts to alarm, immediately close the hydrogen sulfide gas cylinder to stop the air intake, and turn on the fog machine for spraying. The spray volume was 1.5L / min, and the concentration of hydrogen sulfide in the simulated cabin was measured after spraying for 5s, 10s, 15s, 20s, 25s, and 30s respectively...

Embodiment 3

[0036] 1) Put the hydrogen sulfide sensor in the simulated roadway, set the upper limit of the sensor concentration to 800ppm, and the lower limit to 6.6ppm. The mass fractions of sodium carbonate and chloramine-T in the prepared absorption solution are 0.3% and 0.5%, respectively.

[0037] 2) Hydrogen sulfide gas is decompressed by the pressure reducing valve and adjusted by the flow meter to enter the simulated roadway, and the concentration of hydrogen sulfide in the simulated cabin is adjusted by controlling the flow and time to make it gradually increase. When the concentration exceeds the alarm limit value of 800ppm, the sensor on the sensor The automatic alarm device starts to alarm, immediately close the hydrogen sulfide gas cylinder to stop the air intake, and turn on the fog machine for spraying. The spray volume was 1.5L / min, and the concentration of hydrogen sulfide in the simulated cabin was measured after spraying for 5s, 10s, 15s, 20s, 25s, and 30s respectively. ...

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Abstract

The invention belongs to the field of coal mine production safety. A purpose of the present invention is to solve the problem of high sulfur coal mine underground hydrogen sulfide so as to ensure the safe production of coal mine. The present invention discloses an agent for rapidly removing the high sulfur coal mine underground hydrogen sulfide gas. The agent adopts sodium carbonate as an alkaline absorbent, and is characterized in that: the agent further comprises a chloramine-T adopted as a catalytic oxidizing agent; the sodium carbonate and the chloramine-T are prepared into a solution according to a sodium carbonate mass fraction of 0.15-0.3% and a chloramine-T mass fraction of 0.3-0.5%. The invention further discloses a device for rapidly removing the high sulfur coal mine underground hydrogen sulfide gas. The device comprises four parts of a hydrogen sulfide sensor (1), a sensing switch (2), an alarm device (3) and a mist sprayer (4), wherein the agent described in the claim 1 is stored in the mist sprayer. With the device, the absorbent can be dispersed into particles with the extremely small particle sizes, such that the agent adequately contacts the hydrogen sulfide gas so as to improve the absorption efficiency.

Description

[0001] technical field [0002] The invention belongs to the field of coal mine production safety, and aims to solve the problem of hydrogen sulfide protruding underground in high-sulfur coal mines, so as to ensure the safe production of coal mines. [0003] Background technique [0004] During the mining of coal mines, especially high-sulfur coal mines, a large amount of hydrogen sulfide (H 2 S) gas, H 2 S is a highly toxic flammable gas, colorless, with the smell of rotten eggs, its density is 1.19 times that of air, it is easily soluble in water to form hydrogen sulfuric acid, and its solubility in water is CO 2 2.7 times of CH 4 93 times more. h 2 S is both an irritating gas and a corrosive gas. h 2 S concentration at 0.4mg / m 3 People can clearly smell its odor; 70~150 mg / m 3 When inhaled for a few minutes, olfactory fatigue will occur without smelling the odor. The higher the concentration, the faster the olfactory fatigue, and the easier it is to make people...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/78B01D53/86B01D53/52E21F17/18
Inventor 王寿全林海余玉江韦威刘万波王亚楠董颖博陈月芳
Owner 四川省煤炭产业集团有限责任公司
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