Antioxidant toughening modified polyphenylene sulfide monofilament and preparation method thereof

A technology of polyphenylene sulfide and toughening modification, which is applied in the manufacture of rayon, single-component synthetic polymer rayon, melt spinning, etc., can solve the problems of poor oxidation resistance and brittleness, and achieve low cost and high production efficiency. Excellent process stability, oxidation resistance and toughness

Inactive Publication Date: 2012-07-11
SINOSELEN HI TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] In view of the above deficiencies in the prior art, the object of the present invention is to provide an anti-oxidation toughened modifi

Method used

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  • Antioxidant toughening modified polyphenylene sulfide monofilament and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0066] Using the MFR of 168g / 10min linear polyphenylene sulfide raw powder, its structural unit content ≥ 90% mol / mol to produce anti-oxidation toughened modified polyphenylene sulfide chips through the following formula:

[0067] PPS raw powder: 96%

[0068] Antioxidant AO1179: 0.2%

[0069] Antioxidant AO110: 0.2%

[0070] Nano calcium carbonate: 2.6%

[0071] Dispersion coupling agent EK602: 1%

[0072] Preparation of anti-oxidation and toughening modified polyphenylene sulfide chips: Add antioxidant, toughening agent and dispersing coupling agent to PPS raw powder, mix uniformly in a high-speed mixer and dry; mix and dry PPS raw The powder is extruded by a twin-screw extruder and pelletized to make anti-oxidation toughened modified polyphenylene sulfide chips for spinning to produce PPS monofilaments.

[0073] Preparation of anti-oxidative and toughened polyphenylene sulfide monofilaments: before melt spinning, the polyphenylene sulfide chips were dried in ...

Embodiment 2

[0075] Use the MFR of 200g / 10min linear polyphenylene sulfide raw powder, and its structural unit content is ≥70% mol / mol to produce anti-oxidation toughened modified polyphenylene sulfide chips through the following formula:

[0076] PPS raw powder: 95.8%

[0077] Antioxidant AO1179: 0.3%

[0078] Nano calcium carbonate: 2.9%

[0079] Dispersion coupling agent EK602: 1%

[0080] Preparation of anti-oxidation and toughening modified polyphenylene sulfide chips: Add antioxidant, toughening agent and dispersing coupling agent to PPS raw powder, mix uniformly in a high-speed mixer and dry; mix and dry PPS raw The powder is extruded by a twin-screw extruder and pelletized to make anti-oxidation toughened modified polyphenylene sulfide chips for spinning to produce PPS monofilaments.

[0081] Preparation of anti-oxidative and toughened polyphenylene sulfide monofilaments: before melt spinning, the polyphenylene sulfide chips were dried in a vacuum drum with a moisture c...

Embodiment 3

[0083] Using the MFR of 168g / 10min linear polyphenylene sulfide raw powder, its structural unit content ≥ 90% mol / mol to produce anti-oxidation toughened modified polyphenylene sulfide chips through the following formula:

[0084] PPS raw powder: 97%

[0085] Antioxidant AO110: 0.3%

[0086] Nano calcium carbonate: 1%

[0087] Dispersion coupling agent EK602: 1.7%

[0088] Preparation of anti-oxidation and toughening modified polyphenylene sulfide chips: Add antioxidant, toughening agent and dispersing coupling agent to PPS raw powder, mix uniformly in a high-speed mixer and dry; mix and dry PPS raw The powder is extruded by a twin-screw extruder and pelletized to make anti-oxidation toughened modified polyphenylene sulfide chips for spinning to produce PPS monofilaments.

[0089] Preparation of anti-oxidative and toughened modified polyphenylene sulfide monofilaments: before melt spinning, the polyphenylene sulfide chips were dried in a vacuum drum with a moisture...

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Abstract

The invention discloses an antioxidant toughening modified polyphenylene sulfide (PPS) monofilament and a preparation method of the PPS monofilament. The method of the invention comprises the steps of adding an antioxidant, a toughener, and a dispersing coupler into the polyphenylene sulfide powder to prepare antioxidant toughening modified polyphenylene sulfide chip, and melting and spinning; wherein the antioxidant toughening modified polyphenylene sulfide chip consists of the following components by weight: 95-97% of polyphenylene sulfide powder, 0.2-0.6% of antioxidant, 1-4% of inorganic toughener and 1-2% of dispersing coupler. According to the formula of the antioxidant toughening modified polyphenylene sulfide chip and the preparation method of the antioxidant toughening modified polyphenylene sulfide monofilament of the invention, modified polyphenylene sulfide monofilaments with superior breaking strength, breaking elongation, dry-heat shrinkage, antioxidant performance and toughness can be produced, and the method is stable in production process, low in cost, and good in product quality.

Description

technical field [0001] The invention relates to the field of special chemical fibers, in particular to an anti-oxidation toughening modified polyphenylene sulfide monofilament and a preparation method thereof. Background technique [0002] Polyphenylene sulfide (English name Polyphenylene Sulfide, abbreviated as PPS) fiber was first successfully developed by Philips Petroleum Company of the United States. The company started industrial production of PPS resin in 1973, developed fiber-grade PPS resin in 1979, and industrialized PPS short fiber in 1983. Due to the excellent performance of polyphenylene sulfide fiber, Japan's Toyobo, Toray, Teijin and German Bayer have also developed and produced polyphenylene sulfide fiber. [0003] Polyphenylene sulfide can be made into filaments and short fibers, and can also be made into monofilaments. Due to its good textile processing performance and excellent chemical resistance, thermal stability, high temperature resistance and flame...

Claims

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Application Information

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IPC IPC(8): D01F6/94D01F1/10D01D5/08D01D5/12D01D10/02
Inventor 侯庆华杨新华邓佶连宏光
Owner SINOSELEN HI TECH
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