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Saponification process for producing vinylidene chloride

A saponification technology of vinylidene chloride, which is applied in the saponification process field of vinylidene chloride production, can solve the problems of high caustic soda concentration, multiple by-products, and incomplete saponification reaction, so as to reduce side reactions, increase yield, and reduce environmental pollution. pollution effect

Inactive Publication Date: 2012-11-21
NANTONG REPAIR AIR CHEM BIOENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantage of this process is that the concentration of caustic soda in the early stage of dripping chlorinated solution is high, and more by-products are likely to be produced; Raffinate

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0011] A saponification process for producing vinylidene chloride comprises the following steps:

[0012] 1. Add 10% caustic soda into the high-level tank to raise the temperature to 75°C, and automatically control the liquid level to be constant;

[0013] 2. Make the main reaction kettle into a mother liquor containing 1% alkali. Generally, the amount of the mother liquor is determined according to the height of the overflow pipe. When the temperature is raised to 75°C, the side reaction kettle is made into a mother liquor containing 1% alkali. The liquid level is controlled as 80cm, heat up to 70°C, then add alkali and chlorinated solution dropwise at the same time, control the flow rate of alkali to 2200L / h, and the flow rate of chlorinated solution to 1000L / h, and circulate the reaction through the saponification pump of the main reactor;

[0014] 3. The increased material in the upper reactor overflows into the side reaction through the overflow pipe, and circulates the r...

Embodiment 2

[0016] A saponification process for producing vinylidene chloride comprises the following steps:

[0017] 1. Add 13% caustic soda into the high-level tank to raise the temperature to 77°C, and automatically control the liquid level to be constant;

[0018] 2. Make the main reaction kettle into a mother liquor containing 5% alkali. Generally, the amount of mother liquor is determined according to the height of the overflow pipe. When the temperature is raised to 77°C, the side reaction kettle is made into a mother liquor containing 3% alkali. The liquid level is controlled as 100cm, heat up to 90°C, then add alkali and chlorinated solution dropwise at the same time, control the flow rate of alkali to 2600L / h, and the flow rate of chlorinated solution to 1100L / h, and circulate the reaction through the saponification pump of the main reactor;

[0019] 3. The increased material in the main reactor overflows into the side reaction through the overflow pipe, and circulates the react...

Embodiment 3

[0021] A saponification process for producing vinylidene chloride comprises the following steps:

[0022] 1. Add 15% caustic soda into the high-level tank to raise the temperature to 80°C, and automatically control the liquid level to be constant;

[0023] 2. Make the main reaction kettle into a mother liquor containing 3% alkali. Generally, the amount of the mother liquor is determined according to the height of the overflow pipe. When the temperature is raised to 80°C, the side reaction kettle is made into a mother liquor containing 2% alkali. The liquid level is controlled as 90cm, heat up to 80°C, then add alkali and chlorinated solution dropwise at the same time, control the flow rate of alkali to 2400L / h, and the flow rate of chlorinated solution to 1200L / h, and circulate the reaction through the saponification pump of the main reactor;

[0024] 3. The increased material in the main reactor overflows into the side reaction through the overflow pipe, and circulates the re...

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PUM

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Abstract

The invention discloses a saponification process for producing vinylidene chloride. According to the process, caustic soda is added to a head tank, and a liquid level is automatically controlled to a constant level; a main reaction kettle is prepared into a mother liquor with an alkali content of 1-5%, a side reaction kettle is prepared into a mother liquor with an alkali content of 1-3%, and heating is performed to a temperature of 70-90 DEG C; an alkali and a chlorination liquid are simultaneously added in a dropwise manner, flow rates of the alkali and the chlorination liquid are controlled, and saponification of the main reaction kettle is adopted to pump a circulation reaction; increased materials in the main reaction kettle overflow into the side reaction through an overflow pipe, saponification of the side reaction kettle is adopted to pump the circulation reaction, excess materials flow in a steam stripping kettle through an adjust valve, saponification of the steam stripping kettle is adopted to pump the circulation reaction, and excess materials flow in a residue liquid tank through an adjust valve. According to the present invention, a saponification process is improved, caustic soda and a chlorination liquid are continuously added in a dropwise manner, and stability of an alkali solution concentration is controlled, such that a saponification reaction can be performed stably, side reactions are reduced, yield is improved, and environment pollution is reduced.

Description

technical field [0001] The invention relates to the transformation of a production process of chemical products, in particular to a saponification process for producing vinylidene chloride. Background technique [0002] In the traditional saponification process for producing vinylidene chloride, 5 tons of 18% caustic soda are all added to the saponification kettle, and after the temperature is raised to 80°C, 2.5 tons of chlorinated solution is added dropwise. The disadvantage of this process is that the concentration of caustic soda in the early stage of dripping chlorinated solution is high, and more by-products are likely to be produced; Residual discharge. Contents of the invention [0003] Purpose of the invention: the purpose of the invention is to provide a kind of production technique of the colorless transparent trichloroethane with high purity and little pollution in order to solve the deficiencies in the prior art. [0004] The technical scheme adopted in the ...

Claims

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Application Information

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IPC IPC(8): C07C21/08C07C17/25
Inventor 郑建彬张志明
Owner NANTONG REPAIR AIR CHEM BIOENG