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Use of water-soluble tetra sodium sulfonate phenyl porphyrin metal complex in microcontact printing

A technology of micro-contact printing and metal complexes, which is applied in the field of modern electronics to achieve the effect of exquisite patterns, low preparation cost and reduced use of organic solvents

Active Publication Date: 2014-03-19
南通博亿峰都新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the research on sodium tetrasulfonate phenylporphyrin metal complex as a water-soluble green printing agent has not been reported yet.

Method used

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  • Use of water-soluble tetra sodium sulfonate phenyl porphyrin metal complex in microcontact printing
  • Use of water-soluble tetra sodium sulfonate phenyl porphyrin metal complex in microcontact printing

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] 1. The polyimide substrate was soaked in 1mol / L sodium hydroxide at 70°C for 30 minutes, then soaked in 1mol / L acid at 70°C for 15 minutes, then washed with water, and dried in vacuum at 60°C to obtain a carboxylated substrate.

[0026] 2. Dissolve 5,10,15,20-tetrakis[4-(3'-propoxypyridinium bromide)phenyl]porphyrin zinc in water to obtain 5,10,15 with a concentration of 0.2g / L, 20-sodium tetrasulfonate phenylporphyrin zinc aqueous solution.

[0027] 3. Soak the PDMS stamp in 5, 10, 15, 20-tetrasulfonate sodium phenylporphyrin zinc aqueous solution for 60s, take it out and put it in N 2 Dry in air flow for 30s. Put the PDMS stamp coated with 5,10,15,20-tetrakis[4-(3'-propoxypyridinium bromide salt)phenyl]porphyrin zinc aqueous solution on the carboxylated substrate, press lightly for 5s, The PDMS stamp pattern is transferred to the surface of the substrate to obtain a pattern-printed substrate.

[0028] 3. Soak the patterned substrate in 0.1g / L PdCl 2 In the solutio...

Embodiment 2

[0030] 1. Soak the polyimide substrate in 3mol / L sodium hydroxide at 70°C for 30 minutes, then soak it in 3mol / L acetic acid at 70°C for 15 minutes, then wash it with water, and dry it in vacuum at 60°C to obtain a carboxylated substrate.

[0031] 2. Dissolve 5,10,15,20-tetrakis[4-(3'-propoxypyridinium bromide)phenyl]porphyrin zinc in water to obtain 5,10,15 with a concentration of 0.3g / L. 20-sodium tetrasulfonate phenylporphyrin zinc aqueous solution.

[0032] 3. Soak the PDMS stamp in 5, 10, 15, 20-tetrasulfonate sodium phenylporphyrin zinc aqueous solution for 60s, take it out and put it in N 2 Dry in air flow for 30s. Cover the PDMS stamp coated with 5, 10, 15, 20-sodium tetrasulfonate phenylporphyrin zinc aqueous solution on the carboxylated substrate, press lightly for 5s, transfer the PDMS stamp pattern to the substrate surface, and obtain a printed pattern base.

[0033] 4. Soak the patterned substrate in 0.1g / L PdCl 2 In the solution for 10s, after taking it out, ...

Embodiment 3

[0035] 1. Soak the polyimide substrate in 5mol / L sodium hydroxide at 70°C for 30 minutes, then soak it in 5mol / L acetic acid at 70°C for 15 minutes, then wash it with water, and dry it in vacuum at 60°C to obtain a carboxylated substrate.

[0036] 2. Dissolve 5,10,15,20-tetrakis[4-(3'-propoxypyridinium bromide)phenyl]porphyrin zinc in water to obtain 5,10,15 with a concentration of 0.5g / L, 20-sodium tetrasulfonate phenylporphyrin zinc aqueous solution.

[0037] 3. Soak the PDMS stamp in 5, 10, 15, 2, the concentration is 0.5g / L. Soak the PDMS stamp in 5,10,15,20-tetrakis[4-(3'-propoxypyridinium bromide salt)phenyl]porphyrin zinc aqueous solution for 60s, take it out and put it under N 2 Dry in air flow for 30s. Cover the PDMS stamp coated with 5, 10, 15, 20-tetrasulfonate sodium phenylporphyrin zinc aqueous solution on the carboxylated substrate, press lightly for 5s, transfer the PDMS stamp pattern to the substrate surface, and obtain a printed pattern base.

[0038] 4. S...

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PUM

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Abstract

The invention discloses a method for applying a water-soluble tetra sodium sulfonate phenyl porphyrin metal complex to microcontact printing. The method comprises the following specific steps of: 1) substrate carboxylation; 2) preparation of 5,10,15,20-tetra sodium sulfonate phenyl zinc porphyrin water solution; 3) microcontact printing; and 4) chemical plating. The method has the beneficial effects that 1. the obtained pattern is exquisite and fine and a new thought is provided for the microcontact printing industry; and 2. as a printing agent, the 5,10,15,20-tetra sodium sulfonate phenyl zinc porphyrin water solution has water solubility, can reduce use of organic solvents, has the advantages of environment-friendliness, low cost and stability and has great potential in industrial application.

Description

technical field [0001] The invention belongs to the field of modern electronic technology, and particularly relates to the application of a water-soluble sodium tetrasulfonate phenyl porphyrin metal complex in micro-contact printing. Background technique [0002] With the development of modern science and technology, microcontact printing, as an excellent surface "soft engraving" technology, has developed rapidly in recent years. Compared with other printing technologies such as optical lithography, microcontact printing has many characteristics such as fast, cheap, and flexible operation methods. However, there are few microcontact printing agents to choose from at present, and most of them use organic solvents to prepare the printing agent solution, which is not environmentally friendly enough. Therefore, it is of great significance to develop a stable and green printing agent. [0003] In recent years, scientists' research on sodium tetrasulfonate phenylporphyrin metal ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D11/02C23C18/40C23C18/20C09D11/033
Inventor 苏炜李培源
Owner 南通博亿峰都新材料科技有限公司
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