The invention discloses tough,
flame-retardant and hydrophobic reactive
polyurethane (RPU) based on polyhydroxy
ammonium polyphosphate as well as a preparation method and application thereof, and belongs to the crossing field of
flame-retardant materials and multifunctional polymers. The specific preparation process is as follows: diglycolamine is grafted to the surface of
ammonium polyphosphate through a one-pot
ion exchange reaction, and hydroxylated
ammonium polyphosphate (aAPP) is prepared. The preparation method comprises the following steps: preparing an aAPP-NCO double-end-capped
prepolymer, then carrying out an addition
polymerization reaction on the aAPP and the NCO double-end-capped
prepolymer under a medium-free condition to prepare
flame-retardant RPU (aAPPx-RPU), further introducing
polydimethylsiloxane (PDMS) into an RPU main chain, and preparing the tough, flame-retardant and hydrophobic RPU by utilizing the synergistic effect of
phosphorus (P),
nitrogen (N) and
silicon (Si). The preparation method of the tough, flame-retardant and hydrophobic RPU is green and efficient, and can be applied to the fields of fireproof flame-retardant materials, building materials,
electronic materials and the like which need to improve safety and durability.